N74-22383
(HJkSa-TH-X-70044) SOLID STATE
POLY HESITATION AMD CBY STALLOGEAP HY OF
PGLYIHIDE PBECUBSCSS Ph.D. Thesis - Va.
Oniv. (NASA) 160“ p HC $11.00 CSC1 20B
?
Unclas
G3/26 38198
SOLID STATE POLYMERIZATION AND
CRYSTALLOGRAPHY OF POLYIMIDE PRECURSORS
A Dissertation
Presented to
the Faculty of the School of Engineering and Applied Science
University of Virginia
In Partial Fulfillment
of the Requirements for the Degree
Doctor of Philosophy (Materials Science)
by
Noel Thomas Wakelyn
May 197^
APPROVAL SHEET
This dissertation is submitted in partial fulfillment of
the requirements for the degree of
Doctor of Philosophy (Materials Science)
l<uu4
Author
Approved :
Dean, School of Engineering
and Applied Science
May 1974
I
/
ABSTRACT
Although the production of crystallinity In a polymeric
system has historically led to commerically useful proper-
ties, the polyimides, prized for their high temperature
characteristics, as customarily synthesized by melt or solu-
tion casting, are amorphous. It has been shown that poly-
mide containing residual crystallinity can be synthesized
by isothermal annealing of crystals of the salt of the
diisopropyl ester of pyromellitic acid and phenylene dia-
mine. The reaction is topochemical in that the geometry of
the polymer product Is dependent upon that of the crystal-
line precursor. Infrared spectroscopy reveals the presence
of imide absorption In the polymer, while powder diffrac-
tometry suggests residual crystallinity. Single crystal
x-ray analysis of the monomer yields a structure of chains
of alternating acid and base suggesting that the monomer is
amenable to polymerization with a minimum of geometrical
disruption.
II
ACKNOWLEDGEMENT
The author wishes to acknowledge the following groups
and individuals for assistance in both research and prepara-
tion of this text: the National Aeronautics and Space
Administration for sponsoring the research reported and for
assistance with the preparation of the manuscript; Dr.
Vernon L. Bell, Jr. for the synthesis and separation of the
precursor starting materials and Dr. Norman J. Johnston for
their characterization by NMR; Mr. Robert A. Jewell for the
TGA; Dr. F. A. Muller for assistance in establishing the
unit cell; and Drs . R. £., Barker, Jr. and Roger Hanscom,
of the University of Virginia, for helpful suggestions con-
cerning the text.
LIST OP TABLES
Table Page
I. Statistics and Distribution of Normalized
Structure Factors . . 77
LIST OF FIGURES
Figures Page
1. Salt polymerization reactions. (R =
isopropyl functional group.) 6
2. X-ray powder dif frac tograms of amorphous
solution cast polyimide and crystalline
isomeric starting material 8
3- Percent mass loss vs. time for isothermal
annealing 12
4. DTA thermograms of PARA and META open tube
specimens annealed at 120°C 15
5(a). DTA thermograms of PARA open tube specimens
annealed at 130°C 16
5(b). DTA thermograms of PARA open tube specimens
annealed at 140°C 17
5(c). DTA thermograms of PARA open tube specimens
annealed at 150°C 18
5(d). DTA thermograms of PARA open tube specimens
annealed at 160°C 19
5(e). DTA thermograms of PARA open tube specimens
annealed at 170°C 20
6(a). DTA thermograms of META open tube specimens
annealed at 130°C 21
6(b)-. DTA thermograms of META open tube specimens
annealed at 140°C T . . . . 22
/V
Figures Page
6 (c). DTA thermograms of META open tube specimens
annealed at 150°C ..... 23
6(d). DTA thermograms of META open tube specimens
annealed at l60°C 24
6(e). DTA thermograms of META open tube specimens
annealed at 170°C ...... 25
7. DTA thermograms of PARA and META sealed
tube specimens 26
8(a). Infrared spectra of untreated META and
PARA isomers 30
8(b), Infrared spectra of untreated META and
PARA isomers. 31
9. Infrared spectra of PARA open tube specimens
annealed at 120°C 32
10(a). Infrared spectra of PARA open tube specimens
annealed at 130°C 33
10(b). Infrared spectra of PARA open tube specimens
annealed at 130°C ...... 34
11(a). Infrared spectra of PARA open tube specimens
annealed at l40°C 35
11(b). Infrared spectra of PARA open tube specimens
annealed at l40°C . . . 36
12(a). Infrared spectra of PARA open tube specimens
annealed at 150°C 37
12(b). Infrared spectra of PARA open tube specimens
annealed at 150°C . 38
13(a). Infrared spectra of PARA open tube specimens
annealed at l60°C 39
13(b). Infrared spectra of PARA open tube specimens
annealed at 160°C 40
14. Infrared spectra of PARA open tube specimens
annealed at 170°C 4l
V
Figures Page
15. Infrared spectra of PARA sealed tube specimens
annealed for 168 hours 42
16. Infrared spectra of META open tube specimens
annealed at 120°C. . 43
17(a). Infrared, spectra of META open tube specimens
annealed at 130°C 44
17(b). Infrared spectra of META open tube specimens
annealed at 130°C 45
18(a). Infrared spectra of META open tube specimens
annealed at l40.°C. 46
18(b). Infrared spectra of META open tube specimens
annealed at 140°C 47
19(a). Infrared spectra of META open tube specimens
annealed at 150°C 48
19(b). Infrared spectra o'f META open tube specimens
annealed at 150°C. 49
20(a). Infrared spectra of META open tube specimens
annealed at l60°C 50
20(b). Infrared spectra of META open tube specimens
annealed at l6o°C 51
21. Infrared spectra of META open tube specimens
annealed at 170°C 52
22. Infrared spectra of META sealed tube specimens
annealed for 168 hours 53
23 . Infrared spectra of PARA and META diisopropyl
pyromellitic acid 54
24. Infrared spectra of solution made polymer. . . 56
25 . Infrared spectra of selected compounds .... 57
26. X-ray powder dif fractograms of specimens of the
PARA and META isomers annealed at 170°C for
24 hours 67
Vi
TABLE OP CONTENTS
Chapter Page
I. Introduction 1
II. Solid State Polymerization 5
III. Results and Discussion 11
(a) Weight Change 11
(b) Differential Thermal Analysis 13
(c) Infrared Spectra (unannealed). 28
(d) Infrared Spectra (annealed) 62
(e) Powder Dif fractometry 66
(f) Thermal Gravimetric Analysis 72
(g) Single Crystal Dif fractometry 7^
IV. Conclusion 87
References 91
Appendix. 95
A. Listing of 2280 Relative and Normalized
Structure Factors
95
Figures Page
27. X-ray powder dif fractograms of specimens of
the PARA and META isomers annealed at 170°C
for 72 hours 68
28. X-ray powder dif fractograms of specimens of
the PARAi and META isomers annealed at 170°C
for 120 hours ' 69
29 . X-ray powder dif fractograms of specimens of
the PARA isomer, annealed at 170°C for 120 hours,
original and after Soxhlet Extraction ' 70
30. Weight fraction lost versus temperature (°C) for
PARA and META open tube specimens, annealed at
170°C for 72 hours, and subjected to a static
air TGA experiment with a heating rate of
5°C/min 73
31. Zero-moment test 79
32. Minimum residual rings in ac plane 82
33. Representation of molecular orientation of acid
and base parts of precursor salt 90
via
LIST OF SYMBOLS
o
A
. Ar
B
C
°C
cm
Cu
6
E
FREL
g-
H
hkl
HOR
K
X
micron
min
ml
Mo
n
N
Ni
Angstrom unit, 1.0 x 10 ^ meter
aryl, aromatic nucleus '
temperature factor
carbon
degree Celsius; t v , . = t_ . + 273-16
& Kelvin Celsius
-2 -1
centimeter, 1.0 x 10 meter (cm , wave number)
copper
delta, a partial charge
normalized structure' factor
relative structure factor
gram, 1.0 x 10 3 kilogram
hydrogen
indices of diffracting planes
alkyl alcohol
scale factor
lambda, wavelength, generally expressed in
Angstrom units
1.0 x 10 6 meter
minute
milliliter, 1.0 x 10”^ meter 3
molybdenium
n-glide plane
nitrogen
nickel
IX
NMR
R
S2T/L2
0
20
torr
Zr
nuclear magnetic resonance
alkyl group
sin 2 0/X 2
theta, angle of incident beam to reflecting
plarie
angle of diffracted beam from incident beam
1.33322 x 10 2 newton/meter 2
zirconium
two-fold screw axis
1
CHAPTER I
INTRODUCTION
The class of main chain aromatic polyimide polymers
contains many members of great interest to the researcher
and several of growing commercial importance. These mate-
rials, which are prized for their superior high temperature
and radiolytie properties, derived from their main chain
1-4
aromaticity , are produced as films, enamels, fibers, and
composites for such varied uses as insulation (for the wind-
ings of motors), adhesives, and lubricants. They also find
aerospace application as structural materials for light
5-9
weight, high temperature service. Since the imide poly-
mer is usually fabricated in solution from multi-functional
and rather bulky monomers. It is normally found In an amor-
phous state.
In the history of polymer science, the addition of
crystalline order (1-, 2-, or 3-dimensional) to a polymeric
system has resulted in the improvement of commercially
attractive properties such as hardness, toughness, and
increased tensile strength as well as increased dimensional
stability in the presence of solvents. Procedures varying
from the amide "salt process”, which produces a crystalline
product during polymerization, to post-polymerization
2
processes such as the calendering of film and drawing of
fiber are used to produce such order.
Bell, of the NASA-Langley Research Center, has syn-
thesized a variety of salt precursors of imide and pyrrone
polymers, based upon the earlier amide salt process and has
succeeded in establishing a novel route for obtaining a
variety of heteroaromatic polymers formed through a poly-
■ ip
amide stage. It occurred to him, since the precursors
appeared crystalline, that several of them might provide
possible routes for obtaining main chain aromatic polymers
in the crystalline state. Single crystals of trioxane have
been polymerized in the solid state to polyoxymethylene with
11 14
oriented chains. > A variety of ring monomers have been
subjected to radiation polymerization and were converted to
linear polymers by a ring opening mechanism in the solid
state, with properties which suggest the imposition of the
IS
monomer orientation and order upon the polymer structure.
Crystalline organic compounds have been observed to
undergo "topochemical" 1 ^ reactions in which the process is
dependent upon the geometrical relationships of the react-
ing groups such that not only is reaction in the liquid
state different in rate and/or product from reaction in the
solid state but different polymorphic forms of the same
compounds can display different chemistry. 1 ^ While one
3
would suppose that the production of polymerization by-
products would disrupt the crystalline order of the reacting
molecular matrix as they traveled to the surface, topotactlc
condensation polymerization has been observed. For example,
the cyclization of phthalanilic acid, with the elimination
17
of water, is reported to be topotactic. The essential
characteristic of topotactic polymerizations appears to be
the minimization of thermal motion to that actually required
l8
for the linking up of the monomer molecules.
If one could polymerize a crystalline pre-imide pre-
cursor in the solid state at a temperature at which the
minimum molecular motion to achieve the imide linkage occurs,
there is the possibility that the polymer would display at
least part of the crystal structure of the starting material
and a crystalline aromatic polylmide would be achieved.
Along with the possibility of enhanced physical properties
there is the chance of gaining enough chemical and physical
understanding of the process such that one could move toward
the long term goal of the synthetic chemist of being able to
tailor desired properties into his constitutions of matter.
Be that as it may, solid state polymerization holds out the
possibility of constraining an array of molecules in a
known and perhaps desired position until they react.
4
The goal of this research Is the achievement of poly-
imide polymer, possessing residual crystallinity, by the
annealing of a pair of crystalline precursors in various
ways, for varying periods of time, and at various tempera-
tures. A variety of analytical tools have been used in the
attempt to characterize the materials, before and after
annealing, in an effort to determine what they are, what
they become, and the geometrical and physical paths taken.
5
CHAPTER II
SOLID STATE POLYMERIZATION
In order to ascertain the possibility of synthesizing
crystalline polyimide polymer in the solid state and per-
haps gaining insight Into any topochemical constraints as
well as achieving mechanistic understanding, such as the
involvement of an amide stage, it was decided to isother-
mally anneal these salt precursors (called salts by analogy
to the earlier amide work) at the lowest possible tempera-
ture required to generate polymer. It was thought that
more highly crystalline polymer could be achieved at the
lowest temperatures, in which molecular motion is minimized
to that actually required for the formation of the imide
linkage without destroying the crystalline order present
in the salts, or, at least to maintain some of that order
in the polymer. It was recognized that this could Involve
prolonged annealing times. To discern the lowest possible
temperature and the required times, various temperatures
and times were used until a data assemblage was generated
with temperature varying in 10° C Increments from 120 to
170° C and annealing times varying from 1 day to 1 week.
Both open and sealed specimen containers were used. The
overall reaction for the production of polyimide from
isomeric salt is idealized in Figure 1.
6
(c) Polyimide.
Figure 1.- Salt polymerization reactions. (R = isopropyl
functional group.)
7
The starting materials used in this study were a pair
of "salt" precursors of imide polymers synthesized from
phenylenediamine and an isomeric pair of diacid diisopropyl
esters of pyromellitic acid, separated by fractional
crystallization and characterized by NMR. The materials,
presumed to be ammonium salts, can be named 1 , 4-phenylene-
diammonium 4 , 6-dicarboisopropoxy-l , 3-benzenedicarboxylate
(termed the neta isomer and present in the form of pale
pink needles) and 1 , 4-phenylenediammonium 3 , 6-dicarboiso-
propoxy-l , 4-benzenedicarboxylate (termed the para Isomer
and present in the form of pale pink platelets). Commer-
cial analysis yields:
Calculated
C 22 H 26 N 2°8
% Found %
Meta
Found %
Para
Calculated %
Monohydrate
Carbon
59-19
58.88
58.42
56.89
Hydrogen
5.87
5-87
5.94
00
0
\o
Oxygen
28.69
29.03
29.95
31.00
Nitrogen
6.27
6.15
6.13
6.03
These data suggest the possibility of hydration of the
para isomer, with less than 1 water/unit cell.
The X-ray powder dif fractograms of Figure 2 show the
amorphous characteristics of the polyimide produced by
solution casting along with the crystalline patterns of the
9
two salt precursors. Both salts should In time transform
into the same polymer but perhaps by utilizing different
routes and under different conditions produce polymer in a
different geometrical form. It was supposed that the poly-
mer produced by solid state polymerisation will have a pow-
der pattern intermediate between the crystalline patterns
and that of the solution cast material.
The annealing was accomplished in a vacuum oven, modi-
fied by the installation of a massive aluminum block into
which specimen receiving holes had been cut and with thermo-
couples placed in the region of specimen residence. It was
found that the temperature of the interior of the block
could be maintained to within better than 1°C for periods
up to a week. The interior of the oven was subject at all
times to out-gassing by the action of an oil diffusion vacuum
pump which maintained a pressure in the range of 1 torr.
The usual procedure for the insertion of a specimen involved
the attaining of the desired temperature, its maintenance
for sufficient time to insure that it was in true equilibrum
for the conditions, breaking of the vacuum and rapid implace-
ment of an open tube containing the preweighed specimen,
followed by the closing of the oven and reestablishment of
the vacuum. The mass of the container and specimen is
insignificant compared to that of the aluminum heat
10
sink. Typically a temperature decline of 2°C from that
desired was measured for the first half hour following the
insertion of a specimen. The succeeding 5 hours of a test
would be conducted at 1°C lower than desired, the desired
temperature being reached and maintained thereafter.
It was recognized that any weight change information
would be obscured, at least for the higher temperature
tests, by loss of material other than the product water and
alcohol due to the combination of increased temperature and
lowered pressure. Therefore sealed tube specimens were
annealed as duplicates for some of the higher temperature,
longer time, tests. Specimen and container were sealed in
a tube after room temperature outgassing for two days under
-7
a vacuum-ion pump with a manifold pressure of 3 x 10
torr as measured by ion gage. Typically the bottom of the
- 6
tube would be at 5 x 10 torr during the outgassing
procedure. PET* film sealed in a similar manner established
-2
a pressure of 1 x 10 torr within the sealed tube.
The course of polymerization was followed for the
various times and temperatures, for the two isomeric
salts, in open and sealed tubes, by measurement of weight
change, differential thermal analysis, infrared spectrometry,
and powder diffractometry .
*Poly (ethylene terephthalate )
11
CHAPTER III
RESULTS AND DISCUSSION
Weight Change . The complete reaction from the salts
of the diacid diisopropyl esters of pyromellitic acid and
phenylenediamine , with the loss of 2 moles of water and 2
moles of isopropyl alcohol per mole of salt to produce the
polyimlde polymer, would result in the loss of about 35$
of the mass of the specimen. Figures 3(a) and 3(b) display
the percent loss of mass as a function of time for the iso-
thermal annealing, at the various temperatures and contain-
ment conditions, of the meta and para isomers, respectively.
The weight change data of the two isomers are similar,
with the 150°C annealings leveling with time slightly
below the 35$ complete reaction line. After 1-3 days at
temperatures above 150°C, for the open tube specimens,
there is material loss higher than that required for com-
plete reaction indicating loss of reactant material.
Sealed tube specimens were annealed in an attempt to
obtain data covering the higher temperature, longer time,
annealings without reactant material loss. These produce
percent weight losses between the 120-130°C open tube cases
for the l60-170°C sealed tube cases. Of course, the pre-
sence of water/alcohol • above the polymerizing material
should tend to establish an equilibrium condition rather
13
far removed from complete polymerization. There is. In
general, increased loss with temperature and increased loss
with time until about 3 days, at which time reaction involv-
ing water/alcohol loss is substantially complete.
Linear regression analysis of the percent weight loss
data versus the square root of time in hours yields an ade-
quate linear relationship for the para and met a, 130°C,
specimens up to 120 hours. For the equation, y = a + bx :
PARA META
a -0.3653 -0.4757
b 2.513 2.532
SAMPLE CORRELATION COEFFICIENT 0.9864 0.9884
STANDARD ERROR OF ESTIMATE 1.722 1.603
The implication is that the reaction in this low tempera-
ture range is diffusion controlled and that a parabolic
diffusion law Is governing.
Differential thermal analysis . Differential thermal
analysis thermograms were taken of each of the annealed
specimens with a DuPont Model 900 instrument using a pro-
grammed heating rate of 10° C/min. and standard glass beads
as a reference. Tracings of the 120°C open tube annealed
specimen thermograms, comparing the para and meta isomers
14
for the 24 and 168 hour annealings, are displayed in figure
4. Figures 5(a) to 5(e) display tracings of the DTA thermo-
grams of the open tube annealings of the para isomer from
130 to 170°C, respectively. Figures 6(a) to 6(e) display
tracings of the DTA thermograms of the open tube annealings
of the meta isomer from 130 to I70°C, respectively. Figure
7 displays tracings of the DTA thermograms of the para and
meta sealed tube specimens. Comparison of the magnitudes
of endothermic absorption is possible on the same curve but
not between different curves. The temperature of an endo-
therm is directly comparable for all curves.
The DTA data of Figures 4-6 appear to be a series of
single or double fusion endotherms.- Such is not the case.
In the usual melting point determination in which the speci-
men is inspected visually as the temperature is increased
no melting is observed to occur for either annealed or unan-
nealed specimens. At 100-105°C the unannealed para specimen
appeared to try to melt in that it in part assumed the shape
of the capillary tube and in part shrunk away from the tube
and appeared to shimmer, without actually melting. Near
150°C, both isomers underwent faint color changes toward
red. Near 175°C, the para isomer appeared to have crystal-
lised in the sense that it had the grainy appearance of a
crushed inorganic. At this temperature, the meta isomer was
PARA: 170 C, 168 hours
C
META: 160°C, 168 hours
META: 170°, 168 hours
of PARA and META sealed tube
27
a brilliant deep red. At 190°C, both isomers were a rust
brown. Above 190°C, the meta isomer had the appearance of
a hard irregularly shaped, chunky material while the para
filled the tube and had a porous appearance.
The DTA thermogram of the unannealed para isomer is
characterized by 1 endotherm whose minima occurs slightly
above 200°C while the unannealed meta isomer, also display-
ing 1 endotherm, has Its minima slightly below 200 °C. An
attempt at an instant melting point, in which the material
is deposited upon a stage which has been preheated to the
desired temperature, leads to melting with decomposition at
ca. 200°C for both isomers, followed by solidification.
Melting with decomposition is defined as a frothy melt with
evident evolution of gas and change in color. The pale pink
crystals produced a red frothy liquid which immediately
changed to a brown solid.
The para isomer, when heated for 24 hours at 120°C,
displayed a major DTA endotherm near 205°C with a slight
indication of a second endotherm at 235°C. After 168 hours
at the same temperature the DTA produces 2 endotherms, one
at near 205°C and another at near 235°C, the lower tempera-
ture endotherm being of slightly greater magnitude. See
figure 4. The 24 hour, 120°C, meta case produces one major
endotherm near 197°C, while the 168 hour specimen ,■ 120°C ,
28
produces two endotherms, one near 195°C and another near
220°C, the lower temperature endotherm being 2-3 times the
size of the higher temperature one. Since melting is not
occurring at this lowest annealing temperature, it is assumed
that 2 solid state transitions are occurring for each isomer,
the second transition, at the higher temperature in each
case, being possible only after prolonged annealing has
produced enough change in the material. The change that
allows the second transition to proceed is assumed to be
indicated by whatever is producing the first endotherm.
Since there are 2 transitions and 2 gaseous products
involved in the polymerization, one might tend to associate
a transition with the endothermic production and evolution
of gas. However, model compound studies of similar mate-
rials, same diacid-diester but with tetraf unctional amines,
have shown the elimination of water and alcohol to occur
1 Q ~i p
simultaneously. The previously cited work and another ^
indicate that meta-orlented salt Intermediates react to
produce polymer at slightly lower temperatures than para
intermediates in accord with present finding of the relative
positions of the lower temperature endotherms.
Infrared spectra (unannealed) . The meta and para
isomers contain a variety of infrared active functional
groups which can in various ways interfer with each other
to obscure the interpretation of the respective spectra.
29
In addition to the presence of the aromatic rings and the
two isopropyl ester moities there are the following possi-
bilities :
(a) 2 amino + 2 carboxyl groups
(b) 1 amino + 1 ammonium + 1 carboxyl + 1 carboxylate
(c) 2 ammoniums + 2 carboxylates
In addition to harmonic interactions between the various
bands there are band shiftings due to both inter and intra-
molecular hydrogen bonding and .interactional effects pro-
duced by proximity of groups relative to each other and re-
lated to the internal geometry of the respective unit cells
of the crystals.
The supposed polymerization, of the salts by long term
isothermal annealing would tend with time to remove the
amino, ammonium, carboxyl, and carboxylate bands (or any
combination thereof) and produce bands representative of
the imide linkage. The present IR spectra, taken with both
the Perkin-Elmer 137B and the PE-421 utilizing the KBr disk
method includes the original, unannealed specimens (Figures
8a and 8b), the open tube para specimens, function of time at
specific annealing temperatures (Figures 16-21), the closed
tube meta specimens at two different temperatures (Figure
22), specimens of the materials from which the salts were
made (Figure 23), specimens of solution made polymer (Figure
Percent transmittance
Figure 8(a).- Infrared spectra of untreated META and PARA isomers.
UJ
o
Percent transmittance
Figure 8(b).- Infrared spectra of untreated META and PARA isomers.
wavelength (microns;
Figure 9.- Infrared spectra of PARA open tube specimens
annealed at 120°C.
Figure 10(a).- Infrared spectra of PARA open tube specimens
annealed at 130°C.
Figure 10(b).- Infrared spectra of PARA open tube specimens
annealed at 130°C.
Figure 11(b).- Infrared spectra of PARA open tube specimens
annealed at 1^4 0°C .
WAVELENGTH {MICRONS;
Figure 12(b).- Infrared spectra of PARA open tube specimens
annealed at 150°C.
<30 1 — -
3 4
5
6 7 8 9
i 10
WAVELENGTH
MICRONS,
4000 3000
2000
1500 CM’
1000
48 hours
WAVELENGTH
MICRONS:
4000 3000
2000
1500 CM' 1
1000
72 hours
WAVELENGTH 'MICRONS)
Figure 13(a).- Infrared spectra of PARA open tube specimens
annealed at l60°C.
40
4000 3000 2000 1500 CM 1 1000 900 800 700
4000 3000 2000 1500 CM’ 1000 900 800 700
Figure 13(b).-
Infrared spectra of PARA open tube specimens
annealed at l60°C.
ABSORBANCE ABSORBANCE
43
3456789 )0 11
WAVELENGTH .MICRONS.
12 13 14 15
4000 3000 2000 1500 CM' 1000 900 800 700
Figure 16.- Infrared spectra of META open tube specimens
annealed at 120°C.
ABSORBANCE . . ABSORBANCE
44
t
4 COO 3000 2000 1500 CM ’ 1000 900 800 700
4000 3000 2000 1500 CM 1 1000 900 800 700
Figure 17(a).- Infrared spectra of META open tube specimens
annealed at 130°C.
3 4 5 6 7 8 9 . 10 11 12 13 14 15
WAVEIENGTH (MICRONS) '
Figure 17(b).- Infrar.ed spectra of META open tube specimens
annealed at 130°C.
ABSORBANCE ABSORBANCE
47
3 4 5
6 7 8 9 10 11
wavelength 'microns;
12 13 14 15
4000 3000 2000 1500 CM’ 1000 900 800 700
Figure 18(b).- Infrared spectra of META open tube specimens
annealed at l40°C.
49
4000 3000 2000 1500 CM' 1000 900 800 700
3 4 5 6 7 8 9 10 11 12 13 14 15
WAVELENGTH (MICRONS)
4000 3000 2000 1500 CM’ 1000 900 800 700
Figure 19(b).- Infrared spectra of META open tube specimens
annealed at 150°C.
4000 3000
wavelength
■microns;
4000 3000
2000
1 500 CM 1
1000
24 hours
l .....
WAVELENGTH
■MICRONS
4000 3000
2000
1500 CM 1
1000
72 hours
I
r ■
0 11
WAVELENGTH (MICRONS!
Figure 21.- Infrared spectra of META open tube specimens
annealed at 170°C.
ABSORBANCE ABSORBANCE
ABSORBANCE ABSORBANCE
55
24), and specimens of selected compounds which act as models
for the interpretation of spectra (Figure 25) ♦ The presented
spectra of the unannealed specimens (Figures 8a and 8b) are
partial tracings of the strip chart recording from the dual
grating PE-421 instrument while the other IR data (Figures
9-25) are reduced reproductions of the original records from
the prism instrument (PE 137B) and are presented to describe
the effect of the annealing of these materials and their
qualitative change with time and temperature.
The spectra of the original, unannealed, meta material
(Figures 8a and 8b) contains sharp bands at 3375 and 3300
cm ^ which are ascribed to asymmetric and symmetric stretch-
ing of NH^. Both bands are shifted downward from the posi-
— 1 20
tion of the free amino group (3500 and 3400 cm ) by about
110 cm The calculated position of the lower band (sym-
metric stretch) by use of the empirical relation of Leonard
21 -1 -1
and Owens is 3302 cm as compared to 3300 cm measured.
The implication is that the shift to lower wave-numbers is
caused by the participation of the N-H groups in hydrogen
bonding and/or the effect of the crystal lattice. This
assignment and the substantiation produced by the calcula-
tion from the empirical relation which shows that the wave-
number combination for these bands is proper for N-H stretch
rules out possibility "c" for the meta isomer.
4000 3000 2000 1500 CM' 1000 900
4000 3000 2000 1500 CM' 1000 900
Figure 24.- Infrared spectra of solution
PARA film
after post
treatment
~j
— i
■
12 13 14 15
polymer
57
WAVELENGTH 'MICRONS,
4000 3000 3000 1500 CM ’ 1000 POO R00 700
WAVELENGTH MICRONS;
WAVELENGTH (MICRONS)
Figure 25.- Infrared spectra of selected compounds.
58
The spectra of the original, unannealed, para material
contains a fairly broad band at 3175 cm ^ with a small broad
shoulder at 3110 cm -1 . If these were N-H stretching bands,
calculation from the empirical relation would yield a wave-
number of 3127 for the symmetrical stretch as compared with
3110 cm ^ measured. Nakanishi 22 lists a difference of 12
cm between calculated, and measured as "good agreement".
Bellamy 2 ^ , in his discussion of amino acids (which exist as
zwitterions ) , reports that no absorption occurs in the NH
stretching region of 3500-3300 cm * but that instead a single
band appears in the 3130-3030 cm -1 region which has been
assigned to the NH^ + stretching mode. Although Nakanishi
reports NH band shifting of 170 cm 1 and the present meta
isomer NH bands are shifted by ca. 110 cm \ for the above
para bands to be NH stretches a shift of ca. 310 cm ^ would
24
be required which seems excessive. However, Bellamy In
his discussion of intermolecular hydrogen bonds, while ex-
pressing doubt that the small downward shifting (<100 cm
of the NH bands in condensed phase amines are due to hydro-
gen bonding and, indeed, stating the possibility that they
represent a solid state effect, gives an absorption range
of 3320-3240 cm -1 for the association with ketonic groups,
3300-3150 cm -1 for the association with other nitrogen atoms,
and the approximate range of 3^00-3100 cm 1 for possible
59
associated NH stretch absorptions. He also indicates that
broadening of the low-frequency band implies hydrogen bond-
ing.
The orginal para isomer also has a broad band at about
3^00 cm "*■ . This can be the overtone of the C=0 band or a
hydrogen bonded OH stretch . If this band (missing from
the rrieta isomer spectra) is hydrogen bonded OH the implica-
tion Is that there is a continuous variation of the NH stretch
from that of the free amino down to the with the lower
frequency band broadening until It disappears at complete
ionization, or when the partial changes become complete, as
0 H , 0 ,
(i it + ii - +
Ar-C-0 . . . H . . . N - Ar Ar - C- 0 H-N - Ar ,
6 - H 3
the present case being border line, close to salt. Or, if
as Implied by Bellamy, the greatest band lowerings are pro-
duced by N-N interactions, and if this type of interaction
is that required to produce the measured effect, we would
despair of forming polymer from the para Isomer in the solid
state in the topochemical sense.
Infrared spectra of acids, obtained on solids, have
shown OH absorptions occurring as broad bands over the range
of 2500-3000 cm -1 , with a main peak near 3000 cm -1 and a
satellite near 2650 cm 1 , while lacking the free carboxyl
60
absorption, 3500-3600 cm . Both the meta and para iso-
mers (as well as the meta and para diacid-diester starting
material. Figure 23) lack the free OH absorption at 3500-
3560 cm The para has a satellite at 2670 cm 1 and the
meta has one at 2610 cm 1 . Although bands in this region
can be assigned to symmetric NH^ + stretch, they are assigned
to acid OH stretch (showing solid state association effects)
since the broad band is missing in the 3030-3130 cm region
(aside from the small para shoulder at 3110 cm ^) and there
Is only one, rather than a close pair of absorptions in the
2000-3000 cm* 1 region for the two isomers. The parent di-
acid-diester compounds, which do not contain nitrogen, also
absorb in this region. The band at 2985 cm 1 , found in both
isomers and their starting materials, is assigned to isopro-
pyl ester, perhaps overlapped with an OH stretch at 2970
cm 1 .
The meta and para Isomers have highly (and equally)
intense C=0 stretching vibrations at 1715 and 1705 cm 1 ,
respectively. They have intense C-0 stretches (not pure
27 “1
C-0) ' at 1095 and IO 85 cm , respectively, supposedly aris-
ing from a C-0 vibration coupled with an OH in-plane defor-
mation vibration and being affected by structural changes
28
in the opposite direction to that observed in C=0 frequency.
It thus appears that since the C-0 vibrations of the para
61
isomer at about 1700 and 1100 cm ^ are lower in frequency than
the respective meta vibrations that the carboxyl groups of
the para isomer are more highly associated and suggests the
possibility of either a bifurcated hydrogen bond in this
isomer or amine-amine acid-acid association. There are small
bands in each isomer between 1610 and 1550 cm -1 and between
ItOO cm and 1300 cm ^ suggestive of ionized carboxyl. ^
However, since the strongest absorptions are in the about 1700
cm region (carbonyl attached to aryl nuclei), it is assumed
that there is un-ionized carboxyl present in both isomers
based upon the presumption that the 1700 cm 1 band contains con-
tribution from carboxyl carbonyl as well as ester carbonyl
(since there is only one absorption here) coupled with the
facts that the case for un-ionized amine (and thus carboxyl)
is more evident for the meta isomer and that these carbonyl
absorptions are of comparable magnitude.
For the current analysis it is assumed that both isomers
exist before annealing, in the un-ionized state, the meta
NH stretch lowering being due to solid state effects and
perhaps weak hydrogen bonding, while that of the para being
due to strong hydrogen bonding. The para isomer may contain
some ionization. The spectra is cluttered with possibilities
and overlaps and. confused by circumstances such as meta
bonded OH band being lower in frequency than the para’s
62
while its C=0 band at ca. 1700 cm 1 is higher than the para’s
and its N-H stretch being virtually undisturbed in comparison
with the para's. A summary of the effects leading to the
assumption of no ionization is as follows:
I) two N-H bands above the position of the ammonium band
(which is missing)
II) the highest intensity bands are the single carbonyl
vibrations, ca. 1700 cm -1 , of virtually equal
intensity for both Isomers
III) OH absorption in the range 2500-3000 cm”^ for both
isomers, especially the one at 2970 cm" 1 , which is
also present in the diacid-diester starting material
Infrared spectra (annealed) . The qualitative changes of
the annealed precursors are described by the reduced repro-
ductions of the records from the prism spectrophotometer in
Figures 9 - 22 . Infrared bands characteristic of the imide ring
are reported to be the C-N at 1380 cm 1 , the C =0 doublet at
1780 and 1720 cm -1 , and a band of unexplained origin at 720
—1 2 0
cm . These bands are present in the spectra of phthalimide,
which is a model compound representative of a single link of
the polyimide structure. They are present in pyromellitic dian-
hydride (PMDA), with a shifting downward in wave number for
the 720 cm - ^ band, and including the 1380 cm ^ band, of
different shape, even though this compound has bridged oxygen.
They are not present in phenylene diamine, one of the parent
compounds of the precursor isomers. (Figure 25 ).
These imide bands are not present in the parent
diester-diacid compounds (Figure 23 ) with the
63
exception of the band at 1380 cm -1 which appears as a sharp
spike similar in appearance that present in PMDA. It appears
that the 1380 cm band is a poor choice to follow the for-
mation of the imide ring and if used for such purpose must
be rather broad.
Infrared evidence for the imide ring system appears in
the lowest temperature para annealings. While missing in
the 24 hour, 120°C annealing, imide bands occur in the 168
hour spectrum for this temperature as small shoulder at
1780 cm ^ and a small but distinct peak at 720 cm . (Fig-
ure 9)- For the 130° annealings (Figures 10 a & b ) there Is
slight indication for the 720 cm ^ absorption at even 24 hours,
but definite presence at 72, 120, and 168 hours. The 1780
cm - ^ absorption is illusory at 72 and 120 hours at this
temperature but definite at 168 hours along with the 1720
cm ^ absorption. The 1720 cm ^ absorption is a poor one to
follow in these spectra since it occurs at the bottom of the
intense carbonyl absorption and is obscured In several of
the presented spectra by the wrong choice of attenuation for
the concentration of absorbing material in the optical path.
Imide absorption is definite at 720 cm 1 and 1780 cm ^ for
the para precursors annealed at 140°C and above (Figures
11-15) for all annealing times, especially the sealed tube
specimens (Figure 15) in which the absorptions at 1380 and
64
-1
720 cm rival the carbonyl in magnitude. In a spectrum of
solution cast para film the 720 and 1380 cm 1 absorptions
appear with magnitude equivalent to that of the carbonyl
while a spectrum of film, post-treated by annealing in
vacuo at 300°C for one hour, displays a 720 cm 1 absorption
reduced in magnitude with respect to that of the 1380 cm
and carbonyl absorptions. (Figure 24).
There is no definitive evidence of the imide ring in
the infrared spectra of the meta precursor for specimens
annealed at 120°C. (Figure 16). There is slight indication
of the 720 cm ^ absorption in specimens of this isomer an-
nealed at 130°C for periods of time equal to or greater than
72 hours. (Figure 17)- There is indication of the 720 cm"^
absorption, but not of the other imide ring bands, in the
140°C spectra (Figure 18) and comparable 720 cm ^ absorption,
with slight indication of 1780 cm ^ absorption, in the 150°C,
meta spectra (Figure 19). It is only in the/168 hour, l60°C,
meta spectrum that absorption comparable to the para isomer
is observed. (Figures 13 and 20). The spectra of the open
tube 170°C meta specimens (Figure 21) and that of the sealed
tube specimens (Figure 22) yield as much, or more, indication
of the imide ring as the corresponding para isomer spectra.
In fact, the only spectra indicating complete reaction, as
revealed by the loss of the isopropyl absorption at 2985 cm - ' 1 '
65
are the meta 170°C, 72 and 120 hour, specimens and. the seal-
ed tube specimens of both isomers. If the requirement for
complete reaction be the complete loss of absorption near
-1
3000 cm , the only specimens which are wholly polyimide
in this sense are the sealed tube meta isomers and the 120
hour, 170°C meta isomer. Thus while imidization, as Judged
from infrared spectra, appears to proceed more rapidly ini-
tially for the para Isomer, It is only the meta formulation
which attains complete imidization.
If an amide had been formed as a stable intermediate a
carbonyl absorption should occur near 1650 cm ( the Amide
31
I band ) , perhaps evidenced as a splitting of the current
carbonyl toward a lower wave number. There is what appears
to be a splitting of the carbonyl in the longer time, higher
temperature specimens but this occurs in the region and the
appropriate specimens for a 1720 cm -1 imide band. None of
the specimens display an unambiguous Amide I band. The NH
absorptions above 3000 cm ^ persist In the 120°C, para speci-
mens and in the 24 hour, 130°C specimen and no others. In
the spectra of the meta specimens the NH absorptions are
more persistent, being present in the 120°C specimens and
the 130°C up to and including 72 hours, but no other, in
keeping with the present findings which imply that imidiza-
tion occurs more rapidly initially in the para isomer. With
66
the disappearance of the HN absorption, there appears to be
a broadening in the 3000 cm -1 region and a doubling in the
2500 - 2800 cm 1 region suggestive of the participation of
a salt form as an intermediate but the doubling is present
in the diacid-diester starting materials and the broadening
is subjective since the curve is continuous through the
former NH region.
tome try . The diffraction patterns of the
annealed specimens were taken, using a General Electric XRD-
5 instrument, in an attempt to record the crystallinity change
as a function of time and temperature of annealing. As
expected there was a progressive change of the individual
patterns from those characteristic of the respective salts
toward, but not reaching, that of the solution cast material.
(Figure 2). Illustrative of this change is that recorded
from the 170°C specimens. (Figures 26-29). It Is observed
that the broad diffraction band in the 20° (20) position of
the solution cast material is still represented In the 170°C,
120 hour, specimens of both isomers by more than one differ-
entiable peak. This would have to be Interpreted by the
usual methods of crystallinity determination by x-ray dif-
fractometry 32 3 \ In which the specimen Is mathematically
positioned between maximum and minimum crystallinity diffrac-
tion patterns, as containing residual crystallinity. In
Figure 26,- X-ray powder diffractogr*
annealed at 170°C for 24
Figure 27.- X-ray powder dif fractograms of specimens of the PAHA and META
isomers annealed at 170 U C for 72 hours.
CuKa doublet
Figure 29 .- X-nay go»der dlffractograms of specimens of the PARA Isomer, annealed
at 170 C for 120 hours, original and after Soxhlet Extraction.
71
addition to this region there are peaks in the diffracto-
grams for these specimens in regions where the solution cast
material displays a flat background.
The thought being that the deviations from the broad,
glass-like, pattern of the amorphous film material sugges-
tive of residual crystallinity might be those of residual
unreacted starting material, a 170°C, 120 hour para speci-
men was subjected to soxhlet extraction. In soxhlet extrac-
tion a solid is repeatedly bathed in liquid in which one or
more of its constituents is soluble by use of a reflux con-
densing geometry. The unpolymerized material is completely
soluble in the hot water/isopropyl alcohol solvent used in
the extraction. Whether the 24 hour extraction, in addition
to removing unreacted material, would damage the order of
the insoluble polymer or further its crystallization is un-
known, but the former is believed since the temperature of
the boiling mixture is lower than the annealing temperature
and its constitution should drive the depolymerization reac-
tion. It is estimated visually that greater than one half
and less than two thirds of the specimen was returned to the
round bottom flask.
The solid remaining after extraction, while smaller
than that normally used in the powder diffractometry deter-
minations , was placed in a special sample holder and the
72
powder pattern taken. Leached and unleached patterns are
displayed In Figure 29. With the scale set such that an
unleached peak would have been increased, the small leached
specimen displays the multiple peaks in the region of the
amorphous halo that are indicative of crystallinity. The
conclusion is that crystalline polymer is present.
Thermal Gravimetric Analysis . One common method of
estimating the high temperature performance of a polymer
is that of Thermal Gravimetric Analysis (TGA) , in which
specimens are heated in air and/or in vacuo and their weight
change with time recorded. The air testing can be thought
of as, in essence, a measurement of crystallinity since
weight loss can be associated with ease of diffusion of oxi-
dant into the material and ease of diffusion of oxidation
products out of the material, thus a well ordered and tight-
ly packed lattice, in effect a crystalline one, should dis-
play less reducible surface area to the oxidant.
Figure 30 displays the weight fraction lost for para
and meta 170°C, 72 hour, specimens heated in static air with
a heating rate of 5°C/min. A static air TGA experiment is
one in which a small opening at the top of the containment
tube allows loss of material to the atmosphere and the ten-
dency toward equilibration of pressure but does not repre-
sent the severity of a flowing air test in which openings
Weight fraction lost
Figure 30
Temperature, °C
Weight fraction lost versus temperature (°C) for PARA and META open
tube specimens, annealed at 170°C for 72 hours, and subjected to a
static air TGA experiment with a heating rate of 5°C/min.
74
are present at both top and bottom. The meta isomer proves
more stable in this TGA experiment than the para, for the
stated annealing condition, and the implication is that it
is thus the more crystalline specimen.
Single Crystal Dif fractometry . In an effort to learn
the starting geometry of the isomers and perhaps thereby
discern the meaning of the two DTA endotherms as well as
determine if the Isomeric structures were such that it would
be conceivable that they could be amenable to topochemical
polymerization, crystals of the isomers were examined under
a microscope while mounted to a goniometer which could be
rotated during the examination. Both appeared to possess
monoclinic morphology. The para isomer was present as ex-
tremely thin plates while the meta isomer, although consist-
ing of small crystals, was rod-like and thus more amenable
to diffraction analysis. A small meta single crystal was
found and precession camera photographs with Ni-filtered
CuK radiation showed that it belonged to the monoclinic
space group 14 (systematic absences: h 01 with {h+SL) odd,
OkO with k odd). The axes were defined such that the space
group was P2^/u in order to obtain a unit cell with a B-
angle close to 90°. Although this orientation is very com-
mon in the crystallographic literature for organic crystals,
it is non-standard from the viewpoint of the International
75
Tables for X-Ray Crystallography 35 and the following equi-
point set and geometrical structure factors were calculated
for P2^/n:
x,y t z
x- 1 / 2 , 0 + 1 / 2 , z- 1/2
x+ 1 / 2 , 0 - 1 / 2 , z+ 1/2
for ( h + k + i, ) even
A = 4 cos 2 7 t (fix + Iz) cos 2-nky
for (k + k + i) odd
A = -4 sin 2n(hx+Zz) sin 2nky
The mounted crystal was taken to the automatic Picker
Single Crystal X-Ray Diffractometer at the University of
Virginia where the intensities of a quadrant of reflections
were measured (ft: 11 to -12; fe: 28 to 0; t: 5 to 0) out to
sin 0/lambda = .4736 using Mo - radiation. A graphite
monochromator was used with a setting angle of 11.52°
(20 m ). To check electronic and crystal stability during the
period of data collection, the intensities of standard
reflections (200, 080, 002) were measured every 60th
reflection. No systematic variation was observed for these
standard intensities. The master card program for the
diffractometer provided the following unit cell data:
76
a * 12.7127A Beta » 101.53°
b = 30.1615A
c = 6.0594 a
Volume = 2276.50 cubic angstroms
The x-ray density of the meta crystal, calculated from the
above measured unit cell parameters for four acid-base pairs
per cell, is 1.30 g/ml as compared to 1.22 g/ml by commer-
cial floatation analysis. (Commercial analysis for the
para isomer: 1.57 g/ml.)
An overall Isotropic temperature factor (B = I. 986 )
and scale factor ( K = 15.9142) were calculated using a Wilson
plot contained in the MORMSF overlay of the X-Ray System of
^ f\
Crystallographic Programs. Of the 2350 recorded reflec-
tions, 70 are systematically extinct, leaving 2280 of which
1494 are designated observed reflections and 786 "less-
thans". Measured intensity varied from 0 to 2972 and
relative structure factors from .38 to 24.1. The
highest intensity reflection was 080 implying that the 8
planar benzene nuclei were arranged normal to be b-axis and
this is in accord with the magnitudes of the unit cell
dimensions. Table I contains the statistics and distribu-
tion for the normalized structure factors (E). Appendix A
is a listing of 2280 relative and normalized structure
factors .
TABLE 1.- STATISTICS AND DISTRIBUTION OF NORMALIZED STRUCTURE FACTORS
THEORETICAL EXPERIMENTAL
AVERAGE
VALUE
CENTRIC
ACENTRIC
1 El |
|E2 1
|E3j
|E4|
|E|
.798
.886
.706
.559
.706
.556
|E 2 |
1.000
1.000
1.000
1.021
1.000
1.018
jE 2 -
1|
.968
.736
1.060
1.356
1.061
1.354
|E | GT.
3.0
.27
.01
12
■ 51
43
1.87
8
• 33
38
1.67
| E | GT.
2.5
1.24
.19
34
1.45
76
3-32
33
1.45
74
3.25
| E | GT.
2.0
4.55
1.83
110
4.77
l6l
7.02
108
4.72
160
6.97
| E | GT.
1.8
7-19
3.92
165
7.20
227
9.87
172
7.51
215
9.38
jE | GT.
1.6
10.96
7.73
262
11.48
303
13-19
260
11.39
287
12.54
| E | GT.
1.4
16.15
14.09
377
16.51
369
16.09
368
16.15
355
15-46
| E | GT.
1.2
23.01
23.69
531
23-26
466
20.34
533
23.37
457
19.96
J E | GT.
1.0
31.73
36.79
724
31-71
593
25.94
722
31.66
588
25.74
|E| GT.
0.0
100.00
100.00
2280
100.00
2280
100.00
2280
100.00
2280
100.00
Note: | El
is calculated
with an
overall
scale factor while | E2 |
is
calculated with scale factors representative of different intervals of
sin 2 0/1 . | E3 | and |E4| are | El | and |E2j, respectively, with
anisotropic corrections applied. Further information is contained in
Appendix A.
78
Before the X-Ray System of Crystallographic Programs
(CRYSPAK) became available in this laboratory a series of
programs, including those for data reduction, Wilson plot-
Zero Moment Test, Fourier and Patterson Map, were written.
The data reduction program contained the correction for
monochromator angle to the Lorentz and polarization correc-
tions.^^ The result of the Zero Moment Test^, which in-
volves the determination of the fraction, N(Z), of the re-
flections less than a specified fraction of the average
intensity and which is based upon the fact that centrosym-
metric crystals tend to have more weak or unobserved reflec-
tions than noncentrosymmetric ones, is shown in Figure 31
along with the theoretical distributions. It is estimated
that the calculated distribution of intensities more nearly
matches that of the theoretical curve for the centrosymmetric
case .
The in-house data reduction program generated the
following statistics and distribution of normalized struc-
ture factor information as compared to the CRYSPAK generated
information in Table I:
A B
Average value of )E| ,6ll .688
Average value of |e 2 - l| .942 .896
80
A B
E|
GT.
1.0
25.00
24.11
E|
GT.
2.0
2.50
2.34
E|
GT.
3.0
.30
• 30
A = zero intensity data left as zero
B = zero intensity data expressed as
W 3 - 0 (ref - 37)
The general implication of the above, coupled with Table I,
is that the data possesses a centric distribution or perhaps
h n
even hypercentric distribution , the latter conclusion
being challenged by the zero moment test (Figure 31),
Preliminary to the use of direct methods, a
mechanized trial-and-error scheme based upon a modified
4l
ORFLS program was employed. As mentioned previously,
there is reason to believe that at least one of the six-
membered rings was parallel, or almost so, to the ac
plane. The subset of hOl data was used to find the mini-
mum residual position for a ring, oriented with respect to
the x-axis, in this plane. The minimum residual positions
of arbitrarily oriented rings in ac space are shown in
81
figure 32. The other half of the cell face is produced by
the Indicated centers. The minimum residual obtained in
xyz space, using the fact that the origin of this space
group can be moved to any center to reduce the computation.
for
the rings
taken
pairwiSe
, is
for the
following
position
la ■
- .00747
.07825
. 84825
lb
. 24267
.19429
• 59741
2a
.02840
.07825
. 64477
2b
. 27854
.19429
.39393
3a
.13812
. 07825
. 64477
3b
. 38826
.19429
.39393
4a
. 21199
. 07825
. 84825
4b
.46213
.19429
.59741
5a
.17612
.07825
1.05173
5b
.42626
. 19429
.80089
6a
. 06640
.07825
1.05173
6b
. 31654
.19429
.80089
Application of the two-fold screw and the n -glide would
spread eight rings in a sensible manner along the long
y-axis based upon the measured minimum residual positions
at y * .07825 and .19429. Unfortunately, this trial struc-
ture, representing 12/32 of the whole, failed to refine with
application of the standard Fourier methods; however, the
ring at y = .19429 did re-orient with respect to the x
and y axes such as to be recognizable in this new position
in various direct methods E-maps. Also, the general drift
of matter in the E-maps corresponds to that observed in this
trial and error porcess by molecules a and b.
1/2 X
Figure 32.- Minimum residual rings in clc. plane.
CD
ro
83
The centrosymmetric direct methods programs used were
the PHASE overlay of CRYSPAK and the LONGS ^ 2 multiple solu-
tion computer program, based on the reiterative application
of Sayre's equation. After much variation of the para-
meters of the various direct methods programs similar E-maps
were obtained. All calculations from intensity data to
final E-maps for the CRYSPAK study were made with the vari-
ous overlayed programs of CRYSPAK while all calculations
with the exception of the LONGS phasing for the LONGS study
were with in-house written programs. Rings taken from the
two independent studies are listed below:
CRYSPAK LONGS
lc
.26542
. 20947
>57222
1L
.26486
. 20000
• 53526
2 c
>33232
.19087
. 38889
2L
. 32187
.20074
.37731
3c
.44781
>20333
. 51006
3L
.43849
.22785
. 49949
4c
.48373
.19855
.72756
4L
. 48333
. 20833
.72917
5c
■•43133
.20128
. 866 77
5L
.41814
.19167
. 84105
6 c
.31833
.19776
. 78312
6 L
. 29461
.22346
.76786
The coincidence of a ring at y * .20 between the direct
methods and the trlal-and-error method was encouraging;
however, the E-maps suggested that the other molecule
(y ~ > 08 ) was not parallel to the ac. plane but was roughly
84
parallel to the y-axis, although oriented in x and z along
the drift line of molecules a and b of the trial-and-error
calculation. This molecule apparently extended from
y - .06 almost up to the one at if * .20. This would make
chemical sense in that an infinite chain of alternating acid
and base parts would extend through the material in proper
position to "zip" up to form polymer. It was also presumed
that this lower (in y ) molecule was a pyromellitic ester
making the molecule at y * ,20 a phenylene diamine.
Coordinates of the nuclear carbon atoms of the lower
molecule » taken from the CRYSPAK f-map are given below along
with those of the four nuclear-bonded side chain carbons:
PI
. 84917
.16726
1.03125
P2
.7691 9
.13402
1.05704
C 2
.69167
.15942 1.13237
P3
.76413
. 08956
1. 02431
C3
.69769
.06250 1.15972
P4
.83199
.05951
.94384
P5
.91649
.08686
. 88715
C5
.97911
.06235 .69514
P 6
. 89896
.13440
. 84954
C 6
.97193
.17622 .71278
These together with the upper molecule would refine with
ORFLS least squares to a residual of about .4. This is
indicative of much error in the trial structure.
85
The regions of the E-maps where the two molecules were
chosen presented a multiplicity of choices for benzene rings,
overlaping, with the apex of one ring in the center of
another while sharing two other carbons. The geometry of
the positions of the two nitrogens in the upper molecule
and the 4 carbons in the lower molecular fell in with the
overlaping pattern. Calculations of the residual for a
large variety of alternate rings failed to provide a better
choice of trial structure. Use of the TANGEN overlay of
CRYSPAK, which allows biasing of the sign determination by
specifying certain signs from a structure factor calculation
from atom input, only produced substantially similar E-maps
at best. Choices of nitrogen atoms for the upper molecule
could not be made because of lack of sensitivity of the
residual calculation and the ambiguity of the ring locations.
Atom locations for the ester and acid oxygen and carbon atoms
could be made in reasonable positions, and did lower the
residual, but did not refine satisfactorily. The answer
appeared to lie in the recently discovered fact that E-maps
which fail to produce refineable trial structures often
yield a correct . asymmetric unit, but one incorrectly aligned
_ 4-w < 44,45,46
to the origin. * *
To detach the calculation from a choice of origin, an
extra quadrant of data was generated by use of the monoclinic
86
mirror and calculations begun , also using the TANGEN over-
lay, in the space group, PI. Groups of atoms, rings, pairs
of rings, and alternates were all input. An input ring, in
addition to itself would produce its shifted alternate,
both in the input volume and in volumes produced by inher-
ent symmetry operations. It was evident that the data con-
tained inherent n-glide planes and screw axes, shifted
slightly, but basically as had been presumed. Since alter-
nate, overlayed rings, were always produced and since least
squares proved too insensitive to discriminate between them
the problem proved intractable within the context of the
available resources.
The implication of this study is that the asymmetric
unit contains a pyromellltic acid-ester and a phenylene
diamine molecule, roughly as defined by the given coordi-
nates, with molecular relationships within the unit being
approximate, but descriptive, but with the relationship of
the unit pair to the origin being unknown.
87
CHAPTER IV
CONCLUSION
The meta and para starting materials (phenylene dia-
mine and di-isopropyl ester of pyromellitic acid) appear
not to be salts in the unannealed solid state. However,
there is evidence for a partial ionization of the para isomer,
which may explain the observation of a more rapid initial
imidization for this material.
While there is no clear evidence for the involvement of
an amide stage, there is evidence of the possible participa-
tion of a salt intermediate. The use of evacuated sealed
tubes may be a way of obtaining the optimum temperature of
annealing for the Imidization without loss of needed mate-
rial before it has had the time to undergo the required
solid state rearrangement.
The reaction which appears to be essentially complete
after 3 days, as judged by water/alcohol loss, does not
yield the desired infrared spectra of the imide polymer,
implying the necessity of longer annealing times and higher
temperatures for the purpose of solid state rearrangement.
At the lower temperature (130°C) the chemical reaction
appears to be governed by a parabolic diffusion rate. A
comparison of the time-temperature data for
the onset of
88
loss of the first and second DTA endotherms with Infrared
spectral data denoting the appearance of definite imlde bands
and complete loss of ester character follows for the open
tube specimens:
COMPLETE
^ LOSS OP FIRST LOSS OP SECOND IMIDE LOSS
TEMP . 0
C ENDOTHERM
ENDOTHERM
BANDS -3000cm 1
PARA
120
130
72-120
hrs .
140
48-72
hrs .
X*
150
<24
hrs .
X
160
<24
hrs .
X
170
<24
hrs .
X
META
120
130
72-120
hrs .
mo
48-72
hrs .
150
<24
hrs .
160
<24
hrs .
X
170
<24
hrs .
X
X X
*Observed
Through
the use of powder
X^ray diffrac tome try it has
been
established that
the material, which
infrared analysis
has shown to contain bands characteristic of the imlde link-
age, has been polymerized in the solid state to a form
Page intentionally left blank
Base Acid Base Acid Base
Figure 33.- Representation of molecular orientation of acid and base parts of
precursor salt.
UD
o
91
REFERENCES
1. Charlesby, A.: Atomic Radiation and Polymers . Pergamon
Press (New York}", I960 .
2. Pezdirtz, G. F. : Polymers for Spacecraft. Modern
Plastics, vol. 40, no. 12, Aug. 1963, pp. 123-128,
132-134.
3. Kelble, J. M. , and Bernados, J. E.: High Temperature
Nonmetallic Materials. Aerospace Eng., vol. 22,
no. 1, Jan. 1963 , PP • 56-75-
4. Marvel, C. S.: Polyaromatic Heterocycles. Am. Chem.
Soc . Polymer Preprints, vol. 5, no. 1, Apr. 1964,
pp. 167-177.
5. Bilot, N. , and Rose, K. L.: High Temperature Electri-
cal Wire Coatings. AFML-TR-69-111 , Part II. Aug.
1970.
6. Arvay , E. A., and Aponyi, T. J.: The Development of
High Temperature Stable Polyimide Structural
Adhesives. AFML-TR-71-3 . Apr. 1971.
7. Campbell, M., and Hopkins, V.: Development of
Polyimide Bonded Solid Lubricants. Lubrication
Engineering, vol. 23, July 1967 , pp. 288-294.
8. Standage, A. E., and Turner, W. N. : A High-Temperature
Polyimide Reinforced with Silica Fiber. Journal of
Materials Science. Vol. 2, Mar. 1967 , pp . 103-111,
9. Stein, B. A., and Pride, R. A.: Effects of 450°F and
600°F Exposures on the Mechanical Properties of
Polyimide/Glass-Fiber Honeycomb Sandwiches and
Laminated Beams. American Institute of Aeronautics,
Aerospace and Astronautics, Aerospace Sciences
Meeting, 5th, New York, Jan. 23-26, 1967 .
10. Flory, P. J.: Principles of Polymer Chemistry .
Cornell University Press (Ithaca, New York), 1953.
Sorenson, W. A,, and Campbell, T. W. : Preparative
Methods of Polymer Chemistry , Interscience fNew York ) ,
1961, p. £(0"!
11 .
92
12. Bell, V. L. : Heteroaromatic Polymers via Salt
Intermediates. Polymer Letters, vol. 5> 1967,
pp. 941-9 46.
13. Lando, J., et al : Single-Crystal Character of Poly-
oxymethylene Prepared from Single Crystals of
Trioxane. Journal of Polymer Science, vol. 60,
Issure 169, 1962, pp. 524-526.
14. Okamura, S. , Hayashi, K. , and Nishii, M. : Polymer
Crystals Obtained by Radiation Polymerization of
Trioxane in Solid State, Journal of Polymer
Science, vol. 60, Issue 169, 1962, pp. 526-529.
15. Okamura, S., Hayashi, K. , and Kitanishi, Y. : Radiation-
Induced Solid-State Polymerization of Ring Compounds.
Journal of Polymer Science. vol. 58, 1962, pp.
925-953.
16. Hohlschuetter , V. : Z. anorg. Chem. vol. 105, 1918,
p. 1.
17. Morawetz, H. , et al: Topotactic Reactions in Organic
Crystals. Proceedings of the National Academy of
Sciences of the United States of America. vol. 49,
1963, PP. 789-793.
18. Cohen, M. D. , and Schmidt, G. M. J.: J. Chem. Soc.,
vol. II, 1964, p. 1996.
19. Young, P. R. : Effluent Analysis of Model Pyrrone
Compounds by Gas Chromatography. M. S. Thesis.
Virginia Polytechnic Institute, 1971.
20. Nakanishi, K. : Infrared Absorption Spectroscopy -
Practical , Holden-Day , Inc". (San "Francisco), 1962.
21. Leonard, N. J., and Owens, F. H. : J. Am. Chem. Soc.,
vol. 80, 1958, p. 6039.
22. Nakanishi, op, cit., p. 156.
23. Bellamy, L. J.: The Infra-red Spectra of Complex
Molecules, John Wiley & Sons, Inc. (New York) ~
19 £ 6 ~.
24. Ibid. , pp. 253-4.
25. Nakanishi, op. cit., p. 32.
93
26. Bellamy, op. cit., p. 163 .
27. Ibid. , p. 188.
28. Ibid. , pp. 170-1,
29. Ibid. , p. 174 .
30. Adrova, N. A., et al: Polyimides - A New Class of
Thermally Stable Polymers , Progress in Materials
Science Series, vol. 7, Technomic Publiching Co.,
Inc. (Stamford, Conn.), 1970.
a) Bellamy, op. cit.
b) Nishizaki, S., and Fukami, A.: Kogyo Kagaku
Zasshi, vol. 6 7 (3), 1963, pp. 382-6.
c) Ibid., 1964, pp. 474-8.
d) Freeman, J. H. , et al: Soc , Plastics Engrs.
Trans., vol. 5(2), 1962, pp. 216-21.
31. Bellamy, op. cit., p. 205.
32. Wakelin, J. H. , Virgin, H. S., and Crystal, E. : J.
Appl . Phys., vol. 30, 1959, P- 1654.
33. Statton, W. 0.: J. Appl. Polymer Sci., vol. 7, 1963,
p. 803.
34. Bosley, D. E. : J. Appl. Polymer Sci., vol. 8 , 1964,
p. 1521.
35. International Tables for X-Ray Crystallography , vol. I,
Kynock Press (Birmingham, England), 1965.
36 . Stewart, J. M. , Kundell, F. A., and Baldwin, J. C.:
The X-Ray System of Crystallographic Programs,
Computer Science Center, University of Maryland,
July 1970.
37. Hamilton, W. C.: Acta Cryst . , vol. 8 , 1955, p. 185 .
38. Azaroff, L. V.: Acta Cryst., vol. 8 , 1955, p. 701.
39- Howells, E. R. , Phillips, D. C. , and Rodgers, D.: Acta
Cryst., vol. 8 , 1950, p. 210.
40. Lipson, H. and Cochran, W. : The Determination of
Crystal Structures , G. Bell and Sons LTD (London),
1966 , p. 63 .
94
4l • Busing, W. R., Martin, K. 0., and Levy, H. A.: ORFLS ,
A Fortran Crystallographic Least-Squares Program,
0RNL-TM-305.
42. Long, R, E. : A Program for Phase Determination by
Reiterative Application of Sayre’s Equation, Doctoral
Dissertation (Part III), University of California,
Los Angeles, 1965 .
43- Sayre, D. : Acta Cryst.,vol. 5, 1952, pp. 60 - 65 .
44. Karle , J . : Acta Cryst., vol. B24, 1968 , pp. 182-186.
45. Karle, I. L. , and Karle, J. : Acta Cryst., vol. B27,
1971, pp. 1891-1898.
46. Karle, J.: Acta Cryst., vol. B28, 1972, pp . 820-824.
95
Appendix A
Listing of 2280 relative and normalized structure
Factors. (JCODE: 1, observed; 2 , less-thans.)
OVERALL TEMPERATURE FACTORS AND SCALES TO BE USED
IN THE CALCULATION OF NORMALIZED STRUCTURE FACTORS
LEAST SQUARES VALUES USED TO CALCULATE E(l) —
OVERALL ISOTROPIC T.F. B = 1.986 OVERALL FREL SCALE K = 15.9142
K - CURVE VALUES USED TO CALCULATE E(2) —
FREL FACTOR IF S2T/L2 FROM 0.00 TO .16 (INTERVAL = 0.01) DK =
15.5202 14.9352 14.3722 13.8305 13.3091
15.7871 20.7303 19.3444 20.3840 18.4953
22.4868 20.8119 21.8141 25.9284
ANISOTROPIC CORRECTIONS TO E(l) FOR CALCULATION OF E(3) —
DB11 DB12 DB13 DB22 DB23 DB33
-.00007 .00074 .00042 .00003 .00176 -.00213
ANTISOTROPIC CORRECTIONS TO E(2) FOR CALCULATION OF E(4) —
DB11 DB12 DB13 DB22 DB23 DB33
-.00167 .00185 -.01318 -.00038 .00694 -.02583
DK = .8464
1.3297
17.5702
19.4826
DK
.8340
DK
1.4289
SERIAL NO .
H
K
L
1
-10
0
0
2
-8
0
0
3
-6
0
0
4
-4
c
0
5
-2
0
0
6
2
0
0
7
4
0
0
8
6
0
0
9
8
0
0
10
10
0
0
11
11
1
0
12
10
1
0
13
9
1
0
14
8
1
0
15
7
1
0
16
6
1
0
17
5
1
0
18
4
1
0
19
3
1
0
20
2
1
0
21
l
1
0
22
-l
1
0
23
-2
1
0
24
-3
1
0
25
-4
1
0
26
-5
1
0
27
-6
1
0
28
-7
1
0
29
-8
1
0
30
-9
1
0
31
-10
1
0
32
-11
1
0
33
-11
2
0
34
-10
2
0
35
-9
2
0
36
-8
2
0
37
-7
2
0
38
-6
2
0
39
-5
2
0
40
-4
2
0
41
-3
2
0
42
-2
2
0
JCODE EPSILON S2T/12
1 2 .1611
l 2 .1031
1 2 .0580
1 2 .0258
1 2 .0064
1 2 .0064
1 2 .0258
1 2 .0580
2 2 .1031
1 2 .1611
2 l .1952
1 1 .1614
2 1 .1308
1 1 .1034
1 l .0792
1 1 .0583
1 1 .0406
2 1 .0261
2 1 .0143
1 1 .0067
1 1 .0019
1 1 .0019
2 1 .0067
1 1 .0148
1 I .0261
1 1 .0406
1 1 .0583
1 1 .0792
2 l .1034
1 1 .1308
l 1 .1614
^ 1 .1952
1 1 .1961
* 1 .1622
1 1 .1316
1 l .1042
1 1 .0801
1 1 .0591
1 l .0414
1 l .0269
1 1 .0156
* l .0075
FREL
/ El /
1.407
.714
1.231
.449
6.978
1.777
.690
.125
4.465
.623
3.720
.519
1.195
.216
5.741
1.462
0.000
0.000
1.407
.714
0.000
0.000
.813
.584
0.000
0.000
1.423
.735
1.142
.494
4.019
1.451
1.555
.472
0.000
0.000
0.000
0.000
.848
.168
1.257
.231
2.133
.392
0.000
0.000
1.268
.281
.979
.251
1.904
.578
4.809
1.736
2.285
.987
0.000
0.000
.762
.467
.813
.564
1.930
1.617
1.222
1.028
1.151
.831
1.080
.664
1.887
.980
1.620
.705
3.598
1.309
.553
.169
4.068
1.056
1.422
.319
3.510
.704
/ E2 /
/ E3 /
0.000
.699
.679
.440
2.524
1.747
.165
.123
.920
.614
.766
.511
.285
.213
2.076
1.437
0.000
0.000
0.000
.699
0.000
0.000
0.000
.5 76
0.000
0.000
1.113
.725
.810
.487
2.054
1.433
.582
.466
0.000
0.000
0.000
0.000
.248
.166
.350
.228
.594
.386
0.000
0.000
. 396
.277
.331
.247
.713
.566
2.457
1.699
1.619
.964
0.000
0.000
.742
.454
0.000
.567
0.000
1.566
0.000
.988
0.000
.801
1.059
.642
1.487
.950
1.148
.685
1.833
1.275
.214
.165
1.383
1.033
.446
.313
1.032
.69 2
/ E4 /
0.000
.656
2.554
.172
.982
.81 8
.299
2.101
0.000
0.000
0.000
0.000
0.000
1.090
.812
2.100
.605
0.000
0.000
.265
.376
.636
0.000
.416
.344
.728
2.458
1.582
0.000
.685
0.000
0.000
0.000
0.000
.960
1.392
1.106
1.811
.216
U424 ^
« 46 7
1*092
Page intentionally left blank
SERIAL NO .
H
K
L
JCOOE
EPS RON
S2T / L2
85
- 4
4
0
1
l
.0302
86
-3
4
0
l
1
.0189
87
-2
4
0
1
1
.0108
88
-1
4
0
1
1
.0060
89
0
4
0
1
2
.0044
90
1
4
0
1
l
.0060
91
2
4
0
l
1
.0108
92
3
4
0
1
1
.0189
93
4
4
0
1
1
.0302
9 *
5
4
0
1
1
.0447
95
6
4
0
1
1
.0624
96
7
4
0
2
1
.0833
97
8
4
0
1
1
.1075
90
9
4
0
1
1
.1349
99
10
4
0
2
1
.1655
100
11
4
0
2
1
.1994
101
11
5
0
2
1
.2018
102
10
5
0
2
1
.1680
103
9
5
0
1
1
.1374
104
8
5
0
l
1
.1100
105
7
5
0
l
1
.0858
106
6
5
0
2
1
.0649
107
5
5
0
1
1
.0472
108
4
5
0
1
1
.0327
109
3
5
0
1
1
.0214
110
2
5
0
1
1
.0133
111
1
5
0
2
1
.0085
112
-1
5
0
2
1
.0085
113
-2
5
0
l
l
.0133
114
-3
5
0
1
1
.0214
115
-4
5
0
1
1
.0327
116
-5
5
0
2
1
.0472
117
-6
5
0
2
1
.0649
118
-7
5
0
1
1
.0858
119
-8
5
0
l
1
.1100
120
-9
5
0
1
1
.1374
121
-10
5
0
2
1
.1680
122
-11
5
0
1
1
.2016
123
-11
6
0
2
1
.2049
124
-10
fc
0
2
1
.1710
125
-9
6
0
1
1
.1404
126
-3
6
c
1
1
.1130
FR6L
/ El /
/E 2 /
/E 3 /
/ E4 /
1.969
.532
.684
.518
.690
3.546
.831
1.140
.811
1.173
1.353
.205
.409
.279
.428
4.079
.800
1.183
.786
1.253
3.504
.474
. 70B
.467
.756
4.242
.832
1.231
*822
1.322
1.296
.272
.392
.270
.422
3.686
.864
1.186
.859
1.275
1.833
.495
.636
.493
.682
2 . 11C
.668
.924
.667
.982
.617
.231
.343
.232
.360
0.000
0.000
0.000
0.000
0.000
2.276
1.208
1.853
1.214
1.887
1.333
.835
1.343
.840
1.339
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.047
1.300
2.105
1.317
2.127
2.173
1.173
1*813
1.185
1.867
2.698
1.227
2.038
1.237
2.133
0.000
0.000
0.000
0.000
0.000
.991
.322
.473
.323
.506
1.942
.540
.684
.540
.736
.805
.195
.263
.194
.284
1.089
.237
.336
.235
.362
C.000
0.000
0.000
0.000
0.000
0.030
0.000
0.000
0.000
0.000
1.365
.297
.421
.291
.437
1.315
.318
.430
.310
.439
1.871
.520
.659
.505
.658
C.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.349
.614
1.019
.580
.937
2.402
1.296
2.004
1.235
1.780
.774
.491
.796
.466
.680
0.000
0.000
0.000
0.000
0.000
.873
.751
0.000
.705
0.000
0.000
0.000
0.000
0.000
0.000
C.OOC
0.000
0.000
0.000
0.000
-779
.503
.825
.474
.691
1.788
.984
1.582
.933
1.379
SERIAL NO .
H
K
L
127
-7
6
0
128
-6
6
0
129
-5
6
0
130
-4
6
0
131
-3
6
0
132
-2
6
0
133
-1
6
0
134
0
6
0
135
1
6
0
136
2
6
0
137
3
6
0
136
4
6
0
139
5
6
0
140
6
b
0
141
7
6
0
142
8
6
0
143
9
6
0
144
10
6
0
145
11
6
0
146
11
7
0
147
10
7
0
148
9
7
0
149
8
7
0
150
7
7
0
151
6
7
0
152
5
7
0
153
4
7
0
154
3
7
0
155
2
7
0
156
1
7
0
157
-1
7
0
158
-2
7
0
159
-3
7
0
160
-4
7
0
161
-5
7
0
162
-6
7
0
163
-7
7
0
164
-8
7
0
165
-9
7
0
166
-10
7
0
167
-11
7
0
168
-11
8
0
JCOOE EPSILON S2T/L2
1 1 .0868
1 t .0679
1 1 .0502
1 1 .0357
1 l .0244
1 1 .0163
1 1 .0115
2 Z .0099
1 1 .0115
1 1 .0163
1 1 .0244
1 1 .0357
2 1 .0502
2 1 .0679
1 1 .0688
2 1 .1130
1 1 .1404
1 l .1710
1 1 .2049
1 1 .2064
2 1 .1746
1 1 .1440
1 l .1166
1 1 .0924
2 1 .0715
1 1 .0537
2 1 .0392
1 1 .0260
1 1 .0199
1 1 .0151
l 1 .0151
1 1 .0199
2 1 .0280
2 1 .0392
1 1 .0537
2 1 .0715
1 1 .0924
1 1 .1166
2 1 .1440
1 1 .1746
1 1 .2084
I 1 .2126
FREL
/ El /
/ E2 /
/E3/
/E4/
4.620 2.150
1.672 .656
1.006 .337
3.564 1.026
1.443 .363
3.831 . 866
8.157 1.731
0.000 0.000
8.469 1.797
3.603 .816
1.273 .320
3.318 .955
0.000 0.000
0.000 0.000
4.670 2,173
C.000 0.000
2.698 1.741
1.851 1.392
1.753 1.529
1.247 1.103
0.000 0.000
1.922 1.265
3 . 45fe 1.945
1.823 .871
0.000 0.000
1.325 .459
0.000 0.000
• 7CS .185
1.514 .359
1.344 .299
1.590 .354
.913 .217
0.000 0.000
0.000 0.000
2.053 .711
0.000 0.000
.689 .329
3.757 2,114
0.000 0.000
1 a 666 1.274
2.924 2. see
1.537 1.383
3.605
2.048
1.117
.630
.526
.325
1.277
.993
.483
.353
1.209
.849
2.481
1.700
0.000
0.000
2.576
1.781
1.138
.812
.426
.320
1.186
.957
0.000
0.000
0.000
0.000
3.644
2.203
0.000
0.000
2.859
1.777
0.000
1.425
0 . 000
1.569
0.000
1.142
0.000
0.000
2.199
1.299
3.269
1.991
1.426
.888
0.000
0.000
.686
.464
0.000
0.000
.241
.186
.490
.358
.420
.297
.497
.348
.296
.212
0.000
0.000
0.000
0.000
1.066
.682
0.000
0.000
.539
.312
3.554
1.993
0.000
0.000
0.000
1.185
0.000
2 . 39JL
0.000
lo268
3.257
1.043
.508
1.260
.487
1.245
2.596
0.000
2.756
1.225
.459
1.262
0.000
0.000
3.846
0.000
2.925
0.000
0.000
0.000
0.000
2.277
3.437
1.517
0.000
.742
0.000
.261
.527
.448
.517
» 302
0.000
0.000
1.010
0.000
.478
3.036
0.060
0.000
60©
GoGOG VO
vo
SERIAL NO.
H
K
L
JCOOE
EPSILON
S2T/L2
16*5
-10
8
0
1
1
.1787
170
-9
8
0
1
1
.1481
171
-8
8
0
1
1
.1207
172
-7
8
0
2
l
.0965
173
-6
8
0
1
1
.0756
174
-5
8
0
1
1
.0579
175
-4
8
0
1
1
.0434
176
-3
8
0
1
l
.0321
177
-2
8
0
1
1
.0240
178
-1
8
0
1
I
.0192
179
0
8
0
l
2
.0176
180
1
8
0
1
1
.0192
181
2
e
0
1
1
.0240
182
3
8
0
1
I
.0321
183
4
8
0
2
1
.0434
184
5
8
0
1
1
.0579
185
6
8
0
1
1
.0756
186
7
8
0
1
1
.0965
187
8
8
0
2
1
.1207
1 88
9
8
0
1
1
.1481
189
10
8
0
1
1
.1787
190
11
8
0
1
1
.2126
191
11
9
0
1
1
.2172
192
10
9
0
1
1
.1834
193
9
9
0
2
1
.1528
194
8
9
0
1
1
.1254
195
7
9
0
2
1
.1012
196
6
9
0
2
1
.0803
197
5
9
0
1
1
.0625
198
4
9
0
1
1
.0480
199
3
9
0
2
1
.0368
200
2
9
0
1
1
.0287
201
1
9
0
1
1
.0239
2 02
-1
9
0
1
1
.0239
203
-2
9
0
1
1
.0287
204
-3
9
0
1
1
.0368
205
-4
9
0
1
1
.0480
206
-5
9
0
l
1
.0625
207
-6
9
0
1
1
.0803
208
-7
9
0
2
1
.1012
209
-8
9
0
2
1
.1254
210
-9
9
0
2
1
.1528
FUEL
/El/
/E2/
/E3/
/E4/
2.220
1.730
0.000
1.598
0.000
2.235
1.505
2.784
1.401
2.232
1.665
.961
1.669
.901
1.397
0.000
0.000
0.000
0.000
0.000
1.722
.723
1.225
.687
1.107
2.006
.721
1.026
.690
.959
1.769
.553
.738
.532
.710
3.653
1.009
1.283
.978
1.268
5.868
1.469
1.957
1.433
1.980
10.467
2.463
3.374
2.417
3.480
24.098
3.926
5.430
3.875
5.694
10.670
2.510
3.439
2.493
3.655
5.769
1.445
1.925
1.443
2.065
3.653
1.009
1.283
1.014
1.305
0.000
0.000
0.000
0.000
0.000
2.263
.814
1.158
.826
1.254
2.159
.906
1.536
.924
1.657
1.355
.687
1.072
.704
1.149
0.000
0.000
0.000
0.000
0.000
1.371
.922
1.705
.954
1.784
1.454
1 .133
0.000
1.177
0.000
1.255
1.129
0.000
1.179
0.000
2.964
2.717
0.000
2.861
0.000
2.239
1.781
0.000
1.866
0.000
O.OOC
0.000
0.000
0.000
0.000
1.065
.632
1.049
.655
1.123
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.953
.733
1.089
.747
1.183
1.286
.421
.632
.427
.686
0.000
0.000
0.000
0.000
0.000
1.736
.461
.598
.462
.640
2.243
.561
.747
.557
.791
2.948
.737
.982
.723
1.005
1.328
.352
.457
.343
.457
1.197
.349
.431
.337
.421
1.286
.421
.632
.405
.600
1.070
.401
.597
.383
.549
2.195
.956
1.559
.905
1.384
0.000
0.000
0.000
0.000
0.000
C.OOO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
100
SERIAL NO .
H
K
L
JCOOE
EPS I LON
S 2 T / L 2
211
-10
9
0
1
1
.1839
212
-11
9
0
1
1
.2172
213
-11
10
0
1
1
.2229
214
-10
10
0
2
1
.1886
215
-9
10
0
1
1
.1580
216
-8
10
0
1
1
.1306
217
-7
1 C
0
2
1
.1069
218
-6
10
0
1
l
.0655
219
-5
10
0
1
1
.0678
220
-9
10
0
1
1
.0533
221
-3
10
0
1
1
.0920
222
-2
10
0
1
1
.0339
223
-1
10
0
1
1
.0291
229
0
10
0
l
2
.0275
225
1
10
0
1
1
.0291
226
2
10
0
1
1
.0339
227
3
10
0
1
1
.0920
228
9
10
0
1
1
.0533
229
5
10
0
1
1
.0678
230
6
10
0
1
1
.0855
231
7
10
0
1
1
.1069
232
8
10
0
1
1
.1306
233
9
10
0
1
1
.1580
239
10
10
0
2
1
.1886
235
11
10
0
2
1
.2229
236
10
11
0
1
1
. 1999
237
9
11
0
1
1
.1638
238
8
11
0
1
1
.1369
239
7
11
0
1
1
.1122
290
6
11
0
2
1
.0913
291
5
11
0
1
1
.0735
292
9
11
0
2
1
.0590
293
3
11
0
1
1
.0978
299
2
11
0
2
1
.0397
295
1
11
0
1
1
.0399
296
-1
11
0
2
1
.0399
297
-2
11
0
1
1
.0397
298
-3
11
0
1
1
.0978
299
-9
11
0
1
1
.0590
2 50
-5
11
0
2
1
.0735
251
-6
11
0
2
1
.0913
252
-7
11
0
1
1
.1122
FREL
/El /
/ E 2 /
/E 3 /
/ E 4 /
2.538
2.020
0.000
1.853
0.000
.899
.819
0.000
.796
0.000
.901
.693
0.000
.761
0.000
0.000
0.000
0.000
0.000
C .000
1 .806
1.276
.979
1.173
.366
1.078
.659
1.097
.611
.840
0.000
0.000
0.000
0.000
0.000
3.231
1.966
2.932
1.382
2.120
2.609
1.023
1.732
.973
1.567
2.577
.866
1.390
.851
1.253
1 . 890
.567
.728
.597
.702
2.919
.029
1.036
.802
1.026
6 . 98 e
1.730
2.238
1.697
2.268
5.657
1.096
1.366
1.039
1.413
6.968
1.725
2.231
1.717
2.347
2.621
.790
.930
.792
.992
1.359
.916
. 538
.922
.579
2.956
1.019
1.537
1.035
1.667
1.786
.702
1.188
.718
1.293
3.691
1.679
2.777
1.725
3.023
1.293
.655
1.001
.679
1.006
2.156
1.318
2.095
1.375
2.258
1.615
1.191
.928
1.198
.457
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.219
1.017
0.000
1.083
0.000
2.582
1.877
0.000
1.989
0.000
.772
.987
.787
.512
.854
1.785
.977
1.555
1.019
1.695
0.000
0.000
0.000
0.000
0.000
.696
.266
.960
.279
.501
0.000
0,000
0.000
0.000
0.000
1.722
.563
.839
.569
.902
0.000
0.000
0.000
0.000
0.000
1.056
.301
.377
.300
.394
0.000
0.000
0.000
0.000
0.000
1.093
.329
.399
.320
.391
2.367
.773
1.153
.746
1.097
.608
.221
.310
.211
.285
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.919
1.595
2.539
1.985
2.082
101
SERIAL NO.
H
K
L
jcooe
EPSILON
S 2 T/L 2
253
-8
11
0
1
1
.1364
254
-9
11
0
1
1
.1638
255
-10
11
0
2
1
.1944
256
-10
12
0
2
1
.2007
257
-9
12
0
2
1
.1701
258
-8
12
0
1
1
.1427
259
-7
12
0
1
l
.1185
260
-6
12
0
1
1
.0976
261
-5
12
0
1
1
.0799
262
-4
12
0
1
1
.0654
263
-3
12
0
1
1
.0541
264
-2
12
0
1
1
.0460
265
-1
12
0
1
1
.0412
266
0
12
0
l
2
.0396
267
l
12
0
1
l
.0412
268
2
12
0
1
1
.0460
269
3
12
0
1
1
.0541
270
4
12
0
1
l
.0654
■271
5
12
0
2
1
.0799
272
6
12
0
1
1
.0976
2 73
7
12
0
1
1
.1185
2 74
8
12
0
2
1
.1427
275
9
12
0
1
1
.1701
2 76
10
12
0
2
1
.2007
277
10
13
0
2
1
.2076
278
9
13
0
1
1
.1770
279
8
13
0
2
1
.1496
280
7
13
0
2
1
.1254
281
6
13
0
2
1
.1044
282
5
13
0
2
1
.0867
283
4
13
0
I
1
.0722
2 84
3
13
0
1
1
.0609
285
2
13
0
2
1
.0529
286
1
13
0
1
1
.0481
287
-1
13
0
2
1
.0481
288
-2
13
0
1
1
.0529
289
-3
13
0
1
1
.0609
290
-4
13
0
2
1
.0722
291
-5
13
0
1
1
.0867
292
—6
13
0
1
l
.1044
293
-7
13
0
2
1
.1254
294
-8
13
0
2
1
.1496
FREL
/El/
/E 2 /
/E 3 /
/£ 4 /
1.092
.689
1.113
.636
.872
2.000
1.454
0.000
1.329
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.783
.511
.872
.469
.667
1.481
.843
1.450
.782
1.164
2.213
1.097
1.692
1.027
1.418
1.322
.574
.936
.542
.817
1.654
.636
1.017
.607
.922
2.721
.945
1.411
.910
1.322
2.898
.930
1.331
.904
1.286
1.656
.506
.635
.496
.631
2.784
.591
.719
.585
.731
2.405
.735
.923
.733
.959
2.898
.930
1.331
.937
1.405
3.252
1.129
1.686
1.146
1.806
2.254
.867
1.386
.888
1.500
0.000
0.000
0.000
0.000
0.000
2.618
1.298
2.001
1.351
2.190
2.565
1.461
2.512
1.532
2.751
0.000
0.000
0.000
0.000
0.000
.826
.619
0.000
.659
0.000
C .000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.183
-915
0.000
.981
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.700
.694
1.212
.713
1.309
1.062
.393
.559
.400
.596
0.000
0.000
0.000
0.000
0.000
2.073
.679
1.020
.679
1.051
0.000
0.000
0.000
0.000
0.000
.590
.203
.307
.197
.293
.867
.321
.456
.309
.421
0.000
0.000
0.000
0.000
0.000
1.353
.620
1.032
.584
.884
2.256
1.174
1.783
1.094
1.464
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
102
SERIAL NO. H K L JCODE EPSILON S2T/L2 FREL /EL / /E2/ /F3/ /E4/
295 -9 13 0 X 1 .1770 2.775 2.145 0.000 1.937 0.000
296 -10 13 0 l 1 .2076 1.761 1.553 0.000 1.387 0.000
297 -10 14 0 1 1 .2150 1.260 1.144 0.000 1.015 0.000
298 -9 14 0 1 1 .1844 1.895 1.514 0.000 1.360 0.000
299 -8 14 0 1 1 .1570 1.B02 1.267 .716 1.151 .521
300 -7 14 0 2 1 .1328 0.000 0.000 0.000 0.000 0.000
301 -6 14 0 1 1 .1119 .728 .398 .630 .369 .506
302 -5 14 0 l 1 .0941 1.549 .749 1.203 .704 1.010
303 -4 14 0 1 1 .0796 1.981 .859 1.404 .816 1.229
304 -3 14 0 l 1 .0684 3.691 1.458 2.503 1.400 2.275
305 -2 14 0 2 1 .0603 C.000 0.000 0.000 0.000 0.000
306 -1 14 0 1 1 .0555 5.976 2.103 3.086 2.063 2.994
307 0 14 0 l 2 .0539 1.569 .384 .576 .381 .574
308 1 14 0 1 1 .0555 6.241 2.196 3.222 2.198 3.292
309 2 14 0 1 1 .0603 1.618 .595 .831 .602 .867
310 3 14 0 1 1 .0684 2.686 1.061 1.821 1.083 1.933
311 4 14 0 l 1 .0796 1.477 .640 1.046 .660 1.127
312 5 14 0 1 1 .0941 1.549 .749 1.203 .780 1.309
313 6 14 0 l 1 .1119 .728 .398 .630 .418 .691
319 7 14 0 1 1 .1328 1.532 .948 1.517 1.006 1.671
315 8 14 0 2 1 .1570 O.OOC 0.000 0.000 0.000 0.000
316 9 14 0 2 1 .1844 C.000 0.000 0.000 0.000 0.000
317 10 14 0 1 1 .2150 1.992 1.809 0.000 1.973 0.000
318 10 15 0 1 1 .2230 1.561 1.464 0.000 1.609 0.000
319 9 15 0 1 1 .1923 2,717 2.248 0.000 2.447 0.000
320 8 15 0 1 1 .1650 1.637 1.196 0.000 1.290 0.000
321 7 15 0 1 1 .1408 1.102 .713 1.178 .761 1.300
322 6 15 0 1 1 .1198 .743 .426 .745 .451 .817
323 5 15 0 2 1 .1021 0.000 0.000 0.000 0.000 0.000
324 4 15 0 1 1 .0876 1.175 .542 .905 .561 .971
325 3 15 0 2 1 .0763 0.000 0.000 0.000 0.000 0.000
326 2 15 0 2 1 .0683 C.000 0.000 0.000 0.000 0.000
327 1 15 0 1 l .0634 5.546 2.098 3.194 2.104 3.233
328 -1 15 0 2 1 .0634 0.000 0.000 0.000 0.000 0.000
329 -2 15 0 2 l .0683 O.OOC 0.000 0.000 0.000 0.000
330 -3 15 0 1 1 .0763 1.305 .551 .928 .528 .829
331 -4 15 0 2 1 .0876 0.000 0.000 0.000 0.000 0.000
332 -5 15 0 2 1 .1021 0.000 0.000 0.000 0.000 0.000
333 -6 15 0 2 1 .1198 0.000 0.000 0.000 0.000 0.000
334 -7 15 0 2 1 .1408 O.OOC 0.000 0.000 0.000 0.000
335 -8 15 0 1 1 .1650 2.588 1.892 0.000 1.709 0.000
336 -9 15 0 1 1 .1923 1.718 1.422 0.000 1.269 0.000
103
SERIAL NO .
H
K
L
JCOOE
EPSILON
S2T / L2
337
-10
15
0
2
1
.2230
338
-9
16
0
1
1
.2009
339
-8
16
0
1
l
.1735
340
-7
16
0
1
1
.1493
341
-6
16
0
1
1
.1284
342
-5
16
0
1
1
.1106
343
-4
16
0
1
1
.0961
344
-3
16
0
1
1
.0849
345
-2
16
0
2
1
.0768
346
-1
16
0
1
1
.0720
347
0
16
0
1
2
.0704
348
1
16
0
1
1
.0720
349
2
16
0
1
1
.0768
350
3
16
0
l
1
.0849
351
4
16
0
2
1
.0961
352
5
16
0
1
1
.1106
353
6
16
0
2
1
.1284
354
7
16
0
2
1
.1493
355
8
16
0
1
1
.1735
356
9
16
0
2
1
.2009
357
9
17
0
1
1
.2099
358
8
17
0
2
1
.1825
359
7
17
0
1
1
.1584
360
6
17
0
1
1
.1374
361
5
17
0
1
1
.1197
362
4
17
0
1
1
.1052
363
3
17
0
2
1
.0939
364
2
17
0
2
1
.0859
365
1
17
0
2
1
.0810
366
-1
17
0
2
1
.0810
367
-2
17
0
2
1
.0859
368
-3
17
0
l
1
.0939
369
-4
17
0
1
1
.1052
370
-5
17
0
2
1
.1197
371
-6
17
0
2
1
.1374
372
-7
17
0
1
1
.1584
373
-8
17
0
1
1
.1825
374
-9
17
0
2
1
.2099
375
-9
18
0
1
1
.2196
376
-8
IS
0
1
1
.1922
377
-7
18
0
l
1
.1680
378
-6
18
0
1
1
.1470
FR6L
0.000
.871
1.859
1.587
.758
1.920
1.393
1.647
0.000
1.284
1 .276
.642
.654
2.230
o.ooc
1.026
0.000
0.000
.831
0.000
1.250
0.000
1.807
1.730
1.660
.715
0.000
0.000
0.000
O.OOC
C.000
2.076
1.430
0.000
0.000
9.664
1.690
0.000
1.794
2.104
.823
1.117
/ El /
0.000
.747
1.414
1.073
.458
1.040
.684
.744
0.000
.523
• 362
.261
.277
1.007
0.000
.556
C.000
0.000
.632
0.000
1.113
0.000
1.280
1.099
.953
.374
0.000
0.000
0.000
0.000
0.000
1.003
. 748
0.000
0.000
6.843
1.339
0.000
1.659
1 .739
.610
.747
/ E2 /
0.000
0.000
0.000
2.020
.738
1.622
1.073
1.231
0.000
.915
.644
.458
.465
1.667
0.000
.867
0.000
0.000
0.000
0.000
0.000
0.000
.389
1.780
1.661
. 569
0.000
0.000
0.000
0.000
0.000
1.614
1.138
0.000
0.000
2.080
0.000
0.000
0.000
0.000
0.000
1.360
/E 3 /
0.000
.663
1.272
.978
.422
.972
.647
.712
0.000
.513
.360
.263
.281
1.035
0.000
.584
0.000
0.000
.687
0.000
1.230
0.000
1.383
1.174
1.006
.390
0.000
0.000
0.000
0.000
0.000
.959
.706
0.000
0 .000
6.206
1.198
0.000
1.456
1.548
.551
.684
/ E4 /
0.000
0.000
C.000
1.474
.567
1.307
.904
1.081
0.000
.865
.627
.459
.477
1.749
0.000
.940
0.000
0.000
0.000
0.000
0.000
0.000
.430
1.946
1.794
.605
0.000
0.000
0.000
0.000
0.000
1.392
.941
0,000
0.000
1.480
0.000
0.000
0.000
0.000
0,000
.996
104
SERIAL NO
H
K L
JCODE EPSILON S2T/L2
3 79
-5
18
0
380
-9
18
0
381
-3
18
0
382
-2
18
0
383
-1
18
0
3 89
0
18
0
385
1
18
0
3 86
2
18
0
387
3
18
0
388
9
18
0
389
5
18
0
390
6
18
0
391
7
18
0
392
8
18
0
393
9
18
0
399
8
19
0
395
7
19
0
396
6
19
0
397
5
19
0
398
9
19
0
399
3
19
0
900
2
19
0
901
1
19
0
902
-1
19
0
903
-2
19
0
909
-3
19
0
905
-9
19
0
906
-5
19
0
907
-6
19
0
908
~7
19
0
909
-e
19
0
910
-8
20
0
911
-7
20
0
912
-6
20
0
913
-5
20
0
919
- 9
20
0
915
-3
20
0
916
-2
20
0
917
-1
20
0
918
0
20
0
919
1
20
0
920
2
20
0
1 1 .1293
2 1 >1148
1 1 .1035
1 1 .0955
1 1 .0907
1 2 .0890
1 1 .0907
1 1 .0955
1 1 .1035
2 1 .1198
2 l .1293
2 1 .1970
1 1 .1680
2 1 .1922
1 1 .2196
1 1 .2023
1 1 .1782
1 1 .1572
2 1 .1395
1 l .1250
1 1 .1137
2 l .1057
2 1 .1008
1 1 .1008
1 1 .1057
2 1 .1137
1 1 .1250
1 1 .1395
1 1 .1572
1 1 .1782
1 1 .2023
1 1 .2130
1 l .1889
1 1 .1679
2 1 .1502
1 1 .1357
2 1 .1299
1 1 .1169
1 1 .1115
1 2 .1099
1 1 .1115
i 1 .1169
FREl
/El/
/E2/
/E 3/
/£9/
1.075
.652
1.092
.606
.804
0.000
0.000
0.000
0.000
0.000
2.361
1.220
1.898
1.166
1.565
1.209
.588
.930
.570
.aai
2.790
1.292
2.159
1.268
1.980
2.810
.926
1.559
• 921
1.475
3.190
1.981
2.973
1.992
2.424
.695
.390
.537
.397
.541
2.757
1.925
2.158
1.979
2.231
0.000
0.000
0.000
0.000
0.000
C.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.926
1.057
0.000
1.199
0.000
0.000
0.000
0.000
0.000
0.000
2.690
2.989
0.000
2.772
0.000
1.512
1.305
0.000
1.996
0.000
3.023
2.399
0.000
2.570
0.000
.806
.568
.296
.613
.323
0.000
0.000
0.000
0.000
0.000
1.303
.771
1.286
.811
1.350
1.935
1.070
1.735
1.110
1.778
o.ooc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.579
.801
1.203
.787
1.086
1.899
.993
1.515
.961
1.313
0.000
0.000
0.000
0.000
0.000
1.509
.891
1.985
.837
1.176
1.099
.706
1.150
.659
.866
1.190
.803
.919
.733
.299
3.297
2.529
0.000
2.270
0.000
1.235
1 . 066
0.000
.999
0.000
1.53 8
1.387
0.000
1.223
0.000
3.629
2.953
0.000
2.696
0.000
.823
.610
0.000
.555
0.000
O.OOC
0.000
0.000
0.000
0.000
1.090
.666
1.106
.699
.856
C.000
0.000
0.000
0.000
0.000
1.276
.717
1.202
.699
1.023
1.929
1.099
1.655
1.030
1.469
2.611
.996
1.539
.993
1.420
1.626
.886
1.398
.897
1.337
.736
.919
.699
.925
.685
105
SERIAL NO .
H
K
L
JCQOE
EPSILON
421
3
20
0
1
1
422
4
20
0
1
1
423
5
20
0
1
1
424
6
20
0
1
1
425
7
20
0
1
1
426
8
20
0
2
1
427
8
21
0
1
1
428
7
21
0
1
1
429
6
21
0
1
1
430
5
21
0
2
1
431
4
21
0
1
1
432
3
21
0
1
1
433
2
21
0
2
1
434
1
21
0
2
1
435
-1
21
0
2
1
436
-2
21
0
2
1
437
-3
21
0
2
1
438
-4
21
0
2
1
439
-5
21
0
I
1
440
-6
21
0
1
1
441
-7
21
0
1
1
442
-8
21
0
1
1
443
-7
22
0
2
1
444
-6
22
0
1
I
445
'5
22
0
2
1
446
-4
22
0
1
1
447
-3
22
0
1
1
448
-2
22
0
1
1
449
- 1
22
0
1
1
450
0
22
0
2
2
451
1
22
0
1
1
452
2
22
0
1
1
453
3
22
0
2
1
454
4
22
0
1
1
455
5
22
0
2
1
456
6
22
0
1
1
457
7
22
0
2
1
458
7
23
0
1
1
459
6
23
0
1
1
460
5
23
0
2
1
461
4
23
0
2
1
462
3
23
0
2
1
S 2 T / L 2
FREL
/ El /
/ E 2 /
. / E 3 /
.1244
1.840
1.066
1.820
1.130
.1357
2 . 04 C
1.283
2.068
1.355
.1502
.795
.540
1.005
.578
.1679
1.164
.863
0.000
.937
.1889
4.438
3.617
0.000
3.982
.2130
Cl . 000
0.000
0.000
0.000
.2243
1.806
1.702
0.000
1.913
.2001
1.231
1.052
0.000
1.166
.1792
2.057
1.606
0.000
1.754
.1615
0.000
0.000
0.000
0.000
.1470
1.368
.914
1.663
.969
.1357
1.724
1.084
1.748
1.132
.1276
0.000
0.000
0.000
0.000
.1228
C .000
0.000
0.000
0.000
.1228
0.000
0.000
0.000
0.000
.1276
0.000
0.000
0.000
0.000
.1357
0.000
0.000
0.000
0.000
.1470
0.000
0.000
0.000
0.000
.1615
1.406
1.012
0.000
.933
.1792
.840
.656
0.000
.59 5
.2001
2.131
1.823
0.000
1.626
.2243
2.856
2.692
0.000
2.362
.2120
0.000
0.000
0.000
0 .000
.1910
2.268
1.866
0.000
1.687
.1733
0.000
0.000
0.000
0.000
.1588
1.981
1 . 4 C 6
.318
1.315
. 1475
• 2.092
1.402
2.571
1.333
.1395
1.346
.864
1.407
.836
.1346
1.088
.680
1.093
.660
.1330
0.000
0.000
0.000
0.000
.1346
1.332
.833
1.339
.846
.1395
1.346
. 864
1.407
.892
.1475
0.000
0.000
0.000
0.000
.1588
1 .618
1.148
.260
1.222
.1733
0.000
0.000
0.000
0.000
.1910
2.100
1.727
0.000
1.897
.2120
0.000
0.000
0.000
0.000
.2243
.903
.851
0.000
.955
.2034
.875
.758
0.000
.037
.1857
0.000
0.000
0.000
0.000
.1712
0.000
0.000
0.000
0.000
.1599
0.000
0.000
0.000
0.000
/ E 4 /
1.849
2.154
1.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.718
1.757
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.235
2.002
1.151
.936
0.000
1.244
1.355
0.000
.266
0.000
0.000
0.000
0.000
0.000
0.000
0 . 000
0.000
106
SERIAL NO
H K L
JCODE EPSILON S2T / L2
463
2
23
0
2
1
.1518
464
1
23
0
2
1
-1470
465
-1
23
0
2
1
.1470
466
-2
23
0
1
1
.1518
467
-3
23
0
2
1
.1599
46 8
-4
23
0
1
1
.1712
469
-5
23
0
2
1
.1857
470
-6
23
0
1
1
.2034
471
-7
23
0
1
1
.224 3
472
-6
24
0
2
1
.2163
473
-5
24
0
1
1
.1986
474
-4
24
0
1
1
.1841
475
-3
24
0
2
1
.1728
476
-2
24
0
2
1
.1647
477
-1
24
0
1
1
.1599
478
0
24
0
L
2
.1563
479
1
24
0
2
1
.1599
480
2
24
0
1
1
.1647
481
3
24
0
1
1
. 1728
482
4
24
0
2
1
.1841
483
5
24
0
2
1
. 1986
484
6
24
0
2
1
.2163
485
5
25
0
1
1
.2120
486
4
25
0
l
1
.1975
487
3
25
0
2
1
.1863
488
2
25
0
1
1
.1782
489
1
25
0
1
1
.1734
490
-1
25
0
1
1
.1734
491
-2
25
0
2
1
.1782
492
-3
25
0
l
1
.1863
493
-4
25
0
1
1
.1975
494
-5
25
0
l
l
.2120
495
-4
26
0
2
1
.2116
496
-3
26
0
2
l
.2003
497
-2
26
0
2
1
.1922
498
-1
26
0
1
1
.1874
499
0
26
0
1
2
.1858
500
1
26
0
1
1
.1874
501
2
26
0
2
1
.1922
502
3
26
0
2
1
.2003
503
4
26
0
2
1
.2116
504
3
27
0
1
1
.2148
FREE / El / / E2 / / E3 / / E4 /
0*000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1*128 .773 1.197 .747 .959
0.000 0.000 0.000 0.000 0.000
1 . 851 1.393 0.000 1.301 0.000
0.000 0.000 0.000 0.000 0.000
2.314 2.006 0.000 1.808 0.000
2 . 02C 1.903 0.000 1.685 0.000
O.OOC 0.000 0.000 0.000 0.000
1.227 1.043 0.000 .954 0.000
1-198 .956 0.000 .891 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
.811 .578 .011 .569 .009
1*807 .904 .239 .906 .249
0.000 0.000 0.000 0.000 0.000
1.829 1.336 0.000 1.386 0.000
2.349 1.781 0.000 1.800 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
O.OOC 0.000 0.000 0.000 0.000
.887 .796 0.000 .874 0.000
2.122 1.795 0.000 1.936 0.000
0.000 0.000 0.000 0.000 0.000
1.677 1.304 0.000 1.356 0.000
1.440 1.095 0.000 1.118 0.000
2.199 1.672 0.000 1.647 0.000
0.000 0.000 0.000 0.000 0.000
.850 .685 0.000 .650 0.000
.866 .733 0.000 .682 0.000
1.254 1.126 0.000 1.028 0.000
0.000 0.000 0.000 0.000 0.000
C.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
2.087 1.690 0.000 1.665 0.000
3.290 1.871 0.000 1.879 0.000
1.476 1.195 0.000 1.223 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.991 1.808 0.000 1.929 0.000
107
SERIAL NC.
H
K
L
JCOOE
EPSILON
S2T/L2
FREL
/El/
( E2/
/£ 3/
/E4/
505
2
27
0
1
1
.2068
1.523
1.339
0.000
1.401
0.000
506
1
27
0
2
1
.2019
0.000
0.000
0.000
0.000
0.000
507
-1
27
0
I
1
.2019
.873
.752
0.000
.742
0.000
500
-2
27
0
1
1
.2068
2.781
2.444
0.000
2.363
0.000
509
-3
27
0
1
1
.2148
1.781
1.617
0.000
1.532
0.000
510
-2
28
0
1
1
.2219
2.204
.2.058
0.000
1.989
0.000
511
-1
28
0
2
1
.2171
0.000
0.000
0.000
0.000
0.000
512
0
28
0
1
2
.2155
1.260
.811
0.000
.817
0.000
513
1
28
0
l
1
.2171
1.787
1.637
0.000
1.684
0.000
514
2
28
0
2
1
.2219
0.000
0.000
0.000
0.000
0.000
515
0
28
1
1
1
.2225
2.207
2.065
0.000
2.181
0.000
516
-1
28
1
1
1
.2228
1.274
1.194
0.000
1.235
0.000
517
-3
27
1
1
l
.2179
2.000
1.838
0.000
1.820
0.000
518
-2
27
l
1
1
.2112
1.534
1.372
0.000
1.387
0.000
519
-1
27
1
1
1
.2077
.881
.777
0.000
.801
0.000
520
0
27
1
2
1
.2074
0.000
0.000
0.000
0.000
0.000
521
1
27
1
2
l
.2104
0.000
0.000
0.000
0.000
0.000
522
2
27
1
1
1
.2166
1.996
1.825
0.000
2.001
0.000
523
4
26
1
2
1
.2241
C.000
0.000
0.000
0.000
0.000
524
3
26
1
1
1
.2114
2.50 5
2.244
0.000
2.495
0.000
525
2
26
l
2
1
.2020
c.ooo
0.000
0.000
0.000
0.000
526
1
26
1
2
1
. 1958
0.000
0.000
0.000
0.000
0.000
527
0
26
1
1
1
.1929
1.489
1.235
0.000
1.296
0.000
528
-1
26
1
1
1
.1931
1.216
1.010
0.000
1.039
0.000
529
-2
26
1
1
1
.1966
1.498
1.263
0.000
1.274
0.000
530
-3
26
1
1
1
.2033
.675
.758
0.000
.749
0.000
531
-4
26
l
1
1
.2132
1.539
1.388
0.000
1.345
0.000
532
-5
25
1
l
1
.2124
2.347
2.110
0.000
2.005
0.000
533
-4
25
1
1
1
.1992
1.229
1.047
0.000
1.014
0.000
534
-3
25
1
2
l
.1893
0.000
0.000
0.000
0.000
0.000
535
-2
25
l
1
1
.1826
2.07C
1.641
0.000
1.652
0.000
536
-1
25
1
1
1
.1791
1.455
1.135
0.000
1.165
0.000
537
C
25
1
1
1
.1788
1.454
1.133
0.000
1.186
0.000
536
1
25
1
2
1
.1816
0.000
0.000
0.000
0.000
0.000
539
2
25
1
2
1
.1880
0.000
0.000
0.000
0.000
0.000
540
3
25
l
2
1
.1974
0.000
0.000
0.000
0.000
0.000
541
4
25
1
1
1
.2100
1.768
1.575
0.000
1.773
0.000
542
5
24
1
1
1
.2124
1.537
1.382
0.000
1.574
0.000
543
4
24
1
1
1
.1966
1.498
1.262
0.000
1.413
0.000
544
3
24
1
1
1
.1039
1.198
.955
0.000
1.051
0.000
545
2
24
1
1
1
.1745
1.666
1.274
0.000
1.376
0.000
546 ,,
1
24
1
1
1
.1683
1.427
1.060
0.000
1.125
0.000
SERIAL NO .
H
K
L
547
0
24
1
548
-1
24
1
549
-~z
24
1
550
-3
24
1
551
-4
24
1
552
-5
24
1
553
-6
24
1
554
-7
23
1
555
-6
23
1
556
-5
23
1
557
-4
23
1
558
-3
23
1
559
-2
23
1
560
-1
23
1
561
0
23
1
562
1
23
1
563
2
23
1
564
3
23
1
565
4
23
1
566
5
23
1
567
6
23
1
568
6
22
1
569
5
22
1
570
4
22
1
571
3
22
l
572
2
22
1
573
l
22
1
574
0
22
1
575
-1
22
1
576
-2
22
1
577
-3
22
l
578
-4
22
1
579
-5
22
l
580
-6
22
1
581
-7
22
1
5 82
-8
21
1
583
-7
21
1
584
-6
21
1
585
-5
21
1
586
-4
21
1
587
-3
21
l
588
-2
21
1
JCODE
EPS ILON
S2T / L2
2
1
.1654
1
1
.1656
2
1
.1691
1
1
.1758
2
1
.1858
l
1
.1989
1
1
.2153
2
1
.2220
1
1
.2024
1
1
.1860
1
1
.1728
2
1
.1629
l
1
.1562
2
1
.1527
2
1
.1525
2
1
.1554
2
1
.1616
2
1
.1710
1
1
.1837
2
1
.1995
2
1
.2186
2
1
. 2062
1
1
'. lari ,;
1
1
.1713
2
1
.1567
1
1
.1492
1
1
.1431
2
1
.1401
l
1
.1404
2
1
. 1438
1
1
.1505
1
1
.1605
1
1
.1736
2
1
.1900
2
1
.2096
1
1
.2206
2
1
.1978
1
l
.1782
1
1
.1618
2
l
.1487
1
1
.1387
I
1
.1320
FREl / El / / E 2 / / E3 / /£ 4 /
0.000 0.000 0.000 0.000 0.000
1*159 . 85C 0.000 .870 0.000
0.000 0.000 0.000 0.000 0.000
1-181 .908 0.000 .896 0.000
0.000 0.000 0.000 0.000 0.000
1.504 1.280 0.000 1.217 0.000
1.543 1.404 0.000 1.310 Q.000
C.000 0.000 0.000 0.000 0.000
3.493 3.015 0.000 2.816 0.000
1.700 1.368 0.000 1.301 0.000
1.661 1.260 0.000 1.220 0.000
0.000 0.000 0.000 0.000 0.000
1.609 1.127 .802 1.131 .754
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
2.073 1.652 0.000 1.838 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.204 ,974 0.000 1.095 0.000
2.028 1.528 0.000 1.690 0.000
0.000 0.000 0.000 0.000 0.000
. 2.632 1.779 3.346 1.906 3.563
1.567 1.025 1.758 1.080 1.831
0.000 0.000 0.000 0.000 0.000
.779 .502 .824 .512 .812
0.000 O.OOC 0.000 0.000 0.000
.796 .542 .972 .534 .894
1.814 1 . 29B 0.000 1.257 0.000
1.860 1.416 0.000 1.348 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.270 1.180 0.000 1.069 0.000
0.000 0.000 0.000 0.000 0.000
3.933 3.057 0.000 2.863 0.000
1*150 .828 0.000 .789 0.000
0.000 0.000 0.000 0.000 0.000
1.098 .702 1.141 .691 1.066
1.873 1.154 1.842 1.155 1.780
109
SERIAL NO
H
K
L
JCODE EPSILON S2T / L2
589
-1
21
590
0
21
591
1
21
592
2
21
593
21
594
4
21
595
5
21
596
6
21
597
7
21
598
7
20
599
6
20
600
5
20
' 601
4
20
602
3
20
603
2
20
604
1
20
605
0
20
606
-1
20
607
-2
20
608
-3
20
609
-4
20
610
-5
20
611
-6
20
612
-7
20
613
-8
20
614
-8
19
615
-7
19
616
-6
19
617
-5
19
618
-4
19
619
-3
19
620
-2
19
621
-1
19
622
0
19
623
1
19
624
2
19
625
4
19
626
3
19
627
5
19
628
6
19
629
7
19
630
3
19
1 1 l
1 l l
1 l l
1 l l
12 I
1 2 I
l 2 1
l 1 I
1 2 1
1 l 1
1 l l
l 1 1
1 2 I
1 l 1
1 2 I
1 1 I
1 2 1
1 2 1
1 1 1
1 2 1
1 l 1
1 L 1
1 l 1
l 1 I
1 1 L
l 2 l
1 l 1
l 1 1
1 1 1
1 2 1
1 2 I
1 I I
1 1 1
1 1 I
1 l l
12 I
1 2 1
l 2 1
12 1
1 1 1
1 I 1
1 2 1
. 1285
.1283
.1312
.1374
.1468
.1595
.1753
.1944
.2167
.2054
.1831
. 1641
.1482
.1356
.1262
.1200
.1170
.1173
.1208
.1275
.1374
.1505
. 1669
.1865
.2093
.1986
. 1758
.1562
.1398
. 1267
.1167
.1100
.1066
.1063
.1093
.1154
.1375
.1249
.1533
.1724
.1947
.2202
FREL
/ El /
3.127
1.890
1.695
1.023
1.079
.662
.774
.491
0.000
0 .000
0.000
0.000
0.000
0.000
1.928
1.609
0.000
0.000
i .241
1.085
2.238
1.778
1.415
1.030
C.000
0.000
1.888
1.187
O.COO
0.000
.743
.427
0.000
0.000
O.OOC
0.000
2.604
1.550
C.000
0.000
1.730
1.098
1.779
1.211
1.837
1.355
1.20 3
.970
.883
.784
0.000
0.000
1.670
1.284
1.394
.976
3.112
2.002
O.OOC
0.000
0.000
0.000
2.049
1.106
1. 899
1.002
1.604
.845
1.446
.777
0.000
0.000
0.000
0.000
C.000
0.000
0.000
0.000
2.195
1.662
1.725
1.442
C.000
0.000
/ E2 /
/ E3 /
3.043
1.921
1.651
1.057
1.055
.695
.796
.524
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.823
0.000
0.000
0.000
1.238
0.000
2.001
0.000
1.142
0.000
0.000
1.912
1.278
0.000
0.000
.747
.447
0.000
0.000
0.000
0.000
2.692
1.549
0.000
0.000
1.779
1.064
2 . 174
1.154
0.000
1.271
0.000
. 896
0.000
.712
0.000
0.000
0.000
1.188
.697
.917
3.263
1.910
0.000
0.000
0.000
0.000
1.711
1.104
1.532
1.014
1.291
.868
1.198
.809
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.856
0.000
1.632
0.000
0.000
/ E4 /
3.033
1.691
1.107
.853
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.091
0.000
.789
0.000
0.000
2.634
0.000
1.627
1.912
0.000
0.000
0.000
0.000
0.000
.599
2.920
0.000
0.000
1.694
1.558
1.344
1.273
0.000
0.000
0.000
0.000
0.000 M
0.000
0.000
o
SERIAL NO
H
K
L
JCODE EPSILON S2T / L2
631
8
632
7
633
6
634
5
635
4
636
3
637
2
638
l
639
0
640
-1
641
-2
642
-3
643
-4
644
-5
645
-6
646
-7
647
-8
648
-9
649
-9
650
-8
651
-7
652
-6
653
-5
654
-4
655
-3
656
-2
657
-1
65 8
0
659
1
660
2
661
3
662
4
663
5
664
6
665
7
666
8
667
9
668
8
669
7
6 70
6
671
5
672
4
ia i 2
18 1 2
16 1 1
18 1 2
18 1 1
18 1 2
13 l 2
18 1 1
18 1 1
18 1 2
18 1 2
18 1 2
18 1 2
18 1 2
18 1 l
18 1 I
18 1 2
18 1 1
17 l 2
17 1 1
17 1 2
17 l 2
17 1 2
17 1 2
17 1 1
17 1 2
17 1 1
17 1 1
17 1 1
17 1 1
17 1 2
17 1 1
17 l 1
17 1 1
17 1 1
17 1 1
16 1 1
16 1 1
16 1 1
16 1 l
16 1 2
16 1 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
<2101
.1845
.1622
.1432
.1273
.1147
.1053
.0991
.0961
.0964
.0999
.1066
.1165
. 1297
.1460
.1656
.1884
.2145
.2049
.1780
.1560
.1364
.1200
.1069
.0970
.0903
.0868
.0865
.0895
.0957
.1051
.1177
.1336
.1526
.1749
■ 2004
.2201
.1914
.1659
.1436
• 1245
.1086
FREL
/El /
/ E2 /
/E 3 /
/ E4 /
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.628
1.175
0.000
1.303
0.000
0.000
0.000
0.000
0.000
0.000
1.853
1.112
1.812
1.201
2.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.703
.352
.533
.366
.570
1.207
.592
.929
.607
.974
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.788
.524
.941
.493
.823
1.419
1.041
0.000
.965
0.000
0.000
0.000
0.000
0.000
0.000
1.541
1.398
0.000
1.250
0.000
0.000
0.000
0.000
0.000
0.000
2.518
1.963
0.000
1.800
0.000
0.000
0.000
0.000
0.000
0.000
o.ooe
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.210
.597
.928
.587
.913
0.000
0.000
0.000
0.000
0.000
1.657
.759
1.265
.766
1.309
1.352
.618
1.029
.631
1.086
1.006
.844
1.410
.873
1.523
3.033
1.484
2.339
1.555
2.545
0.000
0.000
0.000
0.000
0.000
1.652
.936
1.595
1.006
1.763
1.085
.674
1 . OB 1
• 734
1.199
1.787
1.229
1.713
1.353
1.900
2.358
1.806
0.000
2.012
0.000
1.508
1.291
0.000
1.456
0.000
1.555
1.441
0.000
1.629
0.000
2.101
1.731
0.000
1.935
0.000
1.159
.851
0.000
.941
0.000
1.358
.891
1.540
.974
1.699
C.000
0.000
0.000
0.000
0.000
1.443
.772
1.188
.825
1.312
111
UAL NO.
H
K
L
673
3
16
1
679
2
16
1
675
1
16
1
676
0
16
1
677
-1
16
1
678
*2
16
1
679
-3
16
1
680
-9
16
1
681
-5
16
l
682
-6
16
1
683
-7
16
1
689
-8
16
1
685
-9
16
1
686
-10
15
1
687
-9
15
1
688
-8
15
1
689
-7
15
l
690
-6
15
1
691
-5
15
1
692
-9
15
1
693
-3
15
1
699
-2
15
1
695
-1
15
1
696
0
15
1
697
1
15
1
698
2
15
1
699
3
15
1
700
9
15
1
701
5
15
1
702
6
15
1
703
7
15
1
709
8
15
1
705
9
15
1
706
9
19
1
707
8
19
1
708
7
19
1
709
&
19
1
710
5
19
1
711
9
19
1
712
3
19
1
713
2
19
1
719
1
19
1
JCODE EPSILON S2T/L2
2 l .0960
1 1 .0866
1 1 .0809
1 1 .0779
1 1 .0777
1 1 .0812
1 I .0879
1 I .0978
2 1 .1110
2 l .1273
1 1 .1969
1 1 .1698
l 1 .1958
1 1 .2165
1 1 .1873
1 1 .1612
X l .1389
1 1 .1188
1 1 .1029
1 1 .0893
2 1 .0799
1 1 .0727
l 1 .0692
1 1 .0689
X 1 .0719
1 1 .0781
1 1 .0875
1 1 .1001
1 1 .1160
2 1 .1350
2 1 .1573
1 1 .1829
1 1 .2116
2 1 .2036
1 1 .1799
2 l .1999
1 1 .1271
X 1 .1080
2 1 .0921
1 1 .0795
X 1 .0701
2 1 .0639
FREL
/El/
/E2/
/E 3/
/**/
0.000
0.000
0.000
0.000
0.000
1.656
.758
1.262
.791
1.375
1.622
.707
1.159
.729
1.244
.927
.395
.658
.902
.699
3.652
1.559
2.593
1.569
2.704
1.757
.771
1.261
.766
1.287
1.176
.593
.908
.533
.904
1.566
.778
1.196
.759
1.157
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.368
.919
1.662
.852
1.449
1.651
1.235
0.000
1.136
0.000
.669
.72 5
0.000
.658
0.000
1.785
1.632
0.000
1.968
0.000
1.709
1.379
0.000
1.256
0.000
1.990
1.929
0.000
1.319
0.000
1.097
.700
1.137
.659
1.009
.791
.923
.730
.900
.672
1.587
.819
1.229
.780
1.169
1.369
.637
1.070
.617
1.048
0.000
0.000
0.000
0.000
0.000
2.659
1.087
1.892
1.079
1.947
9.116
1.637
2.863
1.699
3.005
1.799
.712
1.238
.729
1.321
2.723
1.108
1.991
1.139
2.098
1.319
.562
.932
.5 84
1.017
.678
.312
.521
.328
.573
1.727
.872
1.305
.926
1.438
l .695
.922
1.538
.990
1.693
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.895
.671
0.000
.744
0.000
1.981
1.776
0.000
1.989
0.000
0.000
0.000
0.000
0.000
0.000
1.869
1.927
0.000
1.568
0.000
0.000
0.000
0.000
0.000
0.000
1.069
.690
1.097
.690
1.140
1.765
.990
1.999
1.003
1.581
0.000
0^000
0.000
0.000
0.000
.939
.909
.662
.423
.725
1.686
.676
1.203
.700
1.313
0.000
0.000
0.000
0.000
0.000
112
UL NO .
H
K
L
715
0
14
1
716
-1
14
1
717
-2
14
1
718
-3
14
1
719
-4
14
1
720
-5
14
1
721
-6
14
1
722
-7
14
1
723
-8
14
1
724
-9
14
1
725
-10
14
1
726
-10
13
1
727
-9
13
1
728
-8
13
1
729
-7
13
1
730
-6
13
1
731
-5
13
l
732
-4
13
1
733
-3
13
1
734
-2
13
1
735
-1
13
1
736
0
13
1
737
1
13
l
738
2
13
1
739
3
13
1
740
4
13
1
741
5
13
1
742
6
13
1
743
7
13
1
744
3
13
1
745
9
13
1
746
10
12
1
747
9
12
1
748
8
12
1
749
7
12
1
750
6
12
1
751
5
12
1
752
4
12
1
753
3
12
1
754
2
12
1
755
1
12
1
756
0
12
1
JCOOf EPSILON S2T / L2
1 1 -OfcIO
1 1 .0612
1 l .0647
2 1 .0714
2 1 .0813
2 1 .0945
2 1 .1109
l 1 .1304
1 l .1533
1 1 .1793
2 1 .2086
2 1 .2011
1 1 .1719
2 1 .1458
1 1 .1230
1 1 .1034
1 1 .0871
1 1 .0739
l 1 .0640
l 1 .0573
1 1 .0538
1 1 .0535
2 1 .0565
1 1 .0627
1 1 .0721
2 1 .0847
2 1 .1006
1 1 .1196
2 1 .1419
2 1 .1675
2 1 .1962
1 1 .2213
1 1 .1893
2 l .1606
2 1 .1351
1 1 .1128
1 1 .0937
1 1 .0779
2 1 .0652
1 l .0558
1 1 .0496
1 1 .0467
FR6L /El/ / E2/ /E 3/ /64/
2.376 .879 1.250 .091 1.339
2.677 .993 1.422 .995 1.502
.882 .337 .530 .334 .550
C.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
2.016 1.231 1.956 1.153 1.766
.800 .552 .702 .511 .610
2.058 1.608 0.000 1.471 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.172 .885 0.000 .813 0.000
0.000 0.000 0.000 0.000 0.000
1.834 1.073 1.824 1.000 1.674
1*232 .637 .964 .605 .914
.958 .440 .733 .422 .716
.647 .268 .461 .260 .462
1.644 .625 .965 .613 .989
1.809 .647 .928 .641 .969
6.575 2.277 3.413 2.279 3.622
1.776 .614 .923 .620 .992
0.000 0.000 0.000 0.000 0.000
3.212 1.207 1.800 1.244 1.964
.642 .262 .458 .273 .501
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.819 1.043 1.817 1.117 1.963
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
.899 .838 0.000 .920 0.000
2.094 1.710 0.000 1.863 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.032 .567 .909 ,603 .974
1.383 .667 1.076 .703 1.164
1.608 .687 1.141 .718 1.242
0.000 0.000 0.000 0.000 0.000
1.467 .518 .756 .532 .824
1.924 .640 .997 .651 1.082
1.892 .611 .808 .616 .957
113
SEP I4L NO
H
K
L
JCODE EPSILON S2T / L2
757
-1
12
1
758
-2
12
1
759
-3
12
I
760
-4
12
1
761
-5
12
1
762
-6
12
1
763
-7
12
1
764
-8
12
l
765
-9
12
1
766
-10
12
1
767
-11
11
1
768
-10
11
1
769
-9
11
1
770
-8
11
1
771
-7
1 1
1
772
-6
11
1
773
-5
1 1
1
774
-4
11
1
775
-3
1 1
1
776
-2
11
1
777
-1
11
l
778
0
11
1
779
l
11
l
780
2
11
1
781
3
11
1
782
4
11
1
783
5
1 1
1
784
6
11
1
785
7
11
1
786
8
11
1
787
9
11
1
788
10
11
1
789
10
10
1
790
9
10
1
791
8
10
1
792
7
10
1
793
6
10
1
794
5
10
1
795
4
10
1
796
3
10
1
797
2
10
1
798
1
10
1
l 1 ,0469
1 l .0504
2 1 .0571
1 1 .0670
1 1 .0802
1 1 .0966
1 1 .1162
1 1 .1390
2 1 .1650
1 1 .1943
2 1 .2204
2 1 .1880
1 I .1587
l l .1327
1 1 .1098
l 1 .0902
1 1 .0739
1 1 .0607
1 1 .0508
1 1 .0441
1 1 .0406
2 1 .0403
1 1 .0433
1 1 .0495
1 1 .0589
2 1 .0715
1 1 .0874
2 1 .1065
2 1 .1288
2 1 .1543
2 1 .1830
2 1 .2150
2 l .2092
1 1 .1772
2 1 .1485
2 1 .1230
1 1 .1007
1 1 .0816
1 1 .0658
1 l .0531
1 l .0437
2 l .0375
FREE
/ El /
2.424
. 785
1.932
.648
0.000
0.000
1 .666
.650
1.146
.499
1.560
.768
2.082
1.168
1.098
. 7C3
0.000
0.000
1.49 3
1.245
0.000
0.000
0.000
0.000
2.557
1.814
3.063
1.894
1.916
1.033
3.421
1.608
3.422
1.416
5.877
2.170
3.598
1.211
5.120
1.611
5.740
1.742
C.OOC
0.000
3.955
1.235
2.319
.770
.859
.312
0.000
0.000
1.174
.540
C.000
0.000
0.000
0.000
o.ooc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.511
1.944
0.000
0.000
0.000
0.000
1.412
.716
1.330
.586
1.400
.541
1.563
.538
1.373
.431
0.000
0.000
/ E2 /
/ E3 /
1.148
.784
1.012
.641
0.000
0.000
1.083
.631
.813
.480
1.198
.731
1.954
1.100
1.144
.655
0.000
0.000
0.000
1.136
0.000
0.000
0.000
0.000
.442
1.680
3 . 02B
1.772
1.596
.975
2.699
1.533
2.437
1.362
3.065
2.107
1.883
1.186
2 . 194
1.593
2.153
1.738
0.000
0.000
1.646
1.253
1.196
.788
.438
.322
0.000
0.000
.902
.566
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.080
0.000
0.000
0.000
0.000
1.074
.751
.959
.610
.873
.559
.813
.552
.581
.439
0.000
0.000
/ E4 /
1.224
1.064
0.000
1.096
.804
1.152
1.821
1.030
0.000
0.000
0.000
0.000
.391
2.774
1.510
2.629
2.435
3.131
1.960
2.319
2.304
0.000
1.787
1.302
.476
0.000
.968
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.00 0
0.000
1.129
1.021
.938
.880 M
.630 M
0.000 Js '
SERIAL NO.
K
K
L
JCOOE
EPSILON
S2T/L2
FREL
/El/
/E2/
/E3/
/E4/
799
0
10
1
2
1
.0346
0.000
0.000
0.000
0.000
0.000
BOC
-l
10
1
1
l
.0348
1.293
.369
.461
.367
.495
801
-2
10
1
1
1
.0383
2.360
.699
.857
.690
.910
802
-3
10
1
1
1
.0.4 50
1.874
.596
.831
.584
.870
803
-4
10
1
1
1
.0549
1.886
.660
.975
.641
1.004
804
-5
10
1
2
1
.0681
O.OOC
0.000
0.000
0.000
0.000
805
-6
10
1
2
1
.0845
0.000
0.000
0.000
0.000
0.000
806
-7
10
1
2
l
.1041
0.000
0.000
0.000
0.000
0.000
807
-8
10
1
2
1
. 1269
0.000
0.000
0.000
0.000
0.000
80S
-9
10
1
1
1
.1529
1.385
.954
1.27 5
.887
1.147
809
-10
10
1
1
1
. 1822
2.670
2.113
0.000
1.940
0.000
810
-11
10
1
2
1
.2147
0.000
0.000
0.000
0.000
0.000
811
-11
9
1
2
1
. 2095
0.000
0.000
0.000
0.000
0.000
812
-10
9
1
2
1
.1770
0.000
0.000
0.000
0.000
0.000
813
-9
9
1
1
1
.1477
2.237
1.501
2.760
1.402
2.526
814
-8
9
1
1
l
.1217
1.055
.613
1.055
.577
.997
815
-7
9
1
1
1
.0988
2.433
1.217
1.848
1.156
1.797
816
-6
9
1
1
1
.0792
4.119
1.780
2.920
1.704
2.911
817
-5
9
1
2
1
.0629
0.000
0.000
0.000
0.000
0.000
818
-4
9
1
1
1
.049 7
3.850
1.282
2.001
1.247
2.078
819
-3
9
1
1
1
.0398
1.547
.466
.566
,456
.596
820
-2
9
1
l
1
.0331
.521
.146
.184
.144
.196
821
-1
9
1
1
1
.0296
1.518
.407
.525
• 4C5
.565
822
0
9
1
1
l
.0294
2.473
.662
.854
.662
.924
623
1
9
1
2
1
.0323
C.000
0.000
0.000
0.000
0.000
824
2
9
1
1
1
.0385
.542
.161
.197
.163
.213
825
3
9
1
1
1
.0479
1.990
.651
.975
.665
1.049
826
4
9
1
l
1
.0605
1.369
.505
.709
.519
.757
827
5
9
1
l
1
.0764
1.599
.675
1.137
.699
1.199
828
6
9
1
1
1
.0955
1.391
.679
1.074
.708
1.116
829
7
9
1
1
1
.1178
1.280
.726
1.237
.761
1.263
830
8
9
1
1
1
.1433
1.567
1.027
1.767
1.083
1.766
831
9
9
1
l
l
.1720
2.031
1.535
0.000
1.628
0.000
832
10
9
1
2
1
.2040
0.000
0.000
0.000
0.000
0.000
833
10
8
1
1
1
.1993
1.229
1.047
0.000
1.106
0.000
834
9
a
1
1
1
.1674
1.163
.860
0.000
.904
0.000
835
8
a
1
2
1
.1386
0.000
0.000
0.000
0.000
0.000
836
7
8
1
1
1
.1131
1.033
.569
.915
.592
.922
837
6
8
1
1
1
.0908
1.371
.647
1.079
.670
1.109
838
5
8
1
1
1
.0717
1.924
.782
1.372
.605
1.434
839
4
8
1
1
1
.0559
3.112
1.099
1.604
1.125
1.699
840
3
8
1
2
1
.0432
o.ooo
0.000
0.000
O.OOC
0.000
115
SERIAL NO .
841
842
843
844
845
846
847
848
849
850
851
. 852
853
854
855
856
857
858
859
860
861
862
863
864
865
866
867
868
869
870
871
872
873
874
875
876
877
876
879
880
881
882
H K L
2 8 1
1 8 1
0 8 1
-1 8 1
-2 8 1
-3 8 1
-4 8 1
-5 8 1
-6 8 1
-7 a 1
-8 8 1
-9 8 1
-10 8 1
-11 8 1
-11 7 1
-10 7 1
-9 7 1
-8 7 1
-7 7 1
-6 7 1
-5 7 1
-4 7 l
-3 7 1
-2 7 1
-17 1
0 7 1
1 7 1
2 7 1
3 7 1
4 7 1
5 7 1
6 7 1
7 7 1
8 7 1
9 7 1
10 7 1
10 6 1
9 6 1
8 6 1
7 6 1
6 6 1
5 6 1
JCODE
1
1
2
1
1
1
2
1
1
2
2
2
1
2
2
1
2
1
1
1
1
1
1
1
1
1
1
1
2
1
1
1
2
2
2
2
2
2
1
1
1
1
EPSILON
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
L
1
1
1
1
1
1
1
1
1
1
l
l
1
1
1
1
S 2 T / L 2
FREL
.0338
2.223
.0276
3.370
.0247
C .000
.0249
.684
.0284
1.324
.0351
.748
.0451
0.000
.0582
2.266
.0746
.64 8
.0942
0.000
.1170
0.000
.1430
0.000
.1723
.830
.2048
0.000
.2007
0.000
. 1682
1.164
.1389
0.000
.1129
2.528
.0901
2.901
.0705
1.277
.0541
9.425
.0409
3.165
.0310
3.198
.0243
2.883
.0208
9.99 8
.0206
9.976
.0235
2.859
.0297
3.121
.0391
0.000
.0517
1.437
.0676
.631
.0867
2.789
.1090
0.000
.1345
0.000
.1622
0.000
.1952
0.000
.1916
0.000
.1597
0.000
.1309
1.705
.1054
1.012
.0831
4.383
.0640
1.758
/ El /
/ E 2 /
.626
.788
.883
1.152
0.000
0.000
.173
.230
.350
.455
.214
.267
0.000
0.000
.818
1.158
.270
.462
0.000
0.000
0.000
0.000
0.000
0.000
.628
0.000
0.000
0.000
0.000
0.000
.864
0.000
0.000
0.000
1.390
2.231
1.362
2.291
.513
.910
3.273
4.887
.964
1.203
.872
1.116
.724
.964
2.402
3.260
2.389
3.247
.711
.950
. 839
1.081
0.000
0.000
.488
.750
.248
.418
1.277
2.126
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.044
1.662
.530
.807
1.952
3.213
.669
1.033
/ E 3 /
.634
.888
0.000
.172
.345
.210
0.000
.790
.259
0.000
0.000
0.000
.584
0.000
0.000
.809
0.000
1.319
1.301
.493
3.167
.939
.855
.714
2.381
2.381
.713
.845
0.000
.497
.253
1.312
0.000
0.000
0.000
0.000
0.000
0.000
1.075
.543
1.994
.680
/ E 4 /
.849
1.245
0.000
.247
.487
.283
0.000
1.191
.465
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.166
2.282
.927
5.065
1.265
1.187
1.034
3.513
3.504
1.024
1.158
0.000
.788
.432
2.158
0.000
0.000
0.000
0.000
0.000
0.000
1.582
.790
3.220
1.057
116
RIAL NO .
H
K
C
JC 0 D 6
EPSILON
S 21 YL 2
883
4
6
1
1
1
.0482
884
3
6
1
1
1
.0355
885
2
6
1
1
1
.0261
886
1
6
1
1
1
.0199
887
0
6
1
2
1
.0170
888
-1
6
1
1
1
.0172
889
-2
6
1
2
1
.0207
890
-3
6
1
1
1
.0274
891
-4
6
1
1
1
.0374
892
-5
6
1
1
1
.0505
893
-6
6
1
1
1
.0669
894
-7
6
1
1
1
.0865
895
-8
6
1
2
1
.1093
896
-9
6
1
2
1
.1353
897
-10
6
1
2
1
.1646
898
-11
6
1
l
1
. 1971
899
-11
5
l
2
1
.1941
900
-10
5
1
1
1
.1616
901
-9
5
1
1
1
.1323
902
-8
5
1
1
1
.1063
903
-7
5
1
1
1
.0835
904
-6
5
1
1
1
.0639
905
-5
5
1
1
1
.0475
906
-4
5
1
1
1
.0343
907
-3
5
1
1
1
.0244
908
-2
5
1
1
1
.0177
909
-1
5
1
2
1
.0142
910
0
5
1
1
1
.0140
911
1
5
1
1
1
.0169
912
2
5
1
1
1
.0231
913
3
5
1
1
1
.0325
914
4
5
1
1
1
.0451
915
5
5
1
2
1
.0610
916
6
5
1
1
1
.0801
917
7
5
1
2
l
.1024
918
8
5
1
1
1
.1279
919
9
5
1
1
1
.1566
920
10
5
1
1
1
.1886
921
11
5
1
2
1
.2238
922
11
4
1
1
l
.2213
923
10
4
1
2
1
.1861
924
9
4
1
1
1
.1542
FREL
✓ El /
✓ 62 /
/ E 3 /
/ E 4 /
1.287
.422
.636
.427
.661
1.187
.341
.425
.344
.448
.979
.252
.331
.253
.353
1.708
.406
.554
.406
.594
0.000
0.000
0.000
0.000
0.000
1.319
.303
.419
.300
.452
0.000
0.000
0.000
0.000
0.000
1.215
.317
.415
.311
.443
.538
.158
. 194
.154
.206
2.019
.678
1.057
.657
1.104
.690
.347
.576
.334
.591
2.242
1.025
1.706
.982
1.718
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.732
1.462
0.000
1.367
0.000
0.000
0.000
0.000
0.000
0.000
1.626
1.170
0.000
1.106
0.000
1.874
1.157
1.848
1.100
1.796
2.151
1.133
1.731
1.063
1.724
1.771
.791
1.303
.760
1.326
5.694
2.162
3.327
2.088
3.446
2.689
.076
1.298
.850
1.364
4.763
1.350
1.694
1.317
1.800
3.996
1.006
1.337
.985
1.431
10.792
2.490
3.442
2.451
3.702
0.000
0.000
0.000
0.000
0.000
5.667
1.244
1.757
1.235
1.888
3.964
.905
1.257
.902
1.343
4.671
1.156
1.548
1.156
1.639
1.159
.322
.408
.323
.427
1.496
.476
. 666
.480
.686
0.000
0.000
0.000
0.000
0.000
1.985
.863
1.407
.876
1.390
0.000
0.000
0.000
0.000
0.000
1.855
1.117
1.810
1.140
1.693
.805
.565
.356
.579
.323
1.207
.983
0.000
1.009
0.000
0.000
0.000
0.000
0.000
0.000
.899
.838
0.000
.853
0.000
0.000
0.000
0.000
0.000
0.000
1.388
.962
1.058
.977
.939
117
SERIAL NO
H
K L
JC ODE EPSILON S2T/L2
925
926
927
928
929
930
931
932
933
934
935
936
937
938
939
940
941
942
943
944
945
946
947
948
949
950
951
952
953
954
955
956
957
958
959
960
961
962
963
964
96 5
966
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l
l
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.1254
.0999
.0776
.0585
.0427
.0300
.0206
.0145
.0115
.0117
.0152
.0219
.0319
.0450
.0614
.0810
.1038
.1298
.1591
.1916
.1897
.1572
.1279
.1019
.0791
.0595
.0431
.0299
.0200
.0133
.0098
.0096
.0125
.0187
.0281
.0408
.0566
.0757
.0980
. 1235
.1522
.1842
FREL
✓El ✓
✓ € 2 /
✓E3/
✓ E4/
1.992
0.000
.927
1.820
6.229
2.382
0.000
4.624
0.000
1.055
2.626
1.460
1 .930
0.000
3.134
.938
2.137
0.000
2.141
.858
1.209
2.280
2.624
.708
1.142
3.106
0.000
6.692
2.962
6.044
8.672
.378
12.649
2.657
4.547
1.101
2.249
2.160
1.213
2.120
0.000
0.000
1.182
0.000
.395
.659
1.932
.643
0.000
1.022
0.000
.225
.586
.361
.532
0.000
1.164
*411
1.107
0.000
1.522
• 70S
.989
1.605
1.580
.362
.493
1.134
0.000
1.803
.704
1.750
1.798
.078
2.723
.621
1.199
.335
.800
.907
.603
1.244
0.000
0.000
1.963
0.000
.658
.929
2.532
.826
0.000
1.439
0.000
.321
.822
.486
.677
0.000
1.675
.672
1.677
0.000
.255
0.000
0.000
.846
2.560
.545
.809
1.580
0.000
2.320
.960
2.482
2.601
.113
3.879
.854
1.559
.415
1.156
1.536
.926
2.105
0.000
0.000
1.198
0.000
.399
.662
1.938
.643
0.000
1.015
0.000
.222
.577
.353
.519
0.000
1.127
.396
1.062
0.000
1.447
.670
.942
1.535
1.516
.349
.476
1.101
0.000
1.762
.690
1.721
1.773
.077
2.699
.617
1.194
.334
.800
.908
.606
1.250
0.000
0.000
1.803
0.000
.641
.927
2.579
*856
0.000
1.529
0.000
.346
.885
.522
.722
0*000
1.748
.690
1.690
0.000
.244
0.000
0.000
.825
2.553
.555
.839
1*660
0.000
2.483
1.032
2.668
2.789
*121
4.096
.890
1.600
.418
1.138
1.473
.862
1.997
0.000
0.000
118
SERIAL NO
H K L
JCODE EPSILON S2T/L2
967
11
3
1
968
11
2
1
969
10
2
1
970
9
2
1
971
8
2
1
972
7
2
1
973
6
2
1
974
5
2
1
975
4
2
1
976
3
2
1
977
2
2
1
978
1
2
1
979
0
2
1
980
-1
2
1
901
-2
2
1
982
-3
2
1
983
-4
2
1
984
-5
2
1
985
-6
2
1
986
-7
2
1
987
-8
2
1
988
-9
2
1
989
-10
2
l
990
-11
2
1
991
-12
2
1
992
-12
1
l
993
-11
1
1
994
-10
1
1
995
-9
1
1
996
-8
1
1
997
-7
1
1
998
-6
1
1
999
-5
1
1
1000
-4
1
1
1001
-3
1
1
1002
-2
1
1
1003
-1
1
1
1004
0
1
1
1005
l
l
1
1006
2
1
1
1007
3
1
1
1008
4
1
1
1 I .2194
2 1 .2180
2 1 .1828
1 1 .1509
2 l .1221
1 1 .0966
1 1 .0743
1 l .0552
1 1 .0394
1 1 .0267
1 1 .0173
2 1 .0112
1 1 .0082
1 l .0085
1 1 .0119
1 1 .0186
2 l .0286
1 1 .0417
1 1 .0581
2 l .0777
1 1 .1005
2 1 .1265
1 1 .1550
2 1 .1883
1 1 .2240
2 1 .2232
1 1 .1875
1 1 .1550
1 1 .1257
1 1 .0997
1 1 .0769
1 1 .0573
1 1 .0409
1 1 .0277
1 1 .0178
1 1 .0111
1 1 .0076
1 l .0074
1 1 .0103
1 1 .0165
1 l .0259
2 1 .0386
FREL
/El/
/E2/
/£ 3/
/E4/
1.268
1.172
0.000
L.183
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.126
.768
1.330
.766
1.131
0.000
0.000
0.000
0.000
0.000
2.516
1.239
1.932
1.235
1.767
3.239
1.345
2.306
1.339
2.176
1.791
.629
.925
.625
.898
.545
.163
. 199
.162
.198
1.776
.460
.604
.457
*613
7.005
1.609
2.228
1.593
2.303
0.000
0.000
0.000
0,000
0.000
1.092
.221
.323
.218
.343
.820
.167
.243
.164
.260
1.328
.263
.405
.279
.435
1.099
.257
.353
.252
.379
0.000
0.000
0.000
0.000
0.000
1.238
.380
.435
.371
.518
1.483
.534
.758
.520
.802
0.000
0.000
0.000
0.000
0.000
.706
.357
. 536
.346
.551
0.000
0.000
0.000
0.000
0.000
2.127
1.487
1.172
1.430
1.156
0.000
0.000
0.000
0.000
0.000
3.255
3.064
0.000
2.925
0.000
0.000
0.000
0.000
0.000
0.000
.852
.690
0.000
.665
0.000
2.124
1.479
1.396
1.429
1.395
2.717
1.615
2.674
1.565
2.728
1.400
.709
1.065
.688
1.105
2.265
.960
1.610
.935
1.693
1.348
.482
.692
.471
.735
4.802
1.462
1.822
1.429
1.950
3.722
.976
1.273
.956
1.368
5.782
1.336
1.846
1.311
1.983
2.915
.615
.884
.605
.947
.945
.190
.278
.187
.296
2.811
.563
.826
.554
.871
11.382
2.376
3.428
2.343
3.569
14.948
3.395
4.725
3.351
4.839
4.371
1.121
1.477
1.107
1.483
0.000
0.000
0.000
0.000
0.000
6TT
SERIAL NO.
H
K
L
1009
5
1
1
1010
6
1
1
1011
7
1
1
1012
8
1
1
1013
9
1
1
1014
10
1
1
1015
11
1
1
1016
11
0
1
1017
9
0
1
1018
7
0
1
1019
5
0
1
1020
3
0
1
1021
1
0
1
1022
-1
0
1
1023
-3
0
1
1024
-5
0
1
102 5
-7
0
1
1026
-9
0
1
1027
-11
0
1
1028
-10
0
2
1029
-8
0
2
1030
-6
0
2
1031
-4
0
2
1032
-2
0
2
1033
0
0
2
1034
2
0
2
1035
4
0
2
1036
6
0
2
1037
8
0
2
1038
10
0
2
1039
10
1
2
1040
9
1
2
1041
8
t
2
1042
7
1
2
1043
6
1
2
1044
5
1
2
1045
4
1
2
1046
3
1
2
1047
2
1
2
1048
1
1
2
1049
0
1
2
1050
-1
1
2
JCODE
EPSILON
S2T/L2
1
1
.0544
2
1
.0735
1
1
.0958
l
1
.1213
2
1
.1500
2
1
.1820
1
1
.2172
2
2
.2169
1
2
.1498
1
2
.0955
1
2
.0541
1
2
.0256
1
2
.0101
2
2
.0074
1
2
.0175
1
2
.0406
1
2
.0766
1
2
.1254
1
2
.1872
1
2
.1625
2
2
.1099
1
2
• 07C2
1
2
.0433
1
2
.0294
l
2
.0284
1
2
.0402
1
2
.0650
2
2
.1026
1
2
.1531
1
2
.216 5
1
1
.2168
1
1
.1835
1
l
.1534
2
1
.1265
1
1
.1029
1
1
.0824
1
1
.0652
1
1
.0513
1
l
.0405
1
1
.0330
1
1
.0286
2
1
.0276
PREL
/ El /
/ E 2 /
/ E 3 /
/ E 4 /
1.030
.359
0.000
0.000
.984
.482
1.054
.611
0.000
0.000
0.000
0.000
.894
.819
0.000
0.000
.794
.381
3.613
1.249
3.411
.838
2.924
.528
9.450
1.390
0.000
0.000
.442
.072
1.555
.334
2.263
.677
2.916
1.224
1.204
.689
4.073
2.080
0.000
0.000
3.607
1.023
1.370
.303
4.164
.788
7.145
1.336
1 .097
.234
5.617
1 .523
0.000
0.000
1.131
.552
1.785
1.154
1.786
1.635
1.692
1.347
.800
.553
0.000
0.000
1.740
.895
1.334
.591
.984
.340
3 . 7 C 1
1.251
1.903
.577
3.679
1.027
7.337
1.946
0.000
0.000
.534
.355
0.000
0.000
.759
.477
1.055
.604
o.ooo
0.000
0.000
0.000
0.000
.810
0.000
0.000
.721
.374
1.972
1.227
1.251
.824
.697
.520
2.008
1.367
0.000
0.000
.099
.071
.413
.327
1.137
.661
2.032
1.192
0.000
.668
0.000
2.001
0.000
0.000
1.819
.992
.404
.294
1.018
.769
1.735
1.305
.286
.229
2.410
1.491
0.000
0.000
.717
.540
0.000
1.129
0.000
1.616
0.000
1.332
.690
.546
0.000
0.000
1.353
.884
.971
.583
.541
.335
1.935
1.231
.711
.567
1.298
1.008
2.524
1.908
0.000
0.000
.510
0.000
.661
.913
0.000
0.000
0.000
0.000
.586
1.736
1.177
.692
2.073
0.000
.107
.663
1.206
2.096
0.000
0.000
0.000
1.968
.626
1.036
1.686
.262
2.050
0.000
.507
0.000
0.000
0.000
.501
0.000
1.082
.811
.670
1.742
.661
1.245
2.483 m
0.000 ro
SERIAL NO.
H
K
L
JCOOE
EPSILON
S2T/L2
1051
-2
1
2
2
1
.0297
1052
-3
1
2
1
1
.0350
1053
-4
1
2
1
1
.0436
1054
-5
1
2
2
l
.0554
1055
-6
1
2
2
1
.0704
1056
-7
1
2
2
1
.0887
1057
-8
l
2
2
1
.1101
1058
-9
1
2
1
1
.1348
1059
-10
l
2
2
l
.1627
1060
-11
1
2
1
i
.1939
1061
-11
2
2
1
1
.1947
1062
-10
2
2
1
1
.1636
1063
-9
2
2
2
1
.1357
1064
-8
2
2
l
L
.1110
1065
-7
2
2
1
1
.0895
1066
-6
2
2
l
1
.0713
1067
-5
2
2
1
1
.0562
1068
-4
2
2
1
1
.0444
1069
-3
2
2
1
1
.0359
1070
-2
2
2
1
1
,0305
1071
-1
2
2
1
1
.0284
1072
0
2
2
1
l
.0295
1073
1
2
2
1
l
.0338
1074
2
2
2
1
1
.0413
1075
3
2
2
1
1
.0521
1076
4
2
2
1
1
.0661
1077
5
2
2
1
1
.0833
1078
6
2
2
2
1
.1037
1079
7
2
2
1
I
.1273
1080
8
2
2
2
1
• 1542
1081
9
2
2
1
1
.1843
1082
10
2
2
l
1
.2176
1083
10
3
2
1
1
.2190
1084
9
3
2
2
1
.1857
1085
8
3
2
1
1
.1556
1086
7
3
2
1
1
.1287
1087
6
3
2
1
l
.1051
1088
5
3
2
1
1
.0646
1089
4
3
2
1
L
.0674
1090
3
3
2
1
1
.0535
1091
2
3
2
1
i
.0427
1092
1
3
2
1
1
.0352
FREL
/El/
/E2 /
/E3/
/E4/
0.000
0.000
0.000
0.000
0.000
2.048
.585
.731
.571
.763
2.097
.657
.883
.639
.933
0.000
0.000
0.000
0.000
a. ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.088
.681
1.096
.655
1.174
0.000
0.000
0.000
0.000
0.000
.861
.717
0.000
.685
0.000
1.725
1.442
0.000
1.371
0.000
1.999
1.452
0.000
1.386
0.000
0.000
0.000
0.000
0.000
0.000
2.179
1.183
1.853
1.138
1.989
.965
.451
.758
.435
.816
2.561
1.037
1.826
1.003
1.963
3.287
1.165
1.692
1.131
1.811
5.343
1.688
2.318
1.643
2.463
6.019
1.736
2.158
1.695
2.268
.510
.138
• 177
.135
.184
. 667
.229
.298
.225
.303
3.389
.908
1.172
.894
1.168
4.222
1.189
1.497
1.173
1.456
.552
.169
.213
.167
.202
3.219
1.097
1.679
1.086
1.540
3.007
1.164
1.893
1.155
1.678
1.770
.789
1.300
.704
1.109
0.000
0.000
0.000
0.000
0.000
1.691
1.015
1.654
1.011
1.296
0.000
0.000
0.000
0.000
0.000
1.468
1.173
0.000
1.171
0.000
2.000
1.836
0.000
1.035
0.000
.896
.827
0.000
.836
0.000
0.000
0.000
0.000
0.000
0.000
3.113
2.174
1.803
2.189
1.383
2.399
1.451
2.333
1.459
1.874
1.011
.528
.804
.530
.674
3.426
1.544
2.555
1.546
2.227
4.677
1.832
3.079
1.830
2.782
1.674
.578
.870
.576
.812
2.672
.829
1.087
.824
1.045
6.416
1.936
2.292
1.818
2.260
121
SERIAL NO.
1093
1094
1095
1096
1097
1098
1099
1100
1101
1102
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
1113
1114
1115
1116
1117
1118
1119
1120
1121
1122
1123
1124
1125
1126
1127
1128
1129
1130
1131
1132
1133
1134
JCOOE
2
1
1
1
2
1
1
1
1
1
1
1
1
1
2
2
2
1
2
1
1
1
2
2
1
1
1
1
2
2
1
2
1
1
2
1
1
1
1
1
1
1
EPS ICON
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l
1
1
1
1
l
1
1
1
1
1
1
1
1
1
1
1
1
S 2 T / L 2
.0308
« CZ 98
.0319
.0372
.0458
.0576
.0726
. 09 C 9
.1123
.1370
.1649
. 1961
.1980
.1669
.1390
.1143
.0928
.0746
.0595
.0477
.0392
.0338
.0317
.0328
.0371
.0446
.0554
.0694
.0866
.1070
.1306
.1575
.1876
.2209
.2234
.1901
.1600
.1331
.1095
.0890
.0718
.0578
FREL
0.000
3.039
1.631
3.179
0.000
1.351
.644
1.533
1.031
.773
1.157
.864
3.126
1.643
0.000
C .000
0.000
1.123
0.000
3.764
4.561
.741
0.000
0.000
4.740
1 . S 7 C
3.635
1.101
0.000
0.000
1.867
0.000
3.409
1.557
C .000
2.096
1.986
3.341
1.914
1.92 8
.642
6.456
f El/
/E2/
/£ 3 /
/E4/
0.000
0.000
.817
1.052
.450
.572
.931
1.148
0.000
0.000
.485
.69 2
.264
.459
.724
1.207
.565
.900
.490
.793
.846
0.000
.727
0.000
2.650
0.000
1.212
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.467
.799
0.000
0.000
1.229
1 . B 33
1.403
1.809
.209
.263
0.000
0.000
0.000
0.000
1 .385
1.710
.592
.817
1.278
1.877
.438
.770
0.000
0.000
0.000
0.000
1.142
1.815
0.000
0.000
2.763
0.000
1.448
0.000
0.000
0.000
1.718
0.000
1 .417
.004
2.071
3.316
1.029
1.588
.898
1.507
.261
.457
2.322
3.304
0.000
0.000
.804
1.082
.441
.596
.910
1.214
0.000
0.000
.471
.743
.255
.494
.698
1.297
.542
.964
.468
.842
.805
0.000
.688
0.000
2.497
0.000
1.148
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.452
.860
0.000
0.000
1.199
1.963
1.452
1.923
.205
.276
0.000
0.000
0.000
0.000
1.378
1.709
.591
.797
1.280
1.782
.441
.709
0.000
0.000
O.QOO
0.000
1.158
1.494
0.000
0.000
2.617
0.000
1.480
0.000
0.000
0.000
1.769
0.000
1.455
.003
2.120
2.794
1.049
1.391
.913
1.368
.264
.429
2.340
3.187
122
JCODE
1
1
1
1
1
1
1
2
2
2
2
2
1
1
1
2
1
1
2
1
1
1
1
1
1
2
1
2
1
1
2
1
2
1
1
2
2
1
2
1
1
1
EPS I LON
1
1
l
l
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l
1
1
1
1
1
1
1
l
1
1
1
1
1
1
1
l
i
i
i
S 2 TYL 2
• 0471
.0396
.0352
.0341
.0363
.0416
.0502
.0620
.0770
.0953
.1167
.1414
.1693
.2005
.2035
.1724
.1445
.1199
.0983
.0801
.0650
.0532
.0447
.0393
.0372
.0383
.0426
.0501
.0609
.0749
.0921
.1125
.1361
.1630
.1931
.1967
• 1 66 6
.1397
.1161
.0956
.0784
.0644
FREL
/El/
/E2/
/E 3 /
/E 4 /
2.621
5.432
3.221
1.389
1.307
2.767
1.008
0.000
0.000
0.000
0.000
0.000
1.167
1.741
2.315
0.000
2.357
1.661
0.000
3.683
3.244
4.617
6.906
.944
.760
C .000
1.575
0.000
1.226
1.590
0.000
.729
0.000
1.153
1-490
0.000
0.000
1.905
0.000
2.410
2.941
.623
.850
1 .631
.922
.393
.379
.849
.337
0.000
0.000
0.000
0.000
0.000
.871
1.491
2.007
0.000
1.554
.953
0.000
1.601
1.245
1.590
2.186
.283
.222
0.000
.488
0.000
.453
.663
0.000
.400
0.000
. 835
1.237
0.000
0.000
1.225
0.000
1.179
1.263
.238
1.249
1.984
1.151
.494
.470
1.081
.528
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2 . 723
1.663
0.000
2.610
1.973
2.400
3.021
.344
.274
0.000
.638
0.000
.643
1.132
0.000
.639
0.000
0.000
0.000
0.000
0.000
1.996
0.000
1.859
2 . 08 T
.371
• 054
1.630
.918
.389
.373
.833
.329
0.000
0.000
0.000
0.000
0.000
.822
1.399
1.876
0.000
1.472
.909
0.000
1.546
1.209
1.554
2.148
.279
.221
0.000
*490
0.000
.460
.676
0.000
.411
0.000
.866
1.287
0.000
0.000
1.276
0.000
1.216
1.295
.243
1.235
2.007
1.166
.517
.498
1.155
.568
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.839
1.757
0.000
2.802
2.126
2.585
3.242
.367
.289
0.000
.653
0.000
.630
1.079
0.000
.571
0.000
0.000
0.000
0.000
0.000
1.758
0.000
1.751
2.022
.369
123
SERIAL NO .
H
1177
2
1178
1
1179
0
1180
-l
1181
-2
1182
-3
1183
-4
1184
-5
1185
-6
1186
-7
1187
-8
1188
-9
1189
-10
1190
-11
1191
-11
1192
-10
1193
-9
1194
-8
1195
-7
1196
-6
1197
-5
1198
-4
1199
-3
1200
-2
1201
-1
1202
0
1203
1
1204
2
1205
3
1206
4
1207
5
1208
6
1209
7
1210
8
1211
9
1212
9
1213
8
1214
7
1215
6
1216
5
1217
4
1218
3
K
7
7
7
7
7
7
7
7
7
7
7
7
7
7
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
9
9
9
9
9
9
9
L
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
JC ODE EPS ICON S2T / L2 FREL
261/ /EZ/
/ E3 /
1
2
1
2
1
1
1
2
I
1
2
1
2
2
1
1
2
2
1
2
1
1
1
1
2
2
1
1
1
1
1
1
2
1
1
2
1
2
2
1
1
1
1
.0537
1.185
1
.0461
0.000
1
.0418
1.662
1
.0407
0.000
1
.0429
1.932
1
.0482
1.287
1
.0568
1.996
1
.0686
0.000
1
.0836
1.497
1
.1019
1.227
1
.1233
Q.OOC
1
.1480
.791
1
.1759
0.000
1
.2071
C.000
1
.2112
• B85
l
.1801
.841
1
.1521
0.000
1
.1275
0.000
1
.1060
2.150
1
.0877
0.000
1
.0727
1.577
1
.0609
3.576
1
.0524
1.442
1
.0470
2.742
1
.0449
0.000
1
.0460
0.000
1
.0503
2.968
i
.0578
1.481
1
.0686
1.417
1
.0825
2.002
1
.0998
1.575
1
.1202
.743
1
.1438
0.000
1
.1707
2.026
1
.2008
2.305
1
.2055
0.000
1
.1754
1.180
1
.1485
0.000
1
.1249
0.000
1
.1044
1.748
1
.0872
1.515
1
.0732
1.44 3
.410
.615
.416
0.000
0.000
0.000
.511
.654
.513
0.000
0.000
0.000
.601
.791
.595
.422
.637
.416
.711
1.025
.695
0.000
0.000
0.000
.670
1.104
.646
.62 7
.945
.601
0.000
0.000
0.000
.532
.983
.502
0.000
0.000
0.000
0.000
0.000
0.000
.792
0.000
.734
.659
0.000
.616
0.000
0.000
0.000
0.000
0.000
0.000
1.130
1.725
1.081
0.000
0.000
0.000
• 646
1.124
.628
1.323
1.879
1.295
,492
.751
.465
.889
1.302
.882
0.000
0.000
0.000
0.000
0.000
0.000
.994
1.556
1.007
.532
.758
.543
.560
.967
.575
.888
1.458
.917
.793
1.191
.824
.428
.747
.447
0.000
0.000
0.000
1.522
0.000
1.609
1.976
0.000
2.101
0.000
0.000
0.000
.905
0.000
.967
0.000
0.000
0.000
0.000
0.000
0.000
.909
1.381
.952
.696
1.162
.724
.594
1.028
.613
/ E4 /
.625
0.000
.687
0.000
.848
.686
1.106
0.000
1.183
1.004
0.000
1.017
0.000
0.000
0.000
0.000
0.000
0.000
1.824
0.000
1.209
2.029
.811
1.401
0.000
0.000
1.625
.779
.974
1.435
1.141
.695
0.000
0.000
0.000
0.000
0.000
0. 000
0.000
1.345
1 . 161
1.049
tjST
SERIAL NO .
H
K
L
JCOOE
EPSILON
S 2 T / L 2
1219
2
9
2
i
1
.0625
1220
l
9
2
1
1
.0549
1221
0
9
2
1
1
.0506
1222
-1
9
2
1
1
.0495
1223
-2
9
2
1
1
.0517
1224
-3
9
2
2
1
.0570
1225
-4
9
2
1
1
.0656
1226
-5
9
2
1
1
.0774
1227
-6
9
2
l
1
.0924
1228
-7
9
2
1
1
.1107
1229
-8
9
2
2
l
.1321
1230
-9
9
2
2
i
.1568
1231
-10
9
2
2
1
.1847
1232
-11
9
2
1
1
.2159
1233
-11
10
2
1
1
.2211
1234
-10
10
2
1
1
.1900
1235
-9
10
2
1
1
.1620
1236
-8
10
2
l
1
.1374
1237
-7
10
2
1
1
.1159
1238
-6
10
2
2
1
.0976
1239
-5
10
2
1
1
.0326
1240
-4
10
2
1
1
.0 708
1241
-3
10
2
1
1
.0622
1242
-2
10
2
1
1
.0569
1243
-1
10
2
1
1
.0548
1244
0
10
2
2
1
.0559
1245
1
10
2
1
1
.0602
1246
2
10
2
1
1
.0677
1247
3
10
2
1
1
.0785
1248
4
10
2
i
1
.0924
1249
5
10
2
l
1
.1096
1250
6
10
2
2
1
.1301
1251
7
10
2
1
I
.1537
1252
8
10
2
1
1
.1806
1253
9
10
2
2
1
.2107
1254
9
11
2
1
1
.2165
1255
8
11
2
2
1
.1864
1256
7
11
2
2
1
.1595
1257
6
11
2
1
1
.1358
1258
5
11
2
2
1
.1154
1259
4
u
2
i
1
.0982
1260
3
11
2
l
1
.0842
FREL
/El /
/ E 2 /
/£ 3 /
/ E 4 /
2.048
.768
1.140
.788
1.184
1.033
.362
.534
.368
.563
1.650
.554
.864
.560
.921
1.160
.385
.599
.387
.644
3.317
1.126
1.732
1.121
1.871
0.000
0.000
0.000
0.000
0.000
1.533
.591
.950
.579
1.026
.927
.395
.658
.383
.707
.689
.329
.539
.317
.574
1.257
.681
1.062
.651
1.117
o.ooc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.892
.813
0.000
.750
0.000
1.271
1.183
0.000
1.087
0.000
.856
.701
0.000
.650
0.000
1.994
1.437
0.000
1.347
0.000
1.340
.851
1.377
.805
1.415
1.645
.922
1. 53 6
.880
1.605
0.000
0.000
0.000
0.000
0.000
2.752
1.221
2.007
1.187
2.149
7 .644
3.083
5.451
3.024
5.879
3.998
1.496
2.205
1.481
2.386
1.593
.568
.818
.567
.886
2.664
.931
1.379
.937
1.489
0.000
0.000
0.000
0.000
0.000
2.117
.778
l.oai
.796
1.150
.631
.248
.419
.256
.440
1.740
.747
1.235
.777
1.275
1.541
.736
1.205
.771
1.221
.724
.390
.602
.411
.596
0.000
0.000
0.000
0.000
0.000
1.961
1.357
1.607
1.453
1.504
1.191
.936
0.000
1.009
0.000
0.000
0.000
0.000
0.000
0.000
1.546
1.413
0.000
1.551
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0 . 000
2.313
1.456
2.349
1.562
2.304
0.000
0.000
0.000
o.ooo
0.000
2.004
1.397
2.137
1.474
2.194
2.511
1.128
1.864
1.180
1,947
125
SERIAL NO .
H
K
L
1261
2
11
2
1262
1
11
2
1263
0
11
2
1264
-1
11
2
1265
-2
11
2
1266
-3
11
2
1267
-4
11
2
1268
-5
11
2
1269
-6
11
2
1270
-7
11
2
1271
-8
11
2
1272
-9
11
2
1273
-10
11
2
1274
-10
12
2
1275
-9
12
2
1276
-8
12
2
1277
-7
12
2
1278
-6
12
2
1279
-5
12
2
1280
-4
12
2
1281
-3
12
2
1282
-2
12
2
1283
-l
12
2
1284
0
12
2
1285
1
12
2
1286
2
12
2
1287
3
12
2
1288
4
12
2
1289
5
12
2
1290
6
12
2
1291
7
12
2
1292
8
12
2
1293
9
12
2
1294
8
13
2
1295
7
13
2
1296
6
13
2
1297
S
13
2
1298
4
13
2
1299
3
13
2
1300
2
13
2
1301
1
13
2
1302
Q
13
2
JCODE EPSILON S27 / L2
1 1 .0735
2 l .0655
2 1 .0616
1 l .0605
2 1 .0627
l 1 .0680
1 1 .0766
1 1 .0884
1 1 .1034
2 1 .1217
1 1 .1431
2 1 .1678
2 1 .1957
1 1 .2020
1 1 .1741
1 1 .1454
1 1 .1280
1 1 .1057
1 l .0947
1 1 .0829
1 1 .0743
1 1 .0690
2 1 .0669
2 1 .0679
1 1 .0723
1 1 .0798
2 1 .0906
1 1 .1045
2 1 .1217
1 1 .1422
2 1 .1658
2 1 .1927
1 1 .2228
2 1 .1996
1 1 .1727
1 1 .1490
2 1 .1286
l 1 .1114
1 1 .0974
2 1 .0867
2 l .0791
l 1 .0748
FREL / El / / E2 / / E 3 / / E4 /
2.042 .842 1.455 .873 1.542
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.936 .713 1.002 .721 1.087
0.000 0.000 0.000 0.000 0.000
1.548 .610 1.038 .604 1.125
1.728 .731 1.228 .718 1.323
1.178 .546 .915 .531 .976
1.591 .822 1.244 .792 1.311
0.000 0.000 0.000 0.000 0.000
2.073 1.357 2.329 1.282 2.371
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0,000
.873 .752 0.000 .694 0.000
2.039 1.556 0.000 1.451 0.000
.794 .537 1.013 .506 1.021
.757 .456 .739 .435 .761
1.448 .780 1.205 .751 1.262
1.202 .584 .931 .568 .989
.668 .297 .489 .292 .525
1.587 .659 1.130 .655 1.223
2.538 1.008 1.755 1.011 1.908
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.928 .787 1.374 .813 1.483
1.145 .497 .811 .518 .867
0.000 0.000 0.000 0.000 0.000
.714 .371 .564 .395 .587
0.000 0.000 0.000 0.000 0.000
1.106 .720 1.217 .779 1.214
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.274 1.194 0.000 1.325 0.000
O.OOC 0.000 0.000 0.000 0.000
1.438 1.090 0.000 1.200 0.000
1.586 1.071 2.008 1.169 2.034
0.000 0.000 0.000 0.000 0.000
.727 .396 .624 .424 .656
3.831 1.898 2.931 2.011 3.126
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.124 .469 .800 .482 .872
126
SERIAL NO .
H
K
L
1303
-l
13
2
1304
-2
13
2
1305
-3
13
2
1306
-4
13
2
1307
-5
13
2
1308
-6
13
2
1309
-7
13
2
1310
-8
13
2
1311
-9
13
2
1312
-10
13
2
1313
-10
14
2
1314
-9
14
2
1315
-8
14
2
1316
-7
14
2
1317
-6
14
2
1318
-5
14
2
1319
-4
14
2
1320
-3
14
2
1321
-2
14
2
1322
-1
14
2
1323
0
14
2
1324
1
14
2
1325
2
14
2
1326
3
14
2
1327
4
14
2
1328
5
14
2
1329
6
14
2
1330
7
14
2
1331
8
14
2
1332
8
15
2
1333
7
15
2
1334
6
15
2
1335
5
15
2
1336
4
15
2
1337
3
15
2
1338
2
15
2
1339
1
15
2
1340
0
15
2
1341
-1
15
2
1342
-2
15
2
1343
-3
15
2
1344
-4
15
2
JCOOE
EPSILON
S 2 T / L 2
1
1
.0737
1
1
.0759
2
1
.0812
2
1
.0898
2
1
.1016
2
l
.1166
2
1
. 1348
2
1
.1563
1
1
.1810
1
1
.2085
1
1
.2163
2
1
• 1884
1
1
• 1637
1
1
.1423
2
1
.1240
1
1
.1090
1
1
.0972
1
1
.0886
1
1
.0833
1
1
.0811
1
1
.0822
2
1
.0865
2
l
.0941
1
1
.1048
1
1
.1188
1
1
.1360
1
1
.1565
1
1
.1801
1
1
.2070
2
1
.2149
1
1
.1881
2
l
.1644
1
1
.1440
1
1
.1268
1
1
.1128
2
1
.1021
1
1
.0945
1
1
.0902
1
1
.0891
1
1
.0912
1
1
.0966
1
1
.1052
FREL
/ El /
/ E 2 /
1.583
.654
1.128
1.303
.548
.927
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.643
.663
0.000
2.496
2.213
0.000
1.785
1.630
0.000
C .000
0.000
0.000
1.155
.839
0.000
.782
.510
. 863
0.000
0.000
0.000
1.770
.949
1.462
1.977
.978
1.514
.681
.316
.530
.946
.422
.695
1.328
.582
.953
1.154
.511
.838
0.000
0.000
0.000
0.000
0.000
0.000
.714
.373
.567
1.048
.598
1.032
1.725
1.087
1.7 54
1.610
1.129
.751
2 . 79 C
2.188
0.000
1.244
1.094
0.000
o.ooc
0.000
0.000
1.206
.980
0.000
C .000
0.000
0.000
1.110
.730
1.270
2.266
1.356
2.221
2.064
1.134
1.819
0.000
0.000
0.000
.693
.336
.538
2.052
.965
1.620
1.364
.636
1.067
.971
.460
.763
1.846
.909
1.416
2.948
1.541
2.346
/ E 3 1
/ E 4 /
.665
1.230
.551
1.008
O.OOQ
0.000
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
.617
0.000
2.034
0.000
1.494
0.000
0.000
0.000
.789
0.000
.485
.872
0.000
0.000
.924
1.538
.964
1.616
.315
.572
.426
.756
.594
L .041
.527
.917
0.000
0.000
0.000
0.000
.397
.610
.644
1.097
1.184
1.836
1.243
.772
2 . 43 Z
o.ooo
1.229
0.000
0.000
0.000
l. too
0.000
0.000
0.000
.802
1.346
1.472
2.386
1.218
1.974
0.000
0.000
.353
.590
1.000
1.777
.651
1.167
.465
.829
.909
1.526
1.521
2.492
127
SERIAL NO.
H
K
L
JCOOE
EPSILON
S2TVL2
1345
-5
15
2
l
1
.1170
1346
-6
15
2
2
1
.1320
1347
-7
15
2
1
l
.1502
1348
-6
15
2
2
1
.1717
1349
-9
15
2
2
1
.1964
1350
-10
15
2
1
1
.2243
1351
-9
16
2
1
1
.2049
1352
-8
16
2
1
1
.1602
1353
-7
16
2
l
1
.1588
1354
-6
16
2
2
1
.1405
1355
-5
16
2
1
l
.1255
1356
-4
16
2
1
1
.1137
1357
-3
16
2
1
l
.1051
1358
-2
16
2
L
1
.0998
1359
-l
16
2
1
1
.0976
1360
0
16
2
2
1
.0967
1361
1
16
2
2
1
.1030
1362
2
16
2
1
1
.1106
1363
3
16
2
1
1
.1213
1364
4
16
2
2
l
.1353
1365
5
16
2
2
1
.1525
1366
6
16
2
1
1
.1729
1367
7
16
2
1
1
. 1966
1368
a
16
2
2
1
.2235
1369
7
17
2
1
1
.2057
1370
6
17
2
2
L
.1620
1371
5
17
2
l
1
.1616
1372
4
17
2
, 2
1
.1444
1373
3
17
2
l
1
.1304
1374
2
17
2
2
1
.1196
1375
1
17
2
2
1
.1121
1376
0
17
2
1
1
.1078
1377
-1
17
2
1
1
• 1067
1378
-2
17
2
1
L
.1088
1379
-3
17
2
1
1
.1142
1380
-4
17
2
1
l
.1228
1381
-5
17
2
1
1
.1346
1382
-6
17
2
1
1
.1496
1383
-7
17
2
2
1
. 1678
1384
-8
17
2
1
1
.1893
1385
-9
17
2
2
1
.2140
1386
-9
18
2
2
1
.2236
^ o o m
FREl
/ El/
/ 62 /
/E3/
/ €4/
1.475 .832 1.405
C.000 0.000 0.000
1.377 .936 1.736
0.000 0.000 0.000
0.000 0.000 0.000
2.020 1.903 0.000
1.754 1.530 0.000
1.457 1.143 0.000
.609 .574 .133
0.000 0.000 0.000
.753 .447 .742
2.737 1.512 2.453
1.238 .647 .965
1.575 .793 1.191
.979 .982 1.513
.000 0.000 0.000
.000 0.000 0.000
.974 2.152 3.353
1.291 .746 1.292
0.000 0.000 0.000
0.000 0.000 0.000
2.197 1.668 0.000
1.498 1.262 0.000
C.000 0.000 0.000
1.241 1.086 0.000
0.000 0.000 0.000
2.439 1.755 0.000
0.000 0.000 0.000
1.523 .930 1.478
0.000 0.000 0.000
C.000 0.000 0.000
2.037 1.003 1.663
2.781 1.466 2.247
.722 .387 .596
.732 .406 .663
1.673 .978 1.666
1.538 .961 1.545
.794 .538 1.016
0.000 0.000 0.000
1.209 .907 0.000
0.000 0.000 0.000
0.000 0.000 0.000
.811
1.468
0.000
0.000
.090
1.737
0.000
0.000
0.000
o.ooc
1.739
0.000
1.413
0.000
1.071
0.000
.545
.132
0.000
0.000
.436
.770
1.495
2.591
.648
1.056
.605
1.292
1.010
1.655
0.000
0.000
0.000
0.000
2.297
3.685
.808
1.413
0.000
0.000
0.000
0.000
1.868
0.000
1.431
0.000
0.000
0.000
1.243
0.000
0.000
0.000
1.958
0.000
0.000
0.000
1.012
1.628
0.000
0.000
0.000
0.000
1.133
1.831
1.515
2.456
.394
.645
.408
.707
.963
1.749
.939
1.590
.518
1.021
0.000
0.000
.923
0.000
t- 1
0.000
0.000
ro
0.000
0.000
CD
SERIAL NO .
H
K
L
JCODE
EPSILON
S2T / L2
1387
-8
18
2
1
1
■ 1989
1388
-7
18
2
2
1
.1774
1389
-6
18
2
1
1
.1592
1390
-5
18
2
1
1
.1442
1391
-4
18
2
1
1
.1324
1392
-3
18
2
1
1
.1238
1393
-2
18
2
1
1
.1184
1394
-1
18
2
1
1
.1163
1395
0
IS
2
l
l
.1174
1396
1
16
2
1
1
.1217
1397
2
18
2
2
1
.1293
1398
3
18
2
1
1
.1400
1399
4
18
2
1
1
.1540
1400
5
18
2
2
1
.1712
1401
6
18
2
1
1
. 1916
1402
7
18
2
2
1
.2153
1403
6
19
2
l
1
.2018
1404
5
19
2
2
1
.1814
1405
4
19
2
1
l
.1642
1406
3
19
2
2
1
. 1502
1407
2
19
2
2
1
.1394
1408
1
19
2
1
1
. 1319
1409
0
19
2
1
1
.1276
1410
-1
19
2
2
1
,1265
1411
-z
19
2
2
1
.1286
1412
—3
19
2
1
1
.1340
1413
-4
19
2
1
1
.1425
1414
-5
19
2
2
1
.1543
1415
-6
19
2
2
1
.1694
1416
*7
19
2
2
1
.1876
1417
-8
19
2
1
l
.2091
1418
-a
20
2
2
1
.2198
1419
-7
20
2
2
1
.1983
1420
-6
20
2
2
1
.1801
1421
-5
20
2
1
1
.1651
1422
-4
20
2
1
1
.1533
1423
-3
20
2
l
1
.1447
1424
-2
20
2
1
1
.1393
1425
-1
20
2
1
l
.1372
1426
0
20
2
2
1
.1383
1427
1
20
2
2
1
.1426
1426
2
20
2
L
1
.1501
FREL
/ El /
/ E2 /
/ E3 /
/ E4 /
1.504
1.280
0.000
1.195
0.000
0.000
0.000
0.000
0.000
0.000
1.145
.814
.122
.784
.121
1.756
1.156
2.017
1.130
2.057
3.589
2.216
3.541
2.198
3.692
1.677
.986
1.663
.992
1.767
.740
.421
.724
.430
.781
1.041
.585
.980
.606
1.070
1.275
.723
1.228
.760
1.352
1.828
1.062
1.827
1.131
2.023
0.000
0.000
0.000
0.000
0.000
2.059
1.326
2 . 163
1.452
2.396
1.388
.961
1.007
1.067
1.199
0.000
0.000
0.000
0.000
0.000
1.213
1.001
0.000
1.141
0.000
0.000
0.000
0.000
0.000
0.000
2.137
1.840
0.000
2.117
0.000
0.000
0.000
0.000
0.000
0.000
2.162
1.575
0.000
1.761
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.764
.471
.751
.504
.833
1.070
.643
1.046
.679
1.151
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.172
1.353
2 . 171
1.365
2.294
2.595
1.694
2.880
1.683
2.981
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.883
.783
0.000
.731
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.166
1.584
0.000
1.551
0.000
2.263
1.562
1.986
1.554
2.038
2.080
1.373
2.414
1.388
2.534
1.099
.705
1.148
.724
1.228
1.895
1.202
1.945
1.254
2.113
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.124
.764
1.430
.835
1.596
129
SERIAL NO .
H
K
L
JCODE
1429
3
20
2
2
1430
4
20
2
1
1431
5
20
2
1
1432
6
20
2
2
1433
6
21
2
1
1434
5
21
2
2
1435
4
21
2
2
1436
3
21
2
1
1437
2
21
2
2
1438
1
21
2
1
1439
0
21
2
1
1440
-1
21
2
2
1441
-2
21
2
1
1442
-3
21
2
1
1443
-4
21
2
1
1444
-5
21
2
2
1445
-6
21
2
l
1446
-7
21
2
2
1447
-7
22
2
2
1446
-6
22
2
l
1449
-5
22
2
2
1450
-4
22
2
1
1451
-3
22
2
1
1452
-2
22
2
1
1453
-1
22
2
1
1454
0
22
2
2
1
22
2
1
1456
2
22
2
2
1457
3
22
2
1
1458
4
22
2
2
1459
5
22
2
1
1460
4
23
2
1
1461
3
23
2
1
1462
2
23
2
2
1463
l
23
2
1
1464
0
23
2
1
1465
-1
23
2
1
1466
-2
23
2
1
1467
-3
23
2
2
1468
-4
23
2
1
1469
-5
23
2
2
1470
-6
23
2
2
EPSILON
S2T / L2
FREL
/ El /
1
.1609
0.000
0.000
1
.1749
1.667
1.276
1
.1921
1.717
1.419
1
.2125
0.000
0.000
1
.2238
1.805
1.698
1
.2034
0.000
0.000
1
.1862
0.000
0.000
1
.1722
.829
.627
1
.1614
0.000
0.000
I
.1539
1.133
.784
1
.1496
1.375
.931
1
.1485
0.000
0.000
1
.1506
1.378
.938
I
.1560
.804
.563
1
.1645
1.828
1.334
I
.1763
0.000
0.000
1
.1914
1.715
1.413
1
.2096
0.000
0.000
1
.2214
0.000
0.000
I
.2032
2.192
1.855
1
.1881
0.000
0.000
1
.1763
1.182
.911
I
.1678
1.645
1.219
1
.1624
2.443
1.765
1
.1603
1.814
1.296
1
.1614
0.000
0.000
1
.1657
2.007
1.473
1
.1732
0.000
0.000
1
.1840
1.694
1.351
1
.1980
0.000
0.000
1
.2152
1.992
1.811
1
.2103
2.796
2.494
1
.1964
.865
.728
l
.1856
0.000
0.000
1
.1781
1.874
1.456
t
.1737
2.037
1.552
1
.1727
2.625
1.989
I
.1748
2.205
1.687
1
.1801
0.000
0.000
1
.1887
1.479
1.205
1
.2005
0.000
0.000
1
.2155
C.000
0.000
/E 2 /
/ E3 /
/ E4 /
0.000
0.000
0.000
0.000
1.438
0.000
0.000
1.624
0.000
0.000
0.000
0.000
0.000
1.969
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.701
0.000
0.000
0.000
0.000
.906
.849
1.005
1.759
.992
1.931
0.000
0.000
0.000
1.674
.967
1.781
.428
.570
.445
0.000
1.330
0.000
0.000
0.000
0.000
0.000
1.361
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
1.788
0.000
0.000
0.000
0.000
0.000
.910
0.000
0.000
1.239
0.000
0.000
1.825
0.000
0.000
1.364
0.000
0.000
0.000
0.000
0.000
1.603
0.000
0.000
0.000
0.000
0.000
1.521
0.000
0.000
0.000
0 . 000
0.000
2.107
0.000
0.000
2.876
0.000
0.000
.825
0.000
0.000
0.000
0.000
0.000
1.594
0.000
0.000
1.669
0.000
0.000
2.102
0.000
0.000
1.751
0.000
0.000
0.000
0.000
0.000
1.205
C.000
1 \
0.000
0.000
0.000
r— '
{Jj
0.000
0.000
0.000
o
SERIAL NO .
H
K
L
JCODE
EPSILON
S2T / L2
1471
-5
24
2
2
1
.2134
1472
-4
24
2
1
1
.2016
1473
-3
24
2
1
1
.1931
1474
-2
24
2
1
1
.1877
1475
-1
24
2
1
1
.1856
1476
0
24
2
l
1
.1867
1477
1
24
2
1
1
.1910
1478
2
24
2
2
1
.1985
1479
3
24
2
2
1
.2093
1480
4
24
2
2
1
.2233
1481
3
25
2
1
1
.2227
1482
2
25
2
2
1
.2120
1483
l
25
2
1
1
.2044
1484
0
25
2
2
1
.2001
1485
-1
25
2
1
l
.1990
1486
-2
25
2
1
1
.2012
1487
-3
25
2
1
1
.2065
1488
-4
25
2
1
1
*2151
1489
-3
26
2
2
1
.2205
1490
-2
26
2
1
1
.2152
1491
-l
26
2
1
1
.2130
1492
0
26
2
1
1
.2141
1493
1
26
2
1
1
.2185
1494
0
24
3
2
l
.2221
1495
-1
24
3
2
1
.2197
1496
-2
24
3
1
1
.2205
1497
-4
23
3
1
1
.2188
1498
-3
23
3
1
1
.2115
1499
-2
23
3
1
1
.2075
1500
-1
23
3
2
1
.2068
1501
0
23
3
1
1
.2092
1502
1
23
3
2
1
.2149
1503
2
23
3
2
1
.2238
1504
3
22
3
1
1
.2235
1505
2
22
3
2
1
.2114
1506
1
22
3
1
1
.2025
1507
0
22
3
1
1
.1968
1508
-1
22
3
1
1
.1944
1509
-2
22
3
1
1
.1952
1510
-3
22
3
1
1
.1992
1511
-4
22
3
2
1
.2064
1512
-5
22
3
2
1
.2169
FfiEl
/ El /
/ E2 /
/ E3 /
/ E4 /
0.000
0.000
0.000
0.000
0.000
3.264
2.808
0.000
2.815
0.000
1.720
1.428
0.000
1.458
0.000
1.476
1.197
0.000
1.246
0.000
1.201
.965
0.000
1.023
0.000
.851
.607
0.000
.742
0.000
1.212
.997
0.000
1.097
0.000
C.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C.000
0.000
0.000
0.000
0.000
2.549
2.387
0.000
2.745
0.000
0.000
0.000
0.000
0.000
0.000
1.752
1.525
0.000
1.689
0.000
0.000
0.000
0.000
0.000
0.000
1.228
1.046
0.000
1.114
0.000
1.510
1.296
0.000
1.354
0.000
2.326
2.042
0.000
2.092
0.000
1.543
1.402
0.000
1.409
0.000
0.000
0.000
0.000
0.000
0.000
.891
.810
0.000
.849
0.000
.888
.801
0.000
.856
0.000
.889
.805
0.000
.879
0.000
.895
.82 5
0.000
.918
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.008
1.864
0.000
2.001
0.000
1.267
1.168
0.000
1.202
0.000
2.802
2.511
0.000
2.632
0.000
.880
.776
0.000
.829
0.000
0.000
0.000
0.000
0.000
0.000
1.974
1.752
0.000
1.941
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.902
.848
0.000
.982
0.000
0.000
0.000
0.000
0.000
0.000
.873
.754
0.000
.845
0.000
1.731
1.460
0.000
1.607
0.000
2.111
1.762
0.000
1.906
0.000
2.589
2.168
0.000
2.304
0.000
1.738
1.480
0.000
1.545
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
131
SERIAL NO
H
K
JCODE EPSILON S2T / L2
1513
-6
21
1514
-5
21
1515
-4
21
1516
-3
21
1517
-2
21
1518
-1
21
1519
0
21
1520
1
21
1521
2
21
1522
3
21
1523
4
20
1524
3
20
1525
2
20
1526
1
20
152T
0
20
1528
-1
20
1529
-2
20
1530
-3
20
1531
-4
20
1532
-5
20
1533
-6
20
1534
-7
20
1535
-7
19
1536
-6
19
1537
-5
19
1538
-4
19
1539
-3
19
1540
-2
19
1541
-1
19
1542
0
19
1543
1
19
1544
2
19
1545
3
19
1546
4
19
1547
5
19
1548
5
18
1549
4
18
1550
3
18
1551
2
18
1552
1
18
1553
0
IB
1554
-1
18
3 2 1
3 2 1
3 1 l
3 I 1
3 1 1
3 1 1
3 2 1
3 1 1
3 2 I
3 2 1
3 1 I
3 1 1
3 2 1
3 1 1
3 2 1
3 2 1
3 i 1
3 2 l
3 2 I
3 2 1
3 2 i
3 1 1
3 1 1
3 1 1
3 2 1
3 1 l
3 1 1
3 1 1
3 1 1
3 2 1
3 1 1
3 1 1
3 2 1
3 1 1
3 1 1
3 2 1
3 i l
3 2 1
3 2 1
3 2 1
3 l l
3 2 1
.2187
.2050
. 19*6
.1674
.1834
.1026
.1850
.1907
.1996
.2117
.2158
.2004
.1883
.1794
.1736
.1713
.1721
.1761
.1833
.1938
.2074
.2243
.2136
.1967
.1830
.1726
.1654
.1614
.1606
. 1630
.1687
.1776
.1097
.2050
.2236
.2134
.1949
.1795
.1674
.1585
.1529
.1504
FREL
/ El /
/ E 2/
0.000
0.000
0.000
0.000
0.000
0.000
.849
.709
0.000
1.874
1.517
0.000
2.497
1.986
0.000
1.859
1.474
0.000
0.000
0.000
0.000
2.919
. 2.398
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.320
2.114
0.000
1.713
1.466
0.000
c.ooc
0.000
0.000
1.431
1.116
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.155
.873
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.690
.838
0.000
1.514
1.368
0.000
2.251
1.898
0.000
0.000
0.000
0.000
1.414
1.071
0.000
1.141
.836
0.000
1.132
.814
0.000
1.786
1.278
0.000
0.000
0.000
0.000
1.621
1 .206
0.000
1.167
.904
0.000
0.000
0.000
0.000
.864
.754
0.000
.889
.835
0.000
C.000
0.000
0.000
.850
• 711
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.927
1.327
1.788
0.000
0.000
0.000
/ E3 / / E4 /
0.000 0.000
0.000 0.000
-725 0.000
1.577 0.000
2.100 0.000
1.585 0.000
0.000 0.000
2.666 0.000
0.000 0.000
0.000 0.000
2.446 0.000
1.670 0.000
0.000 0.000
1*235 0.000
0.000 0.000
0.000 0.000
.919 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
•812 0.000
1.322 0.000
1.865 0.000
0.000 0.000
1.087 0.000
.861 0.000
.852 0.000
1.359 0.000
0.000 0.000
1.322 0.000
1.006 0.000
0.000 0.000
.864 0.000
.971 0.000
0.000 0.000
.807 0.000
0.000 0.000
0.000 0,000
0.000 0.000 M
1.424 1.965 W
0.000 0.000 m
serial no .
H
K
1555
-2
18
1556
-3
18
1557
-4
ie
1558
-5
18
1559
-6
18
1560
-7
18
1561
-8
18
1562
-8
17
1563
-7
17
1564
-6
17
1565
17
1566
-4
17
1567
-3
17
1568
-2
17
1569
-1
17
1570
0
17
1571
l
17
1572
2
17
1573
3
17
1574
4
17
1575
5
17
1576
6
16
1577
5
16
1576
4
16
1579
3
16
1580
2
16
1581
1
16
1582
0
16
1583
-1
16
1584
-2
16
1585
-3
lb
1586
-4
16
1587
-5
16
1588
-6
16
1589
-7
16
1590
-8
16
1591
-9
15
1592
-8
15
1593
-7
15
1594
-6
15
1595
-5
15
1596
-4
15
FREL / El / / E2 / / E3 / /£ 4 /
0.000 0.000 0.000 0.000 0.000
1.580 1.101 .992 1.130 1.095
.802 .579 0.000 .506 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.536 1 . 44 * 0.000 1.373 0.000
2.143 1.939 0.000 1.043 0.000
1.467 1.221 0.000 1.178 0.000
0.000 0.000 0.000 0.000 0.000
2.408 1.746 0.000 1.734 0.000
0.000 0.000 0.000 0.000 0.000
1.097 .728 1.297 .744 1.428
2-032 1.319 2.209 1.368 2.433
C.OOO 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 0.000
1.776 1.254 .515 1.374 .549
1.625 1.216 0.000 1.350 0.000
0.000 0.000 0.000 0.000 0.000
1.219 1.059 0.000 1.207 0.000
.879 .804 0.000 .918 0.000
0.000 0.000 0.000 0.000 0.000
o.ooo o.ooo o.ooo o.ooo a. ooo
0.000 0.000 0.000 0.000 C.OOO
1.104 .745 1.390 .809 1.464
.766 .493 .804 .529 .859
2.137 1.333 2.141 1.413 2.316
1.301 .801 1.277 .837 1.393
1.845 1.140 1.822 1.177 1.998
2.279 1.440 2-327 1.466 2.555
1.336 .878 1.521 .882 1.667
1.365 .946 1.036 .938 1.129
.810 .601 0.000 .587 0.000
0.000 0.000 0.000 0.000 0.000
1.929 1.682 0.000 1.598 0.000
0.000 0.000 0.000 0.000 0.000
1.473 1.239 0.000 1.177 0.000
2.174 1.675 0.000 1.612 0.000
1.593 1.133 .139 1.106 .150
0.000 0.000 0.000 0.000 0.000
1.856 1.164 1.875 1.166 2.052
133
SERIAL NO,
H
K
L
JCOOE
1597
-3
15
3
l
1598
-2
15
3
1
1599
-1
15
3
1
1600
0
15
3
2
1601
1
15
3
1
1602
2
15
3
2
1603
3
15
3
2
1604
4
15
3
2
1605
5
15
3
l
1606
6
15
3
1
1607
6
14
3
2
1608
5
14
3
2
1609
4
14
3
1
1610
3
14
3
2
1611
2
14
3
l
1612
i
14
3
2
1613
0
14
3
1
1614
-1
14
3
1
1615
-2
14
3
1
1616
-3
14
3
1
1617
-4
14
3
1
1618
-5
14
3
2
1619
-6
14
3
2
1620
-7
14
3
1
1621
-8
14
3
2
1622
-9
14
3
1
1623
-9
13
3
1
1624
-8
13
3
1
1625
-7
13
3
1
1626
-6
13
3
2
1627
-5
13
3
2
1626
-4
13
3
l
1629
-3
13
3
1
1630
-2
13
3
1
1631
-1
13
3
1
1632
0
13
3
2
1633
1
13
3
1
1634
2
13
3
2
1635
3
13
3
2
1636
4
13
3
2
1637
5
13
3
1
1638
6
13
3
1
EPSILON S2T/L2
.1280
.1240
.1232
.1257
.1313
.1402
.1523
.1677
.1862
.2080
.2000
FREL
/El/
/E2/
/E3/
/E4/
1.055 .636
.739 .435
2.210 1.295
0.000 0.000
1.300 .798
0.000 0.000
0.000 0.000
0.000 0.000
.837 .675
.868 .767
0.000 0.000
0.000 0.000
1.594 1.136
0.000 0.000
1.065 .657
0.000 0.000
1.923 1.089
1.445 .806
1.774 .995
.732 .421
2.104 1.262
0.000 0.000
0.000 0.000
1.812 1.345
0.000 0.000
2.136 1.916
1.927 1.677
1.174 .924
1.131 .811
0.000 0.000
0.000 0.000
1.265 .726
1.242 .682
1.420 .759
1.226 .653
0.000 0.000
.725 .406
0.000 0.000
0.000 0.000
0.000 0.000
1.409 1.055
2.391 1.980
1.029
.645
.732
.447
2.197
1.347
0.000
0.000
1.271
.851
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.754
0.000
.867
0.000
0.000
0.000
0.000
.065
1.244
0.000
0.000
1.050
.704
0.000
0.000
1.855
1.140
1.333
.834
1.661
1.017
.736
.425
2.058
1.260
0.000
0.000
0.000
0.000
0.000
1.294
0.000
0.000
0.000
1.796
0.000
1.573
0.000
.877
0.000
.779
0.000
0.000
0.000
0.000
1.268
.723
1.091
.686
1.169
.773
1.002
.671
0.000
0.000
.677
.427
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
1.161
0.000
2.193
1.126
.799
2.380
0.000
1.345
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.064
0.000
1.078
0.000
1.970
1.433
1.800
.802
2.247
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.360
1.183
1.258
1.067
0.000
• TOO
0. 000
0.000
0.000
0.000 Co
0.000 -t
SERIAL NO .
H
K
L
JCOOE
EPSILON
S 2 T / L 2
1639
7
13
3
1
1
.2176
1640
7
12
3
1
1
.2107
1641
6
12
3
1
1
.1857
1642
5
12
3
1
1
.1640
1643
4
12
3
1
1
.1454
1644
3
12
3
l
1
.1301
1645
2
12
3
l
1
.1180
1646
1
12
3
1
1
.1091
1647
0
12
3
l
1
.1034
1648
-1
12
3
2
1
.1010
1649
-2
12
3
1
1
.1017
1650
-3
12
3
2
1
.1057
1651
-4
12
3
2
1
.1130
1652
-5
12
3
2
1
• 1234
1653
-6
12
3
1
1
.1371
1654
-7
12
3
2
1
.1540
1655
-8
12
3
1
1
.1741
1656
-9
12
3
1
1
.1974
1657
-10
12
3
1
1
.2240
1658
-10
11
3
2
1
.2177
1659
-9
11
3
1
1
.1911
1660
-8
11
3
2
1
.1678
1661
-7
11
3
1
1
.1477
1662
-6
11
3
2
1
.1308
1663
-5
11
3
2
l
.1171
1664
-4
11
3
2
1
.1066
1665
-3
11
3
1
1
.0994
1666
-2
11
3
1
1
.0954
1667
-1
11
3
1
1
.0946
1668
0
11
3
1
1
.0971
1669
1
11
3
1
1
.1027
1670
2
11
3
2
1
.1116
1671
3
11
3
2
1
.1237
1672
4
11
3
2
1
.1391
1673
5
11
3
2
1
.1576
1674
6
11
3
1
1
.1794
1675
7
11
3
1
1
.2044
1676
7
10
3
1
1
.1986
1677
6
10
3
l
1
.1736
1678
5
10
3
2
1
.1519
1679
4
10
3
1
1
.1333
1680
3
10
3
1
1
.1180
FREL
/ El /
/ E 2 /
/E 3 /
/ E 4 /
2.917
2.678
0.000
2.994
0.000
2.302
2.056
0.000
2.274
C .000
1.183
.951
0.000
1.042
0.000
.804
.585
0.000
.635
0.000
1.897
1.257
2.235
1.352
2.110
. 75 C
.457
.725
.487
.705
3.252
1.846
3.153
1.947
3.144
2.010
1.078
1.662
1.126
1.695
1.565
.808
1.224
.836
1.272
O.OOC
0.000
0.000
0.000
0.000
1.206
.616
.927
.624
.991
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.01 2
1.275
2.064
1.238
2.240
0.000
0.000
0.000
0.000
0.000
.820
.625
0.000
.594
0.000
2.088
1.765
0.000
1.657
0.000
2.176
2.048
0.000
1.901
0.000
0.000
0.000
0.000
0.000
0.000
2.066
1.701
0.000
1.598
0.000
0.000
0.000
0.000
0.000
0.000
1.556
1.043
1.918
1.001
2.075
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
1.384
.695
1.048
.695
1.123
• 968
.473
.748
.477
.792
1.181
• 574
.915
.584
.956
1.190
.588
.912
.604
.936
1.562
.803
1.214
.833
1.220
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OOC
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.431
1.118
0.000
1.213
0.000
1.492
1.299
0.000
1.420
0.000
2.092
1.778
0.000
1.923
0.000
2.005
1.526
0.000
1.638
0.000
0.000
0.000
0.000
0.000
0.000
1.068
.663
1.062
.700
.963
1.030
.585
.999
.613
.936
135
SERIAL NO .
H
K
L
JCOOE
EPSILON
S2T / L2
1681
2
10
3
2
1
.1059
1682
1
10
3
1
1
.0970
1683
0
10
3
2
1
.0913
1684
-1
10
3
2
1
.0889
1685
-2
10
3
1
1
.0896
1686
-3
10
3
1
L
.0937
1687
-4
10
3
1
1
.1009
1688
-5
10
3
l
1
.1113
1689
-6
10
3
2
1
.12 50
1690
-7
10
3
1
1
.1419
1691
-8
10
3
2
1
.1620
1692
-9
10
3
1
1
.1853
1693
-10
10
3
2
1
.2119
1694
-10
9
3
1
1
.2067
1695
-9
9
3
1
1
.1801
1696
-8
9
3
1
1
.1568
1697
-7
9
3
1
1
.1367
1698
-6
9
3
2
1
.1198
1699
-5
9
3
1
1
.1061
1700
-4
9
3
1
1
.0957
1701
-3
9
3
1
1
.0884
1702
-2
9
3
1
1
.0844
1703
-l
9
3
1
1
.0836
1704
0
9
3
2
1
.0861
1705
1
9
3
1
1
. C918
1706
2
9
3
1
1
.1006
1707
3
9
3
1
1
.1128
1708
4
9
3
1
1
.1281
1709
5
9
3
1
1
.1466
1710
6
9
3
2
1
.1684
1711
7
9
3
2
1
.1934
1712
8
9
3
2
1
.2216
1713
8
8
3
1
1
.2170
1714
7
8
3
2
1
.1888
1715
6
8
3
2
1
.1637
1716
5
8
3
2
1
.1420
1717
4
8
3
2
1
.1234
1718
3
8
3
2
1
.1081
1719
2
8
3
1
1
.0960
1720
1
8
3
1
1
.0871
1721
0
8
3
l
1
.0814
1722
-1
e
3
1
1
.0790
FREL
/ El /
/ E2 /
/ E3 /
/ E4 /
0.000
0.000
0.000
0.000
0.000
2.278
1.125
1.747
1.160
1.731
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.125
.995
1.672
.999
1.756
.963
.464
.750
.462
.797
1.390
.705
1.059
.696
1.137
1.430
.778
1.225
.761
1.322
0.000
0.000
0.000
0.000
0.000
1.331
.866
1.456
.830
1.575
0.000
0.000
0.000
0.000
0.000
1.446
1.160
0.000
1.091
0.000
0.000
0.000
0.000
0.000
0.000
.866
.761
0.000
.709
0.000
1.433
1.123
0.000
1.057
0.000
1.585
1.113
.672
1.057
.725
1.802
1.139
1.842
1.092
1.991
0.000
0.000
0.000
0.000
0.000
1.221
.642
.980
.626
1.054
2.053
1.004
1.584
.988
1.690
1.770
.821
1.375
.814
1.450
2.381
1.072
1.772
1.071
1.842
1.742
.779
1.285
.706
1.313
0.000
0.000
0.000
0.000
0.000
1.013
.482
.794
.493
.775
1.040
.527
.791
.544
.750
1.522
.836
1.340
.869
1.232
.746
.450
.727
.471
.646
1.553
1.036
1.876
1.093
1.604
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.757
1.609
0.000
1.713
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.824
1.385
2.176
1.419
2.027
.998
.458
.764
.466
.733
4.714
2.072
3.392
2.093
3.343
.918
.396
.651
.397
.656
SERIAL NO .
H
K
L
JCOOE
EPSILON
S 2 T / L 2
FREL
/ El /
/ E 2 /
/E 3 /
/ E 4 /
1723
-2
8
3
1
1
.0798
2.517
1.092
1.783
1.087
1.034
1724
-3
8
3
1
1
.0838
2.466
1.104
1.821
1.091
1.904
1725
-4
6
3
1
l
.0910
1.509
.713
1.187
.699
1.258
1726
-5
8
3
1
1
.1014
2.201
1.122
1.687
1.091
1.805
1727
-6
8
3
2
1
.1151
0.000
0.000
0.000
0.000
0.000
1728
-7
8
3
1
1
.1320
1.302
.802
1.280
.768
1.382
1729
-8
8
3
l
1
.1521
.786
.539
.805
.512
.870
1730
-9
8
3
2
1
.1754
0.000
0.000
0.000
0.000
0.000
1731
-10
8
3
1
1
.2020
1.717
1.480
0.000
1.382
0.000
1732
-10
7
3
1
1
.1979
.054
.723
0.000
.676
0.000
1733
-9
7
3
2
1
.1713
0.000
0.000
0.000
0.000
0.000
1734
-8
7
3
2
1
.1480
0.000
0.000
0.000
0.000
0.000
1735
-7
7
3
1
1
.1279
2.235
1.345
2.181
1.287
2.350
1736
-6
7
3
1
1
.1110
1.012
.549
.860
.530
.923
1737
-5
7
3
1
1
.0973
2.574
1.274
1.970
1.237
2.095
1738
-4
7
3
1
1
.0869
1.489
.683
1.137
.667
1.196
1739
-3
7
3
1
1
.0796
2.832
1.227
2.006
1.208
2.078
1740
-2
7
3
2
1
.0756
0.000
0.000
0.000
0.000
0.000
1741
-1
7
3
1
1
.0749
1.277
.533
.909
.531
.905
1742
0
7
3
2
1
.0773
0.000
0.000
0.000
0.000
0.000
1743
4
7
3
2
1
.1193
0.000
0.000
0.000
0.000
0.000
1744
1
7
3
1
l
.0830
1.138
.506
.633
.512
.786
1745
2
7
3
1
1
.0918
1.353
.644
1.061
.655
.970
1746
3
7
3
l
1
.1040
.993
.515
.780
.527
.689
1747
5
7
3
2
1
.1378
0.000
0.000
0.000
0.000
0.000
1748
6
7
3
1
1
.1596
2.642
1.883
.131
1.960
.102
1749
7
7
3
1
1
.1846
1.444
1.155
0.000
1.209
0.000
1750
a
7
3
1
1
.2129
1.746
1.573
0.000
1.656
0.000
1751
8
6
3
1
1
.2093
1.503
1.335
0.000
1.389
0.000
1752
7
6
3
2
1
.1811
0.000
0.000
0.000
0.000
0.000
1753
6
6
3
1
1
.1561
3.357
2.350
1.741
2.422
1.321
1754
5
6
3
2
1
.1343
0.000
0.000
0.000
0.000
0.000
1755
4
6
3
2
1
.1157
0.000
0.000
0.000
0.000
0.000
1756
3
6
3
2
1
.1004
0.000
0.000
0.000
0.000
0.000
1757
2
6
3
1
1
.0883
1.496
.693
1.160
.700
1.040
1758
l
6
3
1
1
.0794
2.429
1.051
1.721
1.055
1.596
1759
0
6
3
2
1
.0737
0.000
0.000
0.000
0.000
0.000
1760
-1
6
3
1
1
.0713
3.726
1.509
2.657
1-498
2.608
1761
-2
6
3
1
1
.0721
1.787
.728
1.274
.719
1.280
1762
-3
6
3
1
1
.0761
2.313
.974
1.644
.956
1.686
1763
-4
6
3
1
1
.0833
.659
.294
.484
.287
.505
1764
-5
6
3
1
1
.0937
2.152
1.038
1.674
1.006
1.769
137
jccoe
1
1
1
l
1
z
1
1
1
2
1
1
1
1
1
1
1
2
1
1
1
1
1
2
2
1
1
2
1
1
2
1
1
2
X
1
X
X
X
2
X
2
EPS ILQN
X
X
1
X
X
X
X
X
1
X
X
X
X
X
X
X
1
X
X
X
1
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
I
X
X
X
X
S2T/L2
<1074
• X 243
.1444
.1678
.1943
.2241
.2211
• 191 3
.1647
. 14 X 4
.1213
.1044
.0907
.0803
.0730
. 0690
.0683
.0707
.0764
.0853
.0974
.1127
.1313
.1530
.1780
-2063
.2038
.1756
.1506
.1288
.1102
.0949
.0628
.0739
.0682
.0658
.0666
.0706
.0776
.0662
. 10 X 9
.1188
FR 6 L
1.415
1.477
1.728
1 . 8 X 0
1.696
0.000
1 .53 X
2.668
1.393
0.000
3.440
11.007
1.906
1.456
1.794
1.396
1.867
0.000
X .436
1.752
.689
.719
1.679
0.000
0.000
.865
1.722
0.000
1.591
2.277
0.000
2.195
3.950
0.000
2.098
1.253
2.739
2.709
.656
0.000
1.002
0.000
/El/
/E2/
/E 3 /
/ E 4 /
.751
1.151
.723
1.229
.871
1.462
.633
1.571
1.139
1.995
1.082
2.151
1 .341
0.000
1.265
0.000
1.415
0.000
1.325
0 . 000
0.000
0.000
0.000
0.000
1.424
0.000
1.328
0.000
2.197
0.000
2.062
0.000
1.017
0.000
.961
0.000
0.000
0.000
0.000
0.000
1.992
3.443
1.905
3.685
5.723
8.691
5.503
9.224
.899
1.502
.870
1.575
.634
1.034
.617
1.068
.737
1.278
.721
1.296
.555
.967
.545
.959
.737
1.262
.728
1.221
0.000
0.000
0.000
0.000
.606
1.021
.605
.929
.793
l .315
.795
1.156
.341
.527
.344
.446
.395
.632
.399
.512
1.030
1.641
1.047
1.271
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.759
0.000
.781
0.000
1.495
0.000
1.520
0.000
0.000
0.000
0.000
0.000
1.083
1.941
1.094
1.392
1.378
2.213
1.387
1.670
0.000
0.000
0.000
0.000
1.068
1.699
1.067
1.404
1.755
2.886
1.748
2.483
0.000
0.000
0.000
0.000
.828
1.417
.818
1.309
.484
.701
.476
.744
1.065
1.753
1.043
1.715
1.090
1.932
1.063
1.936
.280
.466
.272
.476
0.000
0.000
0.000
0.000
.512
.772
.492
.814
0.000
0.000
0.000
0.000
UJ
CO
SERIAL NO .
H
K
L
jcooe
EPSILON
S 2 T / L 2
1807
-8
4
3
2
1
.1389
1808
-9
4
3
2
1
.1623
1809
-10
4
3
1
1
.1888
1810
-11
4
3
2
1
.2186
1811 *
-11
3
3
2
1
.2167
1812
-10
3
3
1
1
.1869
1813
-9
3
3
1
1
.1603
1814
-8
3
3
1
1
.1370
1815
-7
3
3
1
1
.1169
1816
-6
3
3
1
1
.1000
1817
-5
3
3
2
1
.0863
1818
-4
3
3
2
1
.0759
1819
-3
3
3
1
1
. 0686
1820
-2
3
3
1
1
.0646
1821
-1
3
3
1
1
.0639
1822
0
3
3
2
1
.0663
1823
1
3
3
2
l .
.0720
1824
2
3
3
2
1
.0609
1825
3
3
3
1
1
.0930
1826
4
3
3
l
L
.1083
1827
5
3
3
1
l
.1269
1828
6
3
3
1
1
.1466
1829
7
3
3
2
1
.1736
1830
8
3
3
1
1
.2019
1831
8
2
3
2
1
.2005
1832
7
2
3
1
1
.1 723
1833
6
2
3
1
1
.1473
1834
5
2
3
1
1
.1255
1835
4
2
3
1
1
.1069
1836
3
2
3
2
1
.0916
1837
2
2
3
1
1
.0795
1838
1
2
3
I
1
.0706
1839
0
2
3
2
1
.0649
1840
-1
2
3
1
1
.0625
1841
-2
2
3
1
1
.0633
1842
-3
2
3
2
1
.0673
1843
-4
2
3
1
1
.0745
1844
-5
2
3
1
1
.0849
1845
-6
2
3
2
1
.09 86
1846
-7
2
3
1
1
.1155
1847
-8
2
3
1
1
.1356
1848
-9
2
3
1
1
.1590
FREL
/ El /
/ E 2 /
/ E 3 /
/ E 4 /
0.000
0.000
0.000
0.000
0.000
C .000
0.000
0.000
0.000
0.000
1.708
1.392
0.000
1.308
0.000
C .000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.234
.997
0.000
.939
0.000
2.882
2,060
0.000
1.950
0.000
2.967
1.880
3.041
1.788
3.253
2.000
1.128
1.902
1.077
2.017
2.043
1.031
1.543
.989
L .616
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.592
.630
1.089
.612
1.077
3.836
1.467
2.302
1.430
2.220
2.297
.872
1.342
.854
1.257
0.000
0.000
0.000
0.000
0.000
0 .000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.707
.339
.552
.336
.445
1.654
.883
1.357
.878
1.046
1.550
.928
1.519
.925
1.115
1.991
1.342
2.501
1.342
1.742
0.000
0.000
0.000
0.000
0.000
2.367
2.039
0.000
2.049
0.000
0.000
0.000
0.000
0.000
0.000
3.403
2.574
0.000
2.555
0.000
1.405
.940
1.718
.931
1.161
.772
.458
.760
.453
.543
4.482
2.370
3.629
2.339
2.725
o.ooc
0.000
0.000
0.000
0.000
1.791
.775
1.269
.761
1.044
.926
.373
.660
.365
-566
0.000
0.000
0.000
0.000
0.000
2.761
1.036
1.537
1.009
1.415
2.201
.831
1.260
.808
1.197
0.000
0.000
0.000
0.000
0.000
.664
.276
.473
.267
.473
2.926
1.322
2.109
1.272
2.236
O.OOC
0.000
0.000
0.000
0.000
1.065
.595
.907
.569
1.041
1.768
1.111
1.791
1.057
1.909
.829
.589
.115
.558
.123
139
SERIAL NO .
H
K
L
JCODE
1849
-10
2
3
2
1850
-11
2
3
1
1851
-11
1
3
1
1852
-10
1
3
1
1853
-9
1
3
1
1854
-8
1
3
2
1855
-7
1
3
1
1856
-6
1
3
1
1857
-5
1
3
1
1858
-4
1
3
1
1859
-3
1
3
l
1860
-2
1
3
1
.1861
-1
1
3
l
1862
0
1
3
2
1863
1
l
3
1
1864
2
1
3
1
1865
3
1
3
2
1666
4
1
3
1
1867
5
1
3
2
1868
6
1
3
2
1869
7
1
3
2
1B70
8
1
3
1
1871
7
0
3
1
1872
5
0
3
1
1873
3
0
3
1
1874
1
0
3
1
1875
-1
0
3
1
1876
-3
0
3
2
1877
-5
0
3
1
1878
-7
0
3
1
1879
-9
0
3
2
1800
-11
0
3
2
1881
-10
0
4
2
1882
-8
0
4
1
1683
-6
0
4
1
1884
-4
0
4
2
1885
-2
0
4
2
1886
0
0
4
1
1887
2
0
4
2
1888
4
0
4
1
1889
6
0
4
1
1890
6
1
4
1
EPSILON
S2T / L2
FREL
/ El /
/E 2 /
/E 3 /
/ E4 /
1
.1855
0.000
0.000
0.000
0.000
0.000
1
.2153
.913
.831
0.000
.781
0.000
1
-2145
3.290
2.983
0.000
2.812
0.000
1
-1847
3.791
3.034
0.000
2.869
0.000
1
-1581
1.171
.828
.289
.786
.309
1
.1348
0.000
0.000
0.000
0.000
0.000
1
.1147
2.127
1.182
1.942
1.129
2.033
1
.0978
.717
.356
.548
.341
.565
1
.0841
3.299
1.481
2.446
1.422
2.472
1
.0737
1.326
.548
.944
.527
.933
1
.0664
1.821
.707
1.161
.683
1.118
1
.0624
.895
.335
.497
.325
.465
1
.0617
2.361
.879
1.275
.853
1.154
1
.0641
0.000
0.000
0.000
0.000
0.000
1
*0698
.652
.261
.462
.254
.388
1
.0787
1.351
.581
.958
.567
.770
1
.0908
0.000
0.000
0.000
0.000
0.000
1
.1061
1.644
.665
1.320
.846
.965
1
.1247
0.000
0.000
0.000
0.000
0.000
1
. 1464
C.000
0.000
0.000
0.000
0.000
l
.1714
0.000
0.000
0.000
0.000
0.000
1
.1997
2.676
2.283
0.000
2.244
0.000
2
.1712
3.797
2.021
0.000
1.964
0.000
2
.1244
4.072
2.032
3.409
1.973
2.294
2
.0905
2.221
.740
1.238
.717
.926
2
.0695
2.351
.663
1.168
.642
.958
2
.0614
4.412
1.159
1.668
1.119
1.481
2
.0662
o.ooc
0.000
0.000
0.000
0.000
2
.0838
3.765
1.192
1.968
1.143
1.966
2
.1144
1.504
.590
.966
.563
1.004
2
.1579
0.000
0.000
0.000
0.000
0.000
2
.2142
0.000
0.000
0.000
0.000
0.000
2
.2205
0.000
0.000
0.000
0.000
0.000
2
.1734
4.747
2.552
0.000
2.387
0.000
2
.1390
2.252
1.020
1.659
.959
1.535
2
.1176
o.obo
0.000
0.000
0.000
0.000
2
.1091
0.000
0.000
0.000
0.000
0.000
2
.1135
2.999
1.170
1.893
1.115
1.355
2
.1307
0.000
0.000
0.000
0.000
0.000
2
.1609
1.444
.732
0.000
.701
0.000
2
.2039
2.839
1.744
0.000
1.673
0.000
1
.2042
4.017
3.494
0.000
3.391
0.000
OtjT
SERIAL NO .
1691
1892
1893
1894
1895
1896
1897
1898
1899
1900
1901
1902
1903
1904
1905
1906
1907
1908
1909
1910
1911
1912
1913
1914
1915
1916
1917
1918
1919
1920
1921
1922
1923
1924
1925
1926
1927
1928
1929
1930
1931
1932
H K L
5 l 4
4 14
3 14
2 14
114
0 1 4
-1 i 4
-2 l 4
-3 14
-4 14
-5 1 4
-6 14
-7 1 4
-8 14
-9 14
-10 1 4
-10 2 4
-9 2 4
-8 2 4
-7 2 4
-6 2 4
-5 2 4
-4 2 4
-3 2 4
-2 2 4
-12 4
0 2 4
12 4
2 2 4
3 2 4
4 2 4
5 2 4
6 2 4
6 3 4
5 3 4
4 3 4
3 3 4
2 3 4
1 3 4
0 3 4
-13 4
-2 3 4
JCODE EPSILON
1 1
1 1
2 1
2 1
2 1
1 1
1 1
1 1
2 1
l 1
1 1
1 l
l 1
1 l
1 1
1 1
2 1
1 1
1 1
2 1
1 1
1 1
2 1
2 1
2 1
2 1
1 1
2 1
2 1
2 1
2 1
2 1
1 1
1 1
2 1
1 l
1 1
2 1
1 1
1 1
2 1
1 1
S 2 T / L 2
fREl
.1811
1.221
.1612
1.444
.1445
0.000
.1310
0.000
.1208
0.000
.1138
2.906
.1100
1.965
.1094
3.782
.1120
0.000
.1179
1.314
.1270
1.343
.1393
.796
.1549
2.177
.1736
1.706
.1956
2.343
.2208
.921
.2216
0.000
.1964
1.775
.1745
3.417
.1557
0.000
.1401
2.112
.1276
1.737
.1187
0.000
.1129
0.000
.1102
0.000
.1108
0.000
.1146
.751
.1216
0.000
.1318
0.000
.1453
0.000
.1620
0.000
.1819
0.000
.2050
2.011
.2064
2.016
.1833
0.000
.1634
1.674
.1467
1.983
.1332
0.000
.1230
.767
.1160
.754
.1122
0.000
.1116
2.474
/ El /
/€ 2 /
.962
0.000
1.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.606
2.608
1.060
1.639
2.033
3.137
0.000
0.000
.746
1.273
.805
1.316
.511
.832
1.515
1.464
1.299
0.000
1 .966
0.000
.856
0.000
0.000
0.000
1.494
0.000
2.611
0.000
0.000
0.000
1.361
2.225
1.045
1.695
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
.417
.685
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0 J .000
1.755
0.000
1.769
0.000
0.000
0.000
1.214
0.000
1.323
2.396
0.000
0.000
.449
.763
.423
.705
0.000
0.000
1.349
2.130
/ E 3 /
.932
1.003
0.000
0.000
0.000
1.541
1.014
1.940
0.000
.707
.761
.482
1.424
1.216
1.834
.796
0.000
1.395
2.448
0.000
1.287
.992
0.000
0.000
0.000
0.000
.403
0.000
0.000
0.000
0.000
0.000
1.723
1.757
0.000
1.199
1.301
0.000
.438
.411
0.000
1.302
/ 64 /
0.000
0.000
0.000
0.000
0.000
1.919
1.266
2.538
0.000
1.118
1.197
.782
1.417
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.124
1.569
0.000
0.000
0.000
0.000
.517
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.589
0.000
.564
.546
0.000
1.803
SERIAL NO .
H
K
L
JCQDE
EPSILON
S2T / L2
1933
-3
3
4
1
1
.1142
1934
-4
3
4
2
1
.1201
1935
-5
3
4
1
1
.1292
1936
-6
3
4
2
1
.1415
1937
-7
3
4
1
1
.1571
1938
-8
3
4
1
1
.1758
1939
-9
3
4
2
1
.1978
1940
-10
3
4
1
1
.2230
1941
-9
4
4
l
1
.1997
1942
-8
4
4
2
1
.1778
1943
-7
4
4
2
1
.1590
1944
-6
4
4
2
1
.1434
1945
-5
4
4
2
l
.1311
1946
-4
4
4
1
1
.1220
1947
-3
4
4
1
1
.1162
1948
-2
4
4
1
1
.1135
1949
-1
4
4
l
1
.1141
1950
0
4
4
1
l
.1179
1951
1
4
4
2
1
.1249
1952
2
4
4
2
1
.1351
1953
3
4
4
1
1
.1486
1954
4
4
4
2
1
.1653
1955
5
4
4
1
1
.1852
1956
6
4
4
2
1
.2083
1957
6
5
4
2
1
.2108
1958
5
5
4
1
1
.1877
1959
4
5
4
1
1
.1677
1960
3
5
4
2
1
.1511
1961
2
5
4
1
1
.1376
1962
1
5
4
2
1
.1274
1963
0
5
4
2
1
.1203
1964
-1
5
4
1
1
.1166
1965
-2
5
4
2
1
.1160
1966
-3
5
4
1
1
.1186
1967
-4
5
4
1
1
.1245
1968
-5
5
4
1
1
.1336
1969
-6
5
4
1
1
.1459
1970
-7
5
4
2
1
.1615
1971
-8
5
4
1
1
.1802
1972
-9
5
4
1
1
.2022
1973
-9
6
4
2
1
.2052
1974
-8
6
4
1
1
.1832
FREL
/El /
/ E2 /
/ E3 /
/ E4 /
1.503
.833
1.361
.801
1.197
0.000
0.000
0.000
0.000
0.000
1.101
.668
1.068
.636
1.006
0.000
0.000
0.000
0.000
0.000
2.480
1.745
.960
1.646
.954
2.097
1.613
0.000
1.514
0.000
0.000
0.000
0.000
0.000
0.000
2.774
2.601
0.000
2.417
0.000
1.784
1.523
0.000
1.424
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.026
1.179
2.023
1.133
1.877
.754
.423
.708
.409
.635
.749
.413
.669
.401
.579
2.253
1.248
2.034
1.217
1.690
1.314
.745
1.272
.731
1.012
C.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.817
1.225
2.281
1.216
1.560
0.000
0.000
0.000
0.000
0.000
1.230
.986
0.000
.987
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.623
2.126
0.000
2.152
0.000
2.532
1.875
0.000
1.889
0.000
0.000
0.000
0.000
0.000
0.000
2.382
1.514
2.454
1.510
1.820
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.544
1.994
3.350
1.958
2.846
0.000
0.000
0.000
0.000
0.000
1.073
.612
1.053
.594
.963
1.336
.788
1.321
.761
1.247
1.574
.979
1.569
.939
1.524
2.138
1.421
2.545
1.355
2.534
0.000
0.000
0.000
0.000
0.000
2.114
1.658
0.000
1.561
0.000
2.002
1.727
0.000
1.615
0.000
0.000
0.000
0.000
0.000
0.000
1.226
.975
0.000
.919
0.000
142
SERIAL NO .
H
K
L
1975
-7
6
4
1976
-6
6
4
1977
-5
6
4
1978
-4
6
4
1979
-3
6
4
1980
-2
6
4
1981
-l
6
4
1982
0
6
4
1983
1
6
4
1984
2
6
4
1985
3
6
4
1986
4
6
4
1987
5
6
4
1988
6
6
4
1989
6
7
4
1990
5
7
4
1991
4
7
4
1992
3
7
4
1993
2
7
4
1994
1
7
4
1995
0
7
4
1996
-1
7
4
1997
-2
7
4
1998
-3
7
4
1999
-4
7
4
2000
-5
7
4
2001
-6
7
4
2002
-7
7
4
2003
-8
7
4
2004
-9
7
4
2005
-9
8
4
2006
-8
8
4
2007
-7
a
4
2008
-6
8
4
2009
-5
8
4
2010
-4
8
4
2011
-3
8
4
2012
-2
8
4
2013
-1
8
4
2014
0
8
4
2015
1
8
4
2016
2
8
4
JCODE
EPSILON
S2T / L2
2
1
.1645
1
1
. 1489
t
l
.1366
l
l
.1275
1
1
.1217
2
1
.1190
2
1
.1196
1
1
.1234
1
1
.1304
1
I
.1406
1
1
.1541
2
1
.1708
1
1
.1907
1
1
.2138
1
l
.2174
1
1
.1943
1
1
.1743
2
1
.1577
1
1
.1442
1
1
.1340
2
1
.1269
1
1
.1231
1
1
.1226
1
1
.1252
l
1
.1311
i
1
.1402
2
1
.1525
2
1
. 1681
l
1
.1868
2
1
.2088
2
1
.2129
2
1
.1909
2
1
.1722
2
1
.1566
2
1
.1443
2
i
.1352
l
1
.1293
1
1
.1267
2
1
.1273
1
1
.1311
1
1
.1381
2
1
.1483
FREL
/ El /
/ E2 /
o.ooo
0.000
0.000
1.819
1.228
2.299
2.240
1.416
2.289
.775
.466
.758
1.081
.62 8
1.081
0.000
0.000
0.000
0.000
0.000
0.000
1.332
.781
1.323
1.747
1.067
1.695
1 .385
.895
1.475
1.838
1.274
1.419
0.000
0.000
0.000
1.241
1.020
0.000
1.288
1.165
0.000
1.834
1 .682
0.000
2.652
2.212
0.000
1.709
1.305
0.000
0.000
0.000
0.000
1.611
1.061
1.852
1.365
.850
1.365
0.000
0,000
0.000
.767
.449
.763
3.757
2.193
3.743
.771
.457
.761
1.917
1.175
1.871
2.112
1.361
2.228
0.000
0.000
0.000
0.000
0,000
0.000
2.309
1.865
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.559
.946
1.512
1.094
.654
1.073
0.000
0.000
0.000
.782
.479
.763
1.123
.716
1.161
0.000
0.000
0.000
/ E3 /
/ E4 /
0.000
0.000
1.174
2.317
1.364
2,255
.452
.727
.612
1.006
0.000
0.000
0.000
0.000
.777
1.104
1.067
1.354
.901
1.124
1.289
1.029
0.000
0.000
1.044
0.000
1.199
0.000
1.751
0.000
2.289
0.000
1.342
0.000
0.000
0.000
1.077
1.450
.858
1.117
0.000
0.000
.447
.676
2.167
3.435
.448
.7 20
1.144
1.822
1.316
2.224
0.000
0.000
0.000
0.000
1.761
0.000
0.000
G.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.933
1.456
.650
1.003
0.000
0.000
.484
.665
.728
.974
t — 1
0.000
0.000
•er
SERIAL NO .
H
K
L
2017
3
8
4
2018
4
8
4
2019
5
8
4
2020
6
8
4
2021
5
9
4
2022
4
9
4
2023
3
9
4
2024
2
9
4
2025
1
9
4
2026
0
9
4
2027
-1
9
4
2028
-2
9
4
2029
-3
9
4
2030
-4
9
4
2031
-5
9
4
2032
-6
9
4
2033
-7
9
4
2034
-8
9
4
2035
-9
9
4
2036
-9
10
4
2037
-8
10
4
2038
-7
10
4
2039
-6
10
4
2040
-5
10
4
2041
-4
10
4
2042
-3
10
4
2043
-2
10
4
2044
-1
10
4
2045
0
10
4
2046
1
10
4
2047
2
10
4
2048
3
10
4
2049
4
10
4
2050
5
10
4
2051
5
11
4
2052
4
11
4
2053
3
11
4
2054
2
11
4
2055
1
11
4
2056
0
11
4
2057
-1
11
4
2058
-2
11
4
JCODE EPSILON S2T / L2
2 1 .1618
2 1 .1785
2 1 .1984
2 l .2215
2 1 .2030
2 1 .1831
1 1 . 1 66 5
1 1 .1530
l 1 .1428
l 1 .1357
1 1 .1319
1 1 .1314
1 l .1340
2 1 .1399
1 1 .1490
1 1 .1613
2 1 .1769
2 1 .1956
2 l .2176
1 1 .2228
1 1 .2008
1 1 .1821
2 1 .1665
l 1 .1542
1 l .1451
2 1 .1392
1 1 .1366
2 l .1372
2 1 .1410
1 - 1 .1480
2 1 .1582
2 1 .1717
1 l .1884
2 1 .2083
1 1 .2140
2 1 .1941
1 1 .1774
1 1 .1640
1 1 .1537
l 1 .1467
1 1 .1429
2 1 .1424
FREL
/ El /
/ E2 /
/ E3 /
/ E4 /
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.882
1.386
0.000
1.444
0.000
1.421
.980
1.297
1.013
1.068
.802
.524
.894
.537
.767
1.937
1.218
1.964
1.239
1.750
1.753
1.080
1.723
1.089
1.589
2.349
1.442
2.298
1.442
2.186
1.576
.982
1.576
.973
1.541
0.000
0.000
0.000
0.000
0.000
1.410
.952
1.783
.927
1.825
.833
.598
0.000
.577
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.306
1.224
0.000
1.149
0.000
2.363
2.027
0.000
1.923
0.000
1.936
1.531
0.000
1.468
0.000
C.000
0.000
0.000
0.000
0.000
1.838
1.275
1.390
1.246
1.439
.806
.533
.944
.527
.959
0.000
0.000
0.000
0.000
0.000
1.373
.868
1.403
.873
1,357
0.000
0.000
0.000
0.000
0.000
C.000
0.000
0.000
0.000
0.000
1.980
1.335
2.466
1.381
2.164
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.957
1.592
0.000
1 .689
0.000
0.000
0.000
0,000
0.000
0.000
.911
.825
0.000
.893
0.000
0.000
0.000
0.000
0.000
0.000
1.718
1.331
0.000
1.414
0.000
1.184
.861
0.000
.907
0.000
1.836
1.271
1.499
1.325
1.344
1.983
1.323
2.399
1.366
2.226
1.796
1.175
2.010
1.201
1.923
O.OOC
0.000
0.000
0.000
0.000
tltjT
SERIAL NO .
H
K
L
2059
-3
11
4
2060
-4
u
4
2061
-5
11
4
2062
-6
11
4
2063
-7
1 1
4
2064
-8
11
4
2065
-a
12
4
2066
-7
12
4
2067
-6
12
4
2068
-5
12
4
2069
-4
12
4
2070
-3
12
4
2071
-2
12
4
2072
-1
12
4
2073
0
12
A
2074
1
12
4
2075
2
12
4
2076
3
12
4
2077
4
12
4
2078
5
12
4
2079
4
13
4
2080
3
13
4
2081
2
13
4
2082
1
13
4
2083
0
13
4
2084
-1
13
4
2085
-2
13
4
2086
-3
13
4
2087
-4
13
4
2088
-5
13
4
2089
-6
13
4
2090
-7
13
4
2091
-8
13
4
2092
-7
14
4
2093
-6
14
4
2094
-5
14
4
2095
-4
14
4
2096
-3
14
4
2097
-2
14
4
2098
-1
14
4
2099
0
14
4
2100
1
14
4
JCODE
EPSILON
S2T / L2
1
1
.1450
2
1
.1509
1
1
.1600
1
1
.1723
1
1
.1878
1
1
.2066
1
1
.2129
2
1
.1942
2
1
.1786
1
1
.1663
l
1
.1572
2
1
.15 13
1
1
.1487
l
1
.1493
2
1
.1530
1
1
.1601
2
1
.1703
1
1
.1838
1
l
.2005
2
1
.2204
2
1
.2073
1
1
.1906
2
1
.1772
2
1
. 1669
2
1
.1599
2
1
.1561
2
1
.1556
1
1
.1582
2
1
, 1641
2
1
.1732
1
1
.1855
1
1
.2010
1
1
.2198
2
1
.2085
1
1
.1929
2
l
.1806
1
1
.1715
2
1
. 1656
1
1
.1630
1
1
.1635
2
1
.1673
1
1
.1744
fREL
/ El /
/ E2 /
2.420
1.601
2.829
0.000
0.000
0.000
2.351
1.678
.005
.850
.643
0.000
1.236
1.002
0.000
1.274
1.119
0.000
1.822
1.642
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1-458
1.073
0.000
1.654
1.165
.609
0.000
0.000
0.000
1.409
.950
1.772
2.442
1.651
3.105
0.000
0.000
0.000
.831
.593
0.000
C.OOO
0.000
0.000
1.942
1.548
0.000
2.362
2.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.878
.721
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.828
.586
.197
0.000
0.000
0.000
0.000
0.000
0.000
.870
.699
0.000
2.189
1.879
0.000
1.841
1 . 7C5
0.000
0.000
0.000
0.000
.881
.731
0.000
0.000
0.000
0.000
1.900
1.432
0.000
0.000
0.000
0.000
1 .449
1.049
0.000
.836
.607
0.000
0.000
0.000
0.000
.853
.652
0.000
/E 3 /
7E47
1.604
2.849
0.000
0.000
1.647
.005
.625
0.000
.963
0.000
1.064
0.000
1.563
C.OOO
0.000
0.000
0.000
0.000
1.057
0.000
1.161
.633
0.000
0.000
.967
1.769
1.700
3.021
0.000
0.000
.624
0.000
0.000
0.000
1.661
0.000
2.192
0.000
0.000
0.000
0.000
0.000
.781
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.593
.203
0.000
0.000
0.000
0.000
.683
0.000
1.815
0.000
1.626
0.000
0.000
0.000
.717
0.000
0.000
0.000
1.441
0.000
0.000
0.000
1.083
0.000
.634
0.000
t — 1
0.000
0.000
-f
.697
0.000
SERIAL NO .
H
K
L
JCOOE
EPSILON
S2T / L2
EREL
/ El /
/ E2 /
/ E3 /
/E 4 /
2101
2
14
4
1
l
.1846
1.740
1.392
o.ooo
1.506
0.000
2102
3
14
4
1
1
.1981
1.779
1. 508
0.000
1.651
0.000
2103
4
14
4
1
1
.2147
1.290
1.171
0.000
1.297
0.000
2104
4
IS
4
2
1
.2227
C.000
0.000
0.000
0.000
0.000
2105
3
15
4
1
1
.2060
1.273
1.115
0.000
1.233
0.000
2106
2
15
4
2
1
.1926
0.000
0.000
0.000
0.000
0.000
2107
1
15
4
1
1
.1823
1.224
.969
0.000
1.045
0.000
2108
0
15
4
1
1
.1753
1.711
1.313
0.000
1.399
0.000
2109
-1
15
4
2
1
.1715
0.000
0.000
0.000
0.000
0.000
2110
-2
15
4
l
1
.1709
2.400
1.804
0.000
1.873
0.000
2111
-3
15
4
2
1
.1736
0.000
0.000
0.000
0.000
0.000
2112
-4
15
4
1
1
.1795
1.724
1.348
0.000
1.363
0.000
2113
-5
15
4
1
1
.1886
2.476
2.015
0.000
2.010
0.000
2114
-6
15
4
l
1
.2009
1.998
1.714
0.000
1.687
0.000
2115
-7
15
4
l
1
.2164
1.567
1.450
0.000
1.408
0.000
2116
-6
16
4
1
1
.2094
.905
.804
0.000
.794
0.000
2117
-5
16
4
2
1
.1971
0.000
0.000
0.000
0.000
0.000
2118
-4
16
4
2
1
.1880
0.000
0.000
0.000
o.ooo
0.000
2119
-3
16
4
2
1
.1821
0.000
0.000
0.000
0.000
0.000
2120
-2
16
4
2
1
.1795
O.OOG
0.000
0.000
0.000
0.000
2121
-1
16
4
1
1
.1800
1.726
1.353
0.000
1.433
0.000
2122
0
16
4
2
1
.1638
C.000
0.000
0.000
0.000
0.000
2123
1
16
4
1
1
.1908
1.242
1.021
0.000
1.111
0.000
2124
2
16
4
1
1
.201 1
2.364
2.030
0.000
2.238
0.000
2125
3
16
4
2
1
.2145
0.000
0.000
0.000
0.000
0.000
2126
3
17
4
1
l
. 2236
1.604
1.507
0.000
1.701
0.000
2127
2
17
4
2
1
.2102
0.000
0.000
0.000
0.000
0.000
2126
1
17
4
2
1
. 1999
0.000
0.000
0.000
0.000
0.000
2129
0
17
4
1
1
. 1929
1.764
1.463
0.000
1.583
0.000
2130
-1
17
4
1
1
.1891
3.035
2.476
0.000
2.642
0.000
2131
-2
17
4
l
1
.1885
1.517
1.235
0.000
1.299
0.000
2132
-3
17
4
1
1
. 1912
.879
.723
0.000
.750
0.000
2133
-4
17
4
2
1
.1971
0.000
0.000
0.000
0.000
O.OOQ
2134
-5
17
4
2
1
.2062
0.000
0.000
0.000
0.000
0.000
2135
-6
17
4
2
1
.2185
0.000
0.000
0.000
0.000
0.000
2136
-5
18
4
2
1
.2158
0.000
0.000
0.000
0.000
0.000
2137
-4
18
4
1
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2.706
2.377
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2.440
0.000
2138
-3
18
4
2
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.2008
0.000
0.000
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0.000
0.000
2139
-2
18
4
1
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1.542
1.308
0.000
1.384
0.000
2140
-1
18
4
1
1
.1987
1.781
1.514
0.000
1.627
0.000
2141
0
18
4
2
1
.2025
C.000
0.000
0.000
0.000
0.000
2142
1
18
4
2
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.2095
0.000
0.000
0.000
0.000
0.000
9171
SERIAL NO .
H
K
L
2163
2
18
6
2166
1
19
4
2165
0
19
6
2166
19
6
2167
-2
19
4
2168
-3
19
6
2169
-6
19
4
2150
-3
20
4
2151
-2
20
4
2152
-l
20
4
2153
0
20
6
2156
-2
14
5
2155
-4
13
5
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-3
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5
2157
-2
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2161
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12
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2162
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2163
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5
2167
-6
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2175
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10
5
2177
-3
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5
2178
-6
10
5
2179
-5
10
5
2180
-6
10
5
2181
-6
9
5
2182
-5
9
5
2183
-4
9
5
2184
-3
9
5
JCODE EPSILON S 2 T / L 2
1 I .2198
1 1 =2197
1 1 .2127
2 1 .2089
1 1 .2083
1 1 .2110
2 1 .2168
1 1 .2217
1 i .2190
l 1 .2196
1 1 .2234
2 1 .224 1
2 1 .2225
i 1 .2180
1 1 .2167
3 £ .2186
2 1 .2238
2 1 .2169
2 l .2117
2 l .2098
2 1 .2111
1 1 .2156
2 1 .2236
1 1 .2171
2 1 .2093
1 1 .2068
2 1 .2035
2 1 .2056
1 1 .2106
1 1 .2189
2 1 .2132
1 1 .2068
2 1 .1996
2 1 .1977
1 1 .1990
2 1 .2035
2 1 .2113
2 1 .2223
2 1 .2170
2 1 .2061
2 1 .1983
l l .1938
FREL
/ El /
/E2/
/ E 3 /
/E4/
1.841
1.704
.919
.651
2.574
2.317
0.000
0.000
.903
.799
2.401
2.147
0 .000
0.000
1.599
1.492
2.251
2.078
2.601
2.407
1.603
1.506
0.000
0.000
0.000
0.000
3.178
2.922
1.832
1.676
. 91 E
. 846
o.ooc
0.000
o.ooc
0.000
0.000
0.000
o.ooc
0.000
o.ooc
0.000
2.585
2.355
O.OOC
o.ooc
.916
.639
0.000
0.000
.898
.763
0.000
0.000
0.000
0.000
1.815
1.620
.918
.847
O.OOC
0.000
.898
.783
3.089
2.636
0.000
0.000
1.992
1.695
0.000
0 . 00 0
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooc
0.000
2.336
i .945
0.000
1.915
0.000
.950
o.ooc
2.S4S
Q.OOC
o.ooc
0.000
.051
o.ooc
2.251
0 . 000
0.000
0.000
1.574
0.000
2. 229
0.000
2.625
0.000
1.670
0.000
0.000
0.000
0.000
0.000
2. 968
c.ooc
1.723
0.000
.sso
Co occ
OcQOC
0.000
O.OOC
0 o 000
O o 0@C
0. 000
Q.©©0
0.000
0.09©
Co 000
2.347
0.000
0.000
0.000
.022
0.000
0.000
0.000
.784
0 o 000
O.OOC
0.000
0.000
0.000
1.673
0.000
.884
0.000
0.000
0.000
. 301
0.000
2.671
0.000
O.OOC
0.000
1.685
0.000
0.000
0.000
0.000
0.000
o.oos
0.000
0.000
0.000
0.000
0 o 000
0.000
0.000
1.919
g.qoo
0.000
9.000
0.000
0.000
0.000
0.000
0.000
G. 000
0.000
0.000
0.000
So 000
C.000
Qo OSS
QoQQG
So 000
0.000
Q.OGQ
OoGOS
S. 000
0. 000
G.SOQ
0.000
o.oes
0.000
0.000
0.000
0.000
0 o 000
0.000
e.ooo
0.000
0.000
0.000
0.000
0 . 000
0.000
0.000
0.000 H
0.000 -fr
e.ooe
noronot-*
JCDOE
1
1
1
l
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
1
2
2
1
EPS ICON
1
1
1
l
1
1
1
1
1
1
i
I
1
I
1
I
I
1
i
1
1
1
I
1
I
1
1
1
I
1
1
1
1
1
1
1
1
l
1
1
1
l
SZT / L 2
.1925
• 1944
.1996
.2079
.2195
.2149
.2033
.1949
.1898
.1878
.1891
.1936
.2014
.2124
.2224
.2082
.1973
.1895
.1850
.1837
.1856
.1908
.1991
.2107
.2220
.2072
.1956
.1872
.1821
.1801
.1814
.1860
.1937
.2047
.2189
.2158
.2016
.1907
.1829
.1784
.1771
.1790
FREt
2.159
0.000
0.000
0.000
1.300
2.042
0.000
0.000
2.481
1.516
0.000
2.497
0.000
0.000
0.000
C .000
0.000
0.000
2.611
1.227
1.231
1.965
1.259
1.816
2.064
1.564
2.170
2. 311
1.501
2.113
1.499
3.698
.882
1.798
.918
1-830
0.000
1.758
.866
0.000
0.000
.860
/El/
fEZ/
/E 3 /
/E 4 /
1.787
0.000
1.779
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.202
0.000
1.239
0.000
1.855
0.000
1.892
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.029
0.000
2.022
0.000
1.230
0.000
1.215
0.000
0.000
0.000
0.000
0.000
2.077
0.000
2.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.092
0.000
2.036
0.000
.977
0.000
.958
0.000
.989
0.000
.977
0.000
1.615
0.000
1.607
0.000
1.072
0.000
1.074
0.000
1.622
0.000
1.637
0.000
1.928
0.000
1.937
0.000
1.377
0.000
1.375
0.000
1.820
0.000
1.806
0.000
1 . 869
0.000
1.843
0.000
1.187
0.000
1.162
0.000
1.657
0.000
1.612
0.000
1.182
0.000
1.142
0.000
2.975
0.000
2.855
0.000
.734
0.000
.699
0.000
1.567
0.000
1.482
0.000
.847
0.000
.795
0.000
1 .668
0.000
1.560
0.000
0.000
0.000
0.000
0.000
1.444
0.000
1.368
0.000
.688
0.000
.656
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.671
0.000
.652
0.000
co
SERIAL NO
H K L
JCQDE EPSILON S2T/L2
2227
0
5
5
2228
1
5
5
2229
2
5
5
2230
3
5
5
2231
3
4
5
2232
2
4
5
2233
1
4
5
2234
0
4
5
2235
-l
4
5
2236
-2
4
5
2237
-3
4
5
2238
-4
4
5
2239
-5
4
5
2240
-6
4
5
2241
-7
4
5
2242
-7
3
5
2243
-6
3
5
2244
-5
3
5
2245
-4
3
5
2246
-3
3
5
2247
-2
3
5
2248
-1
3
5
2249
0
3
5
2250
1
3
5
2251
2
3
5
2252
3
3
5
2253
3
2
5
2254
2
2
5
2255
1
2
5
2256
0
2
5
2257
-1
2
5
2258
-2
2
5
2259
-3
2
5
2260
-4
2
5
2261
-5
2
5
2262
-6
2
5
2263
-7
2
5
2264
-7
1
5
2265
-6
1
5
2266
-5
1
5
2267
-4
1
5
2266
-3
1
5
2 1 .1842
1 l .1925
1 1 .2041
1 1 .2190
1 l .2165
1 1 .2017
t 1 .1901
1 1 .1817
2 1 .1766
1 1 .1746
1 l .1759
1 1 .1805
1 1 .1682
1 1 .1992
2 1 .2134
2 1 .2114
2 1 .1972
1 1 .1863
1 1 .1785
1 1 .1740
l 1 .1727
1 1 .1746
2 1 .1758
2 l .1881
1 1 .1997
1 1 .2146
1 1 .2132
2 1 .1984
1 1 .1868
1 1 .1784
1 1 .1733
1 1 .1713
1 1 .1726
1 1 .1772
1 1 .1849
1 1 .1959
2 1 .2101
l 1 .2092
1 1 .1950
1 1 .1841
1 l .1763
1 1 .1716
FREL
/ El /
/E2/
/E3/
/E4 /
0.000
0.000
1.245
1.031
2.376
2.066
1.298
1.198
1.832
1.674
2.001
1.722
.877
.718
.864
.603
0.000
0.000
1.709
1.307
.856
.658
2.990
2.348
1.750
1.422
1.259
1.072
0.000
0.000
0.000
0.000
0.000
0.000
.871
• 7C2
1.721
1.340
1.206
.920
1.476
1.119
2.093
1.601
0.000
0.000
0.000
0.000
3.215
2.745
.912
.827
2.576
2.323
0.000
0.000
2.138
1.726
1.924
1.497
.852
.647
1.200
.904
2.085
1.580
2.102
1.626
1.741
1.394
2.344
1.969
0.000
0.000
.905
.803
1.534
1.284
3.009
2.402
.856
.660
2.551
1.926
0.000
0.000
0.000
1.013
0.000
2.041
0.000
1.190
0.000
1.644
0.000
1.683
0.000
.699
0.000
.661
0.000
0.000
0.000
1.253
0.000
.627
0.000
2.226
0.000
1.341
0.000
1.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.650
0.000
1.262
0.000
.871
0.000
1.064
0.000
1.529
0.000
0.000
0.000
0.000
0.000
2.656
0.000
.804
0.000
2.232
0.000
0.000
0.000
1.648
0.000
1.423
0.000
.613
0.000
.853
0.000
1.486
0.000
1.523
0.000
1.300
0.000
1.828
0.000
0.000
0.000
.739
0.000
1.187
0.000
2.228
0.000
.614
0.000
1.799
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000 |_j
0.000 _f
O.OOC vo
SERIAL NO.
H
K
L
JCOOE
EPS ICON
SZT/’L 2
PR£L
/El/
/E2/
/E3/
/£4/
2269
-2
1
5
l
1
.1705
1.470
1.103
0=000
1 = 034
0.000
2270
-1
1
5
2
1
.1724
0.000
0.000
0.000
0.000
0.000
2271
0
1
5
1
1
.1776
1.710
1=332
0 = 000
1.256
0.000
2272
1
1
5
2
1
.1860
o.ooc
0.000
0=000
0.000
0. 000
2273
2
1
5
2
l
.1975
0.000
O.QOO
0.000
Q.QQO
0.000
2274
3
1
5
2
1
.2124
0.000
0.000
0.000
0.000
0.006
2275
3
0
5
l
2
.2121
2.227
1.414
0.000
1.329
O.OOC
2276
1
0
5
1
2
.1857
2.463
1.400
0.000
1.311
0.000
2277
-1
0
5
1
2
.1722
.850
.454
0.000
.424
0.000
227B
-3
0
5
1
2
.1715
2.687
1.433
Go 00 0
1.329
0.000
2279
-5
0
5
1
2
.1836
1.227
.692
0.000
.630
QoGOO
2280
-7
0
5
1
2
.2090
4. 340
2.721
0.000
2 = 497
0.000
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